Effect of sodium carbonate on the oxidation of sublimates during niobium electron-beam remelting

The effect of sodium carbonate additions on phase formation during the air oxidation of the sublimates of niobium electron-beam remelting is studied by derivatography, X-ray diffraction analysis, and electron-probe microanalysis. The composition of the oxidation products changes with the heating temperature. The formation of sodium niobates and aluminates is detected by X-ray diffraction analysis at temperatures higher than 600°C. The oxidation of the sublimates is completed by the formation of sodium metaniobate and aluminate. Sodium carbonate additions are shown to accelerate the oxidation of the sublimates.     

Characteristics of a descending dispersed-annular flow

Experimental data on the loss of liquid from the surface of a film and the resistance of dispersed-annular flow are presented.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 52, No. 6, pp. 925–929, June, 1987.     

Phase equilibria in the system Al-Rh

Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l ⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method of forming phases in the field of composition rich in aluminum given in publications are confirmed. __________ Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006.     

Internal-corrosion inhibitors for pipelines carrying deaerated heating water

The effect of internal-corrosion inhibitors on heating-system pipelines is investigated. Tests were conducted on a testing device for polarization measurements under conditions corresponding to the Rostov Heat-Supply System. The concentration of OEDP-zinc, which provides a high degree of protection from general corrosion, is determined. The reagent has been successfully incorporated into the Rostov No. 2 TPP. __________ Translated from élektricheskie Stantsii, No. 7, July 2007, pp. 37–43.     

Internal-corrosion inhibitors for pipelines in heat-supply systems carrying water with a high oxygen content

The reliability of heat-supply systems is determined primarily by internal corrosion of the pipelines. The concentration of oxygen in the water exerts a major influence on the corrosion. In systems with a standard oxygen content, OéDF-Zn is a highly effective corrosion inhibitor. However, there are systems in which the quality of deaeration of the make-up water of the heat-supply system is low (or deaeration is nonexistent), and the concentration of oxygen is considerably above the standard value. Classed among these systems, for example, are the HWS systems, which are incorporated into closed heat-supply systems. The oxygen concentration in these systems is analyzed to assess the situation. __________ Translated from élektricheskie Stantsii, No. 6, June 2007, pp. 35–39.     

Nonstationary processes in a controlled electric drive with a high-voltage frequency converter intended for a mainline pump of a heat-supply station

Results of the studies of nonstationary electromagnetic and electromechanical processes that develop during the start-up (restart) of a frequency-controlled electric drive of a mainline pump as result of perturbation in the electric supply system are presented.     

Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

External heat transfer in infiltrated granular beds. Experimental study

Experimental data was obtained on external heat transfer in infiltrated granular beds of coarse particles. It was determined that calcualtions with the proposed model agree satisfactorily with the experimental results.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 53, No. 6, pp. 919–923, December, 1988.