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41.
Effect of moisture and particle size on the extractability of oils from seeds with supercritical CO2
J. M. Snyder J. P. Friedrich D. D. Christianson 《Journal of the American Oil Chemists' Society》1984,61(12):1851-1856
Moisture level and particle size of soybeans, peanuts and cottonseed were correlated with the extraction rate and yield of
oil when extracted with supercritical carbon dioxide (SC-CO2) at a constant temperature (50 C) and pressure (8000 psig). The rate of extraction and ultimate oil yields were quite low
with cracked soybeans. However, good extraction rates and nearly theoretical oil yields were obtained from ground or thinly
flaked (<0.010″) seeds. Moisture levels between 3% and 12% had little effect on extracability. Oil composition was not influenced
by either parameter. Scanning electron microscopy was used to study seed structure before and after extraction with SC-CO2. Micrographs of SC-CO2-extracted seeds were similar to hexane-extracted seeds.
Presented at the AOCS Meeting, May 1983, Chicago. 相似文献
42.
The nonisothermal and isothermal crystallizations of low‐density polyethylene (LDPE) and polypropylene (PP) in phosphate glass (Pglass)–polymer hybrid blends were studied through differential scanning calorimetry (DSC). As the Pglass volume fraction was increased, the percentage crystallinity decreased. The half‐time for crystallization decreased as the propagation rate constant rose, for both of the polymer matrices, with increasing Pglass concentrations. The Pglass was observed to be a nucleating agent for formation of two‐ or three‐dimensional spherulites in the hybrids. Tensile modulus improved for both of the Pglass–polymer hybrids up to 40% Pglass, but the energy to break decreased. Tensile strength changed slightly with the addition of Pglass to the LDPE matrix, exhibiting a larger value than that of pure LDPE at 30%. The tensile strength decreased as more Pglass was added to the PP matrix. The observed differences between tensile properties of the Pglass–PP and Pglass–LDPE hybrids at identical Pglass volume concentration were found to be consistent with that of the crystallization behavior of the hybrids. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3445–3456, 2003 相似文献
43.
A proposed method for estimating the electrical conductivity of cement paste pore solution at 25 °C is based on the concentrations of OH−, K+ and Na+. The approach uses an equation that is a function of the solution ionic strength, and requires a single coefficient for each ionic species. To test the method, the conductivity of solutions containing mixtures of potassium hydroxide and sodium hydroxide with molar ratios of 4:1, 2:1 and 1:1, and having ionic strengths varying from 0.15 to 2.00 mol/l were measured in the laboratory and compared to predicted values. The proposed equation predicts the conductivity of the solutions to within 8% over the concentration range investigated. By comparison, the dilute electrolyte assumption that conductivity is linearly proportional to concentration is in error by 36% at 1 mol/l and in error by 55% at 2 mol/l. The significance and utility of the proposed equation is discussed in the context of predicting ionic transport in cement-based systems. 相似文献
44.
The process of grinding soybeans to a fine flour and extracting the flour with hexane was studied on a pilot plant scale.
The crude oil from the pilot plant study had 15 ppm phosphorus and was suitable for physical refining after a light acid pretreatment
and bleaching. The refined oil showed a Lovibond color of 1.4 yellow and 0.3 red. The pilot plant study also showed that grinding
of the soybeans and the separation of solid from miscella were the most difficult steps in solvent extraction with fine flour.
A laboratory study on separation of miscella from meal by aqueous ethanol reduced the hold-up volume, but it did not remove
all the miscella. A test with betacarotene showed that only the miscella outside the flour particles was displaced.
Aqueous ethanol solutions used as a second solvent extracted additional nontriglyceride materials (primarily phospholipids)
from the meal. Also, the free fatty acid content of the oil was increased with aqueous ethanol solution wash. The quality
of the extracted crude oil was lowered by using a second solvent, but it had the advantage of needing only one centrifugation
to separate miscella from meal. 相似文献
45.
Dietary n-3 fatty acids, abundant in fish oil, exert a variety of effects that attenuate cardiovascular disease. In this study,
we assessed the effect of fish oil (menhaden oil) on the serum lipid profile in hypertensive and normotensive rats. Spontaneously
hypertensive rats (SHR) or Sprague-Dawley rats (SD) were fed either standard powdered diet (L-485), or L-485+5% menhaden oil
(MO) or L-485+5% corn oil (CO) from weaning through eight months of age. Systolic blood pressure (BP) was periodically determined
on SHR. Serum lipid profiles were performed at eight months on sample taken from the exposed hearts of anesthetized, fasted
rats. SHR, compared with SD (diets combined) had significantly lower triaclyglycerols (TG), higher cholesterol (CHOL), higher
high density lipoprotein cholesterol (HDL CHOL), higher low density lipoprotein cholesterol (LDL CHOL), and a higher LDL:HDL
ratio. Comparison among diets (strains combined) revealed that rats fed MO had the lowest values for TG, CHOL, LDL and LDL:HDL;
HDL did no vary with diet. SHR were less responsive to diet-induced changes than were SD; no decrease in TG, LDL or LDL:HDL
was observed in SHR, nor was degree of hypertension altered in SHR by the MO or CO diet. In summary, MO is more effective
than CO in shifting the lipid profile of rats toward one that is less atherogenic. However, the SD rat is more susceptible
to diet-induced lipid modification than is the SHR. 相似文献
46.
