Retention of linalool and eugenol in hydrogels

Textural parameters of hydrogels prepared from hydrocolloids (guar gum or xanthan; 0.5 or 1% (w/w)) and disaccharides (sucrose and trehalose) were investigated after preparation and storage for 30 days. Volatile compounds (linalool or eugenol) were added to the hydrogels in order to investigate their behaviour in those systems and to determine whether there is correlation between textural parameters and their retention. Textural parameters that were evaluated were firmness, consistency, cohesiveness and index of viscosity. Regarding textural parameters, there was no significant difference between hydrogels prepared with 0.5% of hydrocolloids. With increase of the amount of added hydrocolloid, textural parameters increased and differences between sucrose- and trehalose-containing hydrogels were observed. Hydrogels prepared with trehalose had lower values of textural parameters. Correlation between texture and retention of volatile compounds was not observed or it was very low.     

The importance of air quality for underground spaces: An international survey of public attitudes

Space is a resource that is constantly being depleted, especially in mega-cities. Underground workspaces (UGS) are increasingly being included in urban plans and have emerged as an essential component of vertical cities. While progress had been made on the engineering aspects associated with the development of high-quality UGS, public attitudes toward UGS as work environments (ie, the public's design concerns with UGS) are relatively unknown. Here, we present the first large-scale study examining preferences and attitudes toward UGS, surveying close to 2000 participants from four cities in three continents (Singapore, Shanghai, London, and Montreal). Contrary to previous beliefs, air quality (and not lack of windows) is the major concern of prospective occupants. Windows, temperature, and lighting emerged as additional important building performance aspects for UGS. Early adopters (ie, individuals more willing to accept UGS and thus more likely to be the first occupants) across all cities prioritized air quality. Present results suggest that (perceived) air quality is a key building performance aspect for UGS that needs to be communicated to prospective occupants as this will improve their attitudes and views toward UGS. This study highlights the importance of indoor air quality for the public.     

Brown rice proteins as delivery system of phenolic and volatile compounds of raspberry juice

Development of novel food ingredients with health benefits as well as desired sensory attributes is of great importance for food industry. For that purpose, complexes (BRP/R) between brown rice proteins (amounts varied; 2%, 6% and 10%) and raspberry juice were prepared. Obtained complexes were evaluated for the amount of volatile compounds, phenolic content, anthocyanin content and antioxidant activity. Those parameters depended on proteins amount. The highest adsorption of total phenolics and anthocyanins (18.18 mg g⁻¹ and 4.59 mg g⁻¹, respectively) was observed on complexes obtained with the lowest amount of proteins (2%). Regarding volatiles, dominant flavour note in raspberry juice was berry (40% of overall flavour), followed by citrus and woody notes (each around 18%), while dominant flavour note on complexes was citrus note (60%) followed by green note (15%). These results suggest an efficient plant-based approach to produce value-added protein-based complexes with possible utility as food colourant and flavouring.     

Changes in macroelements,trace elements,heavy metal concentrations and chemical composition in milk of Croatian spotted goats during different lactation stages

The research was conducted on days 60, 90, 120 and 150 during the lactation with the aim to determine the effect of lactation stage on the concentration of crucial elements and chemical composition in Croatian spotted goats' milk. Milk yield significantly decreased (from 1.15 to 0.76 kg/day), while the concentration of Ca, Mg, P, Zn and Mo in the milk of the goats significantly increased during lactation. The concentrations of Cr, Cd and Pb in milk were very low, with no significant deviations during lactation. The quality of milk from Croatian spotted goats is adequate compared with other breeds in the surrounding area of Croatia.     

Sacred records in the landscape: the mirila of the Dalmatian hinterland

This paper discusses former burial rites which resulted in memorials known as mirila. It deals with the custom of marking a temporary resting-place while transporting a deceased person, which was prevalent in the north-eastern Adriatic hinterland, manifested in the erection of mortarless stone structures, the remains of which can still be found in the landscape. The paper considers the material and symbolic components of the cultural landscape through the phenomenon of mirila in the central parts of the Croatian Adriatic hinterland: Ravni Kotari and Bukovica. At the same time, given the complexity of natural and socio-political factors, an attempt is made to establish how the custom arose in the spatial and historical context of the region.     

