Analysis of regioisomers of triacylglycerols of northern currant seed oil by tandem mass spectrometry

Currant oils have special health properties due to their moderate contents of α‐linolenic, γ‐linolenic and stearidonic acids. The distribution of fatty acids (FA) in the triacylglycerols (TAG) may affect the beneficial effects. Seed oils of wild northern red currant (NRC) (Ribes spicatum L.) from Northern Finland and of wild alpine currant (AC) (R. alpinum L.) from the South‐West coast of Finland were investigated. The purified TAG were analysed by tandem mass spectrometry by applying the ammonia negative ion chemical ionisation – collision‐induced dissociation method. Molecular weight fractions rich in C18:3 FA and C18:4 FA were investigated. Of the total oil, the molecular weight species 54:7 (ACN:DB), 54:8 and 54:9 were more abundant in NRC than in AC, being 21.0%, 15.8%, 7.4% and 16.2%, 11.2%, 4.8%, respectively (p <0.05). The species 52:6 was more abundant in AC (3.1%) than in NRC (2.6%) (p <0.05). The preferential order of FA to be in the sn‐2 position in both berries was typically C18:1 > C18:2 > C18:4 > C18:3. No difference was observed between relative locations of C16:0 FA and C18:3 FA in either of the oils. Within the TAG consisting of FA combinations C18:3/C18:3/C18:1 (54:7), C18:1 was more preferentially in the sn‐2 position (p <0.05) in AC (93.2%) than in NRC (74.6%), and in the case of C18:3, the preference was vice versa. Within the molecular weight species 54:9, FA combination C18:4/C18:3/C18:2, linoleic acid preferentially occupied the secondary position (p <0.005) in both berries, and the proportion of the TAG regioisomer pair sn‐C18:3‐C18:4‐C18:2 + sn‐C18:2‐C18:4‐C18:3 was more abundant (30.2%) in NRC than in AC (15.3%). Within the TAG species 52:6, proportions of all the existing combinations, C16:0/C18:3/C18:3, C16:0/C18:4/C18:2 and C16:1/C18:3/C18:2, varied between the two berry species (p <0.005).     

A Novel Environment Characterization Metric for Clustered MIMO Channels

In this work we introduce a novel metric for characterizing the double-directional propagation environment and use this metric to assess the performance of a SAGE parameter estimator for MIMO channels. Using the IlmProp, a geometry-based MIMO channel modeling tool, we construct synthetic channels for three different scenarios showing: (i) well separated clusters containing dense propagation paths, and single-bounce scattering; (ii) partly overlapping clusters containing widely spread propagation paths, and single-bounce scattering; (iii) unclustered multipath components (“rich scattering”), and double-bounce-only scattering. We model the scatterers and the receiver in the environment as fixed, but the transmitter as moving. The Initialization and Search-Improved SAGE (ISIS) estimation tool is used to extract the propagation paths from the constructed channels. Both true and estimated paths are fed to the new system-independent metric which genuinely reflects the structure of the channel and the compactness of the propagation paths. We use this metric to decide on the accuracy of the channel estimator. The results show a convincing agreement between true and estimated paths.     

Near-Infrared Laser-Induced Decomposition of C60 Dissolved in Toluene

In this paper we describe the efficient and substantial decomposition of C₆₀ in toluene solution, induced by moderate intensity (I = 20 - 55 MW cm^-2) near infrared (γ = 1064 nm) laser radiation. This behavior is surprising since both uncharged fullerene and toluene do not have any absorption bands at this wavelength. The decomposition efficiency and products are investigated with UV-Vis absorption spectrophotometry and high-performance liquid-chromatography (HPLC). Possible mechanisms of the fullerene decomposition are discussed.     

Effect of curing process on simulated antisoiling properties of sol–gel coating on pine sapwood

Recently, inorganic–organic hybrid coatings produced by the sol–gel route have proven to be a potential protective treatment for wooden surfaces. In this study, the effect of curing process on simulated antisoiling properties of sol–gel coating was investigated. The sol–gel coating was spray-coated on pine sapwood and cured with different temperature and time combinations. The antisoiling properties were studied by measuring the water contact angle of the coating after different curing processes. In addition, abrasion resistance and contact angle of oleic acid were measured. An optical profilometer was used to investigate surface roughness of the coating. Sufficient hydro- and oleophobicity were obtained with all of the curing parameters. The comparison between curing parameters showed that lower temperature and 1–3 h curing time leads to significant improvement in the durability of the water and oil repellent properties of the coating.     