Justin McKetney Daniel J. Panyard Sterling C. Johnson Cynthia M. Carlsson Corinne D. Engelman Joshua J. Coon 《Proteomics. Clinical applications》2021,15(2-3):2000072
Proteomic analysis of cerebrospinal fluid (CSF) holds great promise in understanding the progression of neurodegenerative diseases, including Alzheimer's disease (AD). As one of the primary reservoirs of neuronal biomolecules, CSF provides a window into the biochemical and cellular aspects of the neurological environment. CSF can be drawn from living participants allowing the potential alignment of clinical changes with these biochemical markers. Using cutting-edge mass spectrometry technologies, we perform a streamlined proteomic analysis of CSF. We quantify greater than 700 proteins across 10 pairs of age- and sex-matched participants in approximately one hour of analysis time each. Using the paired participant study structure, we identify a small group of biologically relevant proteins that show substantial changes in abundance between cognitive normal and AD participants, which were then analyzed at the peptide level using parallel reaction monitoring experiments. Our findings suggest the utility of fractionating a single sample and using matching to increase proteomic depth in cerebrospinal fluid, as well as the potential power of an expanded study. 相似文献
47.
Kevin A. Masser Joshua A. Orlicki Eugene Napadensky Terrence Taylor Doug Harris 《应用聚合物科学杂志》2021,138(3):49703
A series of transparent methacrylate-based crosslinked polymer networks are prepared in which the crosslinker length is controlled as a means to investigate the effects of network ductility on mechanical and ballistic properties. In each network the optical clarity of pure poly(methyl methacrylate) (PMMA) is retained, as well as a low value of haze. Both the glass transition temperature (Tg) and the tensile modulus of the networks are highly tunable, with network values both above and well below that of pure PMMA or the pure crosslinker network. The ballistic performance is likewise affected, with performance values of up to 400% greater than neat PMMA. We examine the effects of the crosslinker molecular weight on the impact performance, finding that, in these systems, the molecular weight between crosslinks is not a driving factor for the impact performance, and this may broadly translate to polymer networks in general. We find that improvements in ballistic performance can be realized at low molecular weight between crosslinks, provided the crosslinking agent is of sufficient ductility. 相似文献
48.
C. -X. Ji Peter F. Ladwig Ronald D. Ott Y. Yang Joshua J. Yang Y. Austin Chang Eric S. Linville Jenny Gao Bharat B. Pant 《JOM Journal of the Minerals, Metals and Materials Society》2006,58(6):50-54
Sputter-deposited, equiatomic PtMn thin films have application in giant magnetoresistive spin valves, tunneling magnetoresistive
spin valves, and magnetic random access memory. However, the as-deposited films are found to be a disordered A1 phase in a
paramagnetic state rather than an antiferromagnetic phase with L10 structure, which is needed for device operation. Therefore, a postannealing step is required to induce the phase transformation
from the asdeposited A1 face-centered-cubic phase to the antiferromagnetic L10 phase. The A1 to L10 metastable transformation was studied by x-ray diffraction and differential-scanning calorimetry. An exothermic transformation
enthalpy of −12.1 kJ/mol of atoms was determined. The transformation kinetics were simulated using the Johnson-Mehl-Avrami
analysis. 相似文献
49.
Experiencing Nature: Embodying Animals in Immersive Virtual Environments Increases Inclusion of Nature in Self and Involvement With Nature
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Sun Joo Ahn Joshua Bostick Elise Ogle Kristine L. Nowak Kara T. McGillicuddy Jeremy N. Bailenson 《Journal of Computer-Mediated Communication》2016,21(6):399-419
Immersive virtual environments (IVEs) produce simulations that mimic unmediated sensory experiences. 3 experiments (N = 228) tested how different modalities increase environmental involvement by allowing users to inhabit the body of animals in IVEs or watch the experience on video. Embodying sensory‐rich experiences of animals in IVEs led to greater feeling of embodiment, perception of being present in the virtual world, and interconnection between the self and nature compared to video. Heightened interconnection with nature elicited greater perceptions of imminence of the environmental risk and involvement with nature, which persisted for 1 week. Although the effect sizes were small to moderate, findings suggest that embodied experiences in IVEs may be an effective tool to promote involvement with environmental issues. 相似文献
50.
Joshua Schoonmaker 《Information & Communications Technology Law》2016,25(2):96-128
Autonomous vehicles are on the cusp of disrupting the entire transportation industry and current privacy legislation is not yet equipped to deal with the changes being spurred by this innovation. This paper enumerates and elucidates on the various privacy concerns that are specific autonomous vehicles. It also proposes the principles of “Privacy-by-Design”, an industry trend pertaining to other arenas of privacy, be adapted and used for regulating privacy around autonomous vehicles. It calls for the NHTSA (National Highway Transportation Safety Administration), with guidance from the FCC, and the FTC, to use their expertise in creating administrative rules that will protect the privacy of the public. Having learned valuable lessons from recent privacy concerns in the mobile device industry, the Privacy-by-Design approach would help ease the transition into this useful, but potentially intrusive technology. Currently, privacy is receiving significant attention in publications, but with autonomous vehicles being a nascent industry, there is very little being said about the privacy concerns specifically pertaining to these technology autonomous vehicles. Recent strides in the technology and the legislative acceptance of these vehicles have made them a widely discussed topic, and thus makes a thorough discussion of privacy related specifically to this technology both timely and relevant. This paper provides an early assessment of an area of concern that is growing as rapidly as are autonomous vehicles. The technology is being proven effective and safe, so the real focus will shift to use concerns, like privacy. The autonomous vehicle industry is still early in its development, and there is imminent opportunity to anchor privacy into the fundamentals of autonomous vehicles, preempting numerous potential infringements. 相似文献