Aseptic Processing of Sweetpotato Purees Using a Continuous Flow Microwave System

ABSTRACT: Sweetpotato purees (SPP) were aseptically processed using a continuous flow microwave system to obtain a shelf-stable product. The dielectric properties of SPP were measured, and the dielectric constant and loss factor were within the range of the published values for fruits and vegetables. Small-scale tests were conducted in a 5-kW microwave unit to determine changes in color and viscosity with different thermal treatments. The results of these tests showed that color values (L*, a*) and viscosity did not change significantly compared with the untreated control. Pilot-scale tests were then conducted in a 60-kW microwave unit where the product was heated to 135 °C and held at that temperature for 30 s. The pilot-scale test produced a shelf-stable product with no detectable microbial count during a 90-d storage period at room temperature. This is the 1st report of aseptically packaged vegetable puree processed by a continuous flow microwave heating system.     

Glucosinolates,glycosidically bound volatiles and antimicrobial activity of Aurinia sinuata (Brassicaceae)

Volatiles of Aurinia sinuata (L.) Griseb. were isolated from aerial parts and analysed by gas chromatography/gas chromatography–mass spectrometry (GC/GC–MS). The main compounds were glucosinolate degradation products originating from glucoberteroin, glucobrassicanapin and glucoalyssin. They were: 6-(methylthio)hexanenitrile (1.8–51.5%), 6-(methylsulfinyl)hexanenitrile (0–11.5%), 5-(methylsulfinyl)pentyl isothiocyanate (0–10.2%), 5-(methylthio)pentyl isothiocyanate (0.4–9.5%), 4-pentenyl isothiocyanate (0.7–8.9%), 5-hexenenitrile (2.6–14.6%) and 5,6-epithiohexanenitrile (0–3.4%). Also other volatiles were identified, such as fatty acids and esters (0.3–19.2%), phenols, phenylpropane derivatives and related compounds (0.4–15.8%), aliphatic alcohols and carbonyl compounds (4.2–11.6%) and some other compounds in smaller percentages.     

Impact of the wetting process on the hydro-mechanical behavior of unsaturated residual soil from flysch rock mass: preliminary results

Slope instabilities in the form of shallow and deep-seated landslides in flysch formations throughout Europe typically occur after prolonged periods of heavy rainfall. The Rječina River Valley, Croatia, is characterized by the presence of flysch material in the lower part of the Valley, where numerous historical and recent landslides have occurred. The weathering process and climate conditions result in a complex engineering geological profile of flysch slopes in the Valley, with unsaturated residual soil covering the slopes. To investigate the behavior of residual soil existing on the flysch slope under increasing water content due to the rainfall infiltration process, undisturbed soil samples collected at natural water content were tested in the modified direct shear apparatus. Under imposed stress conditions, samples of low hydraulic conductivity were subjected to a prolonged wetting process simulating the rainfall infiltration process in the field. The obtained results suggest that a gradual decrease of matric suction and an increase of water content resulted in an increase of displacement rates under constant shear stress, which was interpreted as a failure of samples in partially saturated conditions. A unique shear strength envelope expressed in terms of Bishop’s effective stress equation was found to be able to predict stress conditions at the slip surface at the time of failure, while the relationship between measured matric suction and water content closely matched with the main wetting curve. Although the testing results did not point out any special characteristics of residual soil from flysch rock mass behavior, the data about hydro-mechanical behavior of unsaturated residual soil from flysch rock mass, as well as similar fine-grained soils, are very rare and presented results would be valuable for further research. The presented testing procedure and obtained results are useful for studies of rainfall-induced landslides triggered in fine-grained soil materials in zones above the phreatic line, such as shallow landslides occurring in natural flysch slopes or in physical landslide models built in laboratories.