Glucosinolates,glycosidically bound volatiles and antimicrobial activity of Aurinia sinuata (Brassicaceae)

Volatiles of Aurinia sinuata (L.) Griseb. were isolated from aerial parts and analysed by gas chromatography/gas chromatography–mass spectrometry (GC/GC–MS). The main compounds were glucosinolate degradation products originating from glucoberteroin, glucobrassicanapin and glucoalyssin. They were: 6-(methylthio)hexanenitrile (1.8–51.5%), 6-(methylsulfinyl)hexanenitrile (0–11.5%), 5-(methylsulfinyl)pentyl isothiocyanate (0–10.2%), 5-(methylthio)pentyl isothiocyanate (0.4–9.5%), 4-pentenyl isothiocyanate (0.7–8.9%), 5-hexenenitrile (2.6–14.6%) and 5,6-epithiohexanenitrile (0–3.4%). Also other volatiles were identified, such as fatty acids and esters (0.3–19.2%), phenols, phenylpropane derivatives and related compounds (0.4–15.8%), aliphatic alcohols and carbonyl compounds (4.2–11.6%) and some other compounds in smaller percentages.     

Impact of the wetting process on the hydro-mechanical behavior of unsaturated residual soil from flysch rock mass: preliminary results

Slope instabilities in the form of shallow and deep-seated landslides in flysch formations throughout Europe typically occur after prolonged periods of heavy rainfall. The Rječina River Valley, Croatia, is characterized by the presence of flysch material in the lower part of the Valley, where numerous historical and recent landslides have occurred. The weathering process and climate conditions result in a complex engineering geological profile of flysch slopes in the Valley, with unsaturated residual soil covering the slopes. To investigate the behavior of residual soil existing on the flysch slope under increasing water content due to the rainfall infiltration process, undisturbed soil samples collected at natural water content were tested in the modified direct shear apparatus. Under imposed stress conditions, samples of low hydraulic conductivity were subjected to a prolonged wetting process simulating the rainfall infiltration process in the field. The obtained results suggest that a gradual decrease of matric suction and an increase of water content resulted in an increase of displacement rates under constant shear stress, which was interpreted as a failure of samples in partially saturated conditions. A unique shear strength envelope expressed in terms of Bishop’s effective stress equation was found to be able to predict stress conditions at the slip surface at the time of failure, while the relationship between measured matric suction and water content closely matched with the main wetting curve. Although the testing results did not point out any special characteristics of residual soil from flysch rock mass behavior, the data about hydro-mechanical behavior of unsaturated residual soil from flysch rock mass, as well as similar fine-grained soils, are very rare and presented results would be valuable for further research. The presented testing procedure and obtained results are useful for studies of rainfall-induced landslides triggered in fine-grained soil materials in zones above the phreatic line, such as shallow landslides occurring in natural flysch slopes or in physical landslide models built in laboratories.

     

Diffractive optics at the surface of light-emitting/receiving semiconductor components

Abstract

Semiconductor components that emit or receive light can use diffractive surface structures to increase the functionality and reduce the number of additional optical components needed in the system. The diffractive structure couples the light out of, or into, the semiconductor material; it splits the light and directs it into one focus or several foci at any desired position. Further, the diffractive optics can be designed so that the function of the device is largely insensitive to the polarization of the light. In this survey, we briefly discuss design and fabrication issues, and show simulated and measured results, for a few different types of components.     

Frequency‐shifting‐based algebraic approach to stable on‐line parameter identification and state estimation of multirotor UAV

In this paper, a frequency‐shifting‐based (FSB) algebraic approach to stable on‐line parameter identification and state estimation is proposed. The proposed simultaneous parameter identification and state estimation algebraic approach are applied to multirotor adaptive‐like tracking control assuming that only position measurement is available. The proposed algebraic approach provides very fast convergence towards true values of system parameters and states, without transients that depend on initial conditions and without peaking phenomenon which is characteristics of high‐gain observers. The efficiency of the proposed algorithm is illustrated by a simulation example.     

Adsorbed Eutectic GaIn Structures on a Neoprene Foam for Stretchable MRI Coils

Stretchable conductors based on eutectic gallium–indium (eGaIn) alloy are patterned on a polychloroprene substrate (neoprene foam) using stencil printing. By tuning the amount of eGaIn on the neoprene substrate, different strain‐sensitivity of electrical resistance is achieved. Conductors with a layer of eGaIn, which adsorbs to the walls of 60–100 µm wide neoprene cells, change their electrical resistance for 5% at 100% strain. When the amount of eGaIn is increased, the cells are filled with eGaIn and the strain‐sensitivity of the electrical resistance rises to 300% at 100% strain. The developed conductors are patterned as stretchable on‐body coils for receiving magnetic signals in a clinical magnetic resonance imaging setup. First images with a stretchable coil are acquired on an orange and compared to the images that are recorded using a rigid copper coil of the same size.     