A qualitative H NMR study of CHCl3 adsorption on conjugated acid–base pairs in cation exchanged Y-zeolites

Solution state ¹H NMR is employed to study the mode and strength of chloroform adsorption on conjugated acid–base pairs of cation-exchanged Y-zeolites. ¹H NMR results indicate that two different surface bonding orientations may exist. An acidic hydrogen site of zeolite favours orientation where the chloroform hydrogen points towards the zeolite cage centre. An exchanged electropositive cation increases the basicity of framework oxygens of zeolite and directs the chloroform to adsorb on framework oxygens with a hydrogen bond. In this adsorption site the chemical shift of the chloroform hydrogen has a linear dependence on the electronegativity of the cation.     

Role of Bose enhancement in photoassociation

Abstract

We discuss the role of Bose enhancement of the dipole matrix element in photoassociation, using stimulated Raman adiabatic passage as an example. In a non-degenerate gas the time scale for coherent optical transients tends to infinity in the thermodynamic limit, whereas Bose enhancement keeps this time scale finite in a condensate. Coherent transients are therefore absent in photoassociation of a thermal non-degenerate gas, but are feasible if the gas is a condensate.     

Baltic Sea ice SAR segmentation and classification using modified pulse-coupled neural networks

A method for segmentation and classification of Baltic Sea ice synthetic aperture radar (SAR) images, based on pulse-coupled neural networks (PCNNs), is presented. Also, automated training, which is based on decomposing the total pixel value distribution into a mixture of class distributions, is presented and discussed. The algorithms have been trained and tested using logarithmic scale Radarsat-1 ScanSAR Wide mode images over the Baltic Sea ice. Before the decomposition into mixture of class distributions, an incidence angle correction, specifically designed for these Baltic Sea ice SAR images, is applied. Because the data distributions in the uniform areas of these images are very close to Gaussian distributions, the data are decomposed into a mixture of Gaussian distributions, using the Expectation-Maximazation algorithm. Only uniform image areas are used in the decomposition phase. The mixture of distributions is compared to the distributions of the Baltic Sea ice classes, based on earlier scatterometer measurements and visual video interpretations of the sea ice classes. The parameter values for the PCNN segmentation are defined based on this mixture of distributions. The PCNN segmentation results are also compared to the operational sea ice information of digitized ice charts and to visual interpretation of the sea ice class.     

Urban small area variation in adolescents' health behaviour

Our previous study indicated that region plays a relatively small role in adolescents' health behaviour. Here, the regional patterning of health behaviour is studied further by shifting the focus to small areas. First, we test whether small area socioeconomic, demographic and housing characteristics correlate with health behaviour. The analysis then turns to the relationship between these characteristics and their individual level correlates. We wish to ascertain if behaviour is related to small area characteristics similarly for both genders and for adolescents' socioeconomic characteristics. The Adolescent Health and Lifestyle Survey data from 1989-1995 (16- and 18-year-olds, n = 1048, response rate 71%) were linked with data describing 33 subareas of Helsinki, the capital of Finland. Smoking, alcohol use, abstention from dietary fat and physical activity were used as lifestyle indicators. Gender apparently influences the extent to which the area plays a role. Logistic regression demonstrated that prolonged unemployment predicted low prevalence of abstention from dietary fat (traditional dietary patterns) among girls and heavy drinking among boys. High total rate of unemployment predicted lower physical activity among girls. Also owner-occupied housing correlated positively with girls' physical activity. Although the individual level socioeconomic characteristics were not as strongly related to health behaviour as the small area factors, a low level of education predicted smoking and alcohol use and, among girls, decreased physical activity. We conclude that small area characteristics, especially the level of unemployment of the area, may be even more strongly related to health behaviour than individual socioeconomic characteristics.