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71.
72.
73.
Rui A. S. Lapa José L. F. C. Lima 《Journal of Automated Methods and Management in Chemistry》1991,13(3):119-122
The construction of a microcomputer-controlled electrode switch for
use in potentiometric determinations is described. This can be coupled to most of the analytical equipment usually found in laboratories, to enable a setting up of automatic systems capable of performing sequential determinations with several ion-selective
electrodes. The assessment of its analytical usage and behaviour are discussed. 相似文献
74.
André Revillon 《Journal of Coatings Technology》2002,74(930):55-63
This paper presents an academic analysis of recent progress and changes in polymer science. These changes influence the coatings
industry, as an answer to various constraints, such as enhanced applicability, quality certification, safety, and care of
environment. We do not focus on a specific topic but instead consider the basic concepts, the chemical advances in polymer
synthesis, and progress in fine characterization methods. Experimental results in polymerization, analysis, and new processes,
obtained in recent years, in the final period of my laboratory activity, are illustrated.
Presented at the 79th Annual Meeting of the Federation of Societies for Coatings Technology, in Atlanta, GA, Nov. 5–7, 2001.
200 Avenue Félix Faure, F-69003-Lyon, LMOPS, 69390 Vernaison on behalf of AFTPVA, France, email: arevillon@gonline.fr. 相似文献
75.
André Girard Pierre Dominique Lansard Bernard Liau Anne Marie Mongeon Jean Luc Thibault 《电信纪事》1991,46(5-6):335-350
Classical hierarchical routing in telephone networks is extended to a wider class called out-of-chain routing in such a way that some useful properties of hierarchical routing are retained. This new routing pattern offers more potential paths than the fixed hierarchical one and can be introduced as a dynamic routing where the fixed alternate sequences change at some predetermined instants during the day. The effect of this new routing pattern on the network performances is examined. The main topic of this paper is to present heuristic methods used to optimise such routings in large networks. We show on artificial networks that the throughput of a given network can be significantly improved by suitable routing choices. We demonstrate that the integration of routing changes within a multihour dimensioning process is possible but the lack of realistic data does not permit at this time to quantify the value of routing optimization on real networks. 相似文献
76.
Javier Lara-Romero Rafael Maya-Yescas José Luis Rico-Cerda José Luis Rivera-Rojas Fernando Chiñas Castillo Matey Kaltchev 《Thin solid films》2006,496(2):463-468
The thermal decomposition of model extreme-pressure lubricant additives on clean iron was studied in ultrahigh vacuum conditions using molecular beam strategies. Methylene chloride and chloroform react to deposit a solid film consisting of FeCl2 and carbon, and evolve only hydrogen into the gas phase. No gas-phase products and less carbon on the surface are detected in the case of carbon tetrachloride. Dimethyl and diethyl disulfide react on clean iron to deposit a saturated sulfur plus carbon layer at low temperatures (∼600 K) and an iron sulfide film onto a Fe + C underlayer at higher temperatures (∼950 K). Methane is the only gas-phase product when dimethyl disulfide reacts with iron. Ethylene and hydrogen are detected when diethyl disulfide is used. 相似文献
77.
José Luiz Antunes de Oliveira e Sousa Ravindra Gettu 《Canadian Metallurgical Quarterly》2006,132(2):141-148
The determination of the fundamental stress versus crack opening (σ-w) response of concrete under uniaxial tension is performed in this study through inverse analysis using data from notched beam tests. The procedure used for optimizing the parameters of the σ-w relation using the load versus crack mouth opening displacement response of the notched beam is described. Satisfactory comparisons have been obtained between the σ-w curves obtained through the inverse analysis and those directly measured in uniaxial tension tests. The use of weighting functions in the inverse analysis may be necessary when large crack widths are to be considered. 相似文献
78.
The composition of yellow bronze coatings deposited from acidic sulfate solutions added with polyether laprol and the electrodeposition
conditions are studied by voltammetry and XPS. It is found that halides in rather low (micromolar) concentrations affect significantly
the partial electrodeposition processes. Chlorides increases cathodic polarization, widen the current window of the yellow
bronze electrodeposition, and favor the increase in tin content of the coatings. Bromides narrow the current window, lower
the tin content in the coatings, and hinder the yellow bronze surface oxidation. Iodides inhibit the copper electroreduction
markedly, which makes the yellow bronze deposition practically impossible.
Original Russian Text ? Z. Mockus, S. Kanapeckaité, V. Jasulaitiené, A. Survila, 2006, published in Zashchita Metallov, 2006,
Vol. 42, No. 5, pp. 526–531. 相似文献
79.
80.
C sar Ovalles Carlos Vallejos Tito Vasquez Iraima Rojas Ursula Ehrman Jose Luis Benitez Ronald Martinez 《Petroleum Science and Technology》2003,21(1):255-274
An extra-heavy crude oil underground upgrading process is described which involves the downhole addition of a hydrogen donor additive under steam injection conditions (280-315°C and residence times of at least 24-h). Laboratory experiments showed a 4° increase in the API gravity (from 9 to 12°) of the upgraded product, a two-fold reduction in the viscosity and, an approximately 8% decrease in the asphaltene content with respect to the original crude. Further increases on the temperature led to products with improved properties reaching 15°API at 315°C. It was found that the presence of the natural formation (catalysts) and methane (natural gas) is necessary to enhance the properties of the upgraded crude oil. From GC and GC-MS results a reaction pathway is proposed that involves hydrogen transfers from tetralin to the extra-heavy crude oil resulting in the formation of 1,2-dihydronaphthalene. This compound is then transformed into naphthalene, further upgrading of crude oil through hydrogen donation. The results of the experiments carried out in the presence and absence of the mineral formation and with an inert solid (SiC) strongly indicate that the former acts as a catalyst and not as a heat transfer matrix. Isotopic labeling studies (CD4 and 13CH4) give evidences that, most probably, methane is involved in the upgrading reactions. 相似文献