On-column sample enrichment for capillary electrophoresis sheathless electrospray ionization mass spectrometry: evaluation for peptide analysis and protein identification

Although several designs have been advanced for coupling sample enrichment devices to a sheathless electrospray ionization-mass spectrometry (MS) interface on a capillary electrophoresis (CE) column, most of these approaches suffer from difficulties in fabrication, and the CE separation efficiency is degraded as a result of the presence of coupling sleeves. We have developed a design that offers significant improvements in terms of ease of fabrication, durability, and maintenance of the integrity of the CE-separated analyte zones. Capillaries with different inside and outside diameters were evaluated to optimize the performance of the CE-MS system, resulting in a mass limit of detection of 500 amol for tandem MS analysis of a standard peptide using a 20-microm-i.d. capillary. The improved design incorporates an efficient method to preconcentrate a sample directly within the CE capillary followed by its electrophoretic separation and detection using a true zero dead-volume sheathless CE-MS interface. Testing of this novel CE-MS system showed its ability to characterize proteomic samples such as protein digests, in-gel-digested proteins, and hydrophobic peptides as well as to quantitate ICAT-labeled peptides.     

Brown rice proteins as delivery system of phenolic and volatile compounds of raspberry juice

Development of novel food ingredients with health benefits as well as desired sensory attributes is of great importance for food industry. For that purpose, complexes (BRP/R) between brown rice proteins (amounts varied; 2%, 6% and 10%) and raspberry juice were prepared. Obtained complexes were evaluated for the amount of volatile compounds, phenolic content, anthocyanin content and antioxidant activity. Those parameters depended on proteins amount. The highest adsorption of total phenolics and anthocyanins (18.18 mg g⁻¹ and 4.59 mg g⁻¹, respectively) was observed on complexes obtained with the lowest amount of proteins (2%). Regarding volatiles, dominant flavour note in raspberry juice was berry (40% of overall flavour), followed by citrus and woody notes (each around 18%), while dominant flavour note on complexes was citrus note (60%) followed by green note (15%). These results suggest an efficient plant-based approach to produce value-added protein-based complexes with possible utility as food colourant and flavouring.     

Retention of linalool and eugenol in hydrogels

Textural parameters of hydrogels prepared from hydrocolloids (guar gum or xanthan; 0.5 or 1% (w/w)) and disaccharides (sucrose and trehalose) were investigated after preparation and storage for 30 days. Volatile compounds (linalool or eugenol) were added to the hydrogels in order to investigate their behaviour in those systems and to determine whether there is correlation between textural parameters and their retention. Textural parameters that were evaluated were firmness, consistency, cohesiveness and index of viscosity. Regarding textural parameters, there was no significant difference between hydrogels prepared with 0.5% of hydrocolloids. With increase of the amount of added hydrocolloid, textural parameters increased and differences between sucrose- and trehalose-containing hydrogels were observed. Hydrogels prepared with trehalose had lower values of textural parameters. Correlation between texture and retention of volatile compounds was not observed or it was very low.     

The importance of air quality for underground spaces: An international survey of public attitudes

Space is a resource that is constantly being depleted, especially in mega-cities. Underground workspaces (UGS) are increasingly being included in urban plans and have emerged as an essential component of vertical cities. While progress had been made on the engineering aspects associated with the development of high-quality UGS, public attitudes toward UGS as work environments (ie, the public's design concerns with UGS) are relatively unknown. Here, we present the first large-scale study examining preferences and attitudes toward UGS, surveying close to 2000 participants from four cities in three continents (Singapore, Shanghai, London, and Montreal). Contrary to previous beliefs, air quality (and not lack of windows) is the major concern of prospective occupants. Windows, temperature, and lighting emerged as additional important building performance aspects for UGS. Early adopters (ie, individuals more willing to accept UGS and thus more likely to be the first occupants) across all cities prioritized air quality. Present results suggest that (perceived) air quality is a key building performance aspect for UGS that needs to be communicated to prospective occupants as this will improve their attitudes and views toward UGS. This study highlights the importance of indoor air quality for the public.