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排序方式： 共有1113条查询结果，搜索用时 15 毫秒
101.
Julio C. Minotas Hocine Djellab Edward Ghali 《Journal of Applied Electrochemistry》1989,19(5):777-783
The anodic behaviour of three different copper electrodes in sulphuric acid medium was investigated using cyclic voltammetry in the potential range between the rest potentialE
i=0=–0.34 V and +0.80 V vs the Hg, Hg2SO4/K2SO4 saturated (MSE) reference electrode. Arsenic dissolved in the electrode matrix as well as oxygen dissolved in solution were found to delay passivation. The anodic peak current density was proportional to the square root of the potential sweep rate in two consecutive domains. An unusual break was observed for high scan rates (>50 m V s–1) and was attributed to an increase of the medium viscosity because of the large gradient of concentration near the electrode surface. On the other hand, current oscillations, usually observed in the anodic processes of metallic electrodes, have been studied as a function of the electrode vertical/horizontal positions. Gravity has been found to affect both the frequency and the amplitude of the oscillations. X-ray diffraction measurements conducted on galvanostatically electrolyzed samples revealed, besides copper metal, the presence of copper sulfate pentahydrate and trihydrate for Cu–As and Cu–Sb, respectively. SEM analysis showed the existence of preferential domains of white product on a darker background of metallic copper or copper oxides. 相似文献
102.
Fabiane Ferreira Martins Bruna Cadete Martins Ananda Vitoria Silva Teixeira Matheus Ajackson Vanessa Souza-Mello Julio Beltrame Daleprane 《Molecular nutrition & food research》2024,68(6):2300634
The discovery of metabolically active brown adipose tissue (BAT) in human adults and the worldwide increase in obesity and obesity-related chronic noncommunicable diseases (NCDs) has made BAT a therapeutic target in the last two decades. The potential of BAT to oxidize fatty acids rapidly and increase energy expenditure inversely correlates with adiposity, insulin and glucose resistance, and cardiovascular and metabolic diseases. Currently, BAT is recognized by a new molecular signature; several BAT-derived molecules that act positively on target tissues have been identified and collectively called batokines. Bioactive compounds present in foods are endowed with thermogenic properties that increase BAT activation signaling. Understanding the mechanisms that lead to BAT activation and the batokines secreted by it within the thermogenic state is fundamental for its recruitment and management of obesity and NCDs. This review contributes to recent updates on the morphophysiology of BAT, its endocrine role in obesity, and the main bioactive compounds present in foods involved in classical and nonclassical thermogenic pathways activation. 相似文献
103.
Meng Li Clara Seinsche Samuel Jansson Julio Hernandez Jadranka Rota Eric Warrant Mikkel Brydegaard 《Journal of the Royal Society Interface》2022,19(191)
There are hundreds of thousands of moth species with crucial ecological roles that are often obscured by their nocturnal lifestyles. The pigmentation and appearance of moths are dominated by cryptic diffuse shades of brown. In this study, 82 specimens representing 26 moth species were analysed using infrared polarimetric hyperspectral imaging in the range of 0.95–2.5 µm. Contrary to previous studies, we demonstrate that since infrared light does not resolve the surface roughness, wings appear glossy and specular at longer wavelengths. Such properties provide unique reflectance spectra between species. The reflectance of the majority of our species could be explained by comprehensive models, and a complete parametrization of the spectral, polarimetric and angular optical properties was reduced to just 11 parameters with physical units. These parameters are complementary and, compared with the within-species variation, were significantly distinct between species. Counterintuitively to the aperture-limited resolution criterion, we could deduce microscopic features along the surface from their infrared properties. These features were confirmed by electron microscopy. Finally, we show how our findings could greatly enhance opportunities for remote identification of free-flying moth species, and we hypothesize that such flat specular wing targets could be expected to be sensed over considerable distances. 相似文献
104.
Supply chain networks need to respond efficiently to operation disruptions, as one of their aims is to guarantee the on time delivery of products. Hence, robustness has become one of the important issues to consider when designing supply networks. There are alternative ways to measure what robustness means in this context. In this paper, we propose a new metric based on the effect on service level of the collapse of active transportation links. Numerical experiments are carried out to understand how different design factors affect robustness. Robustness under a targeted attack is compared with robustness to random failures. Results show that flow complexity (i.e. the number of potential transportation links between supply network nodes) is the most influential factor affecting supply network and its robustness, as well as the service level that can be maintained after disruptions. Thus, diversification both in supply sources and transportation routes seems to be key to robustness. 相似文献
105.
The mechanical reinforcement of nanocomposites containing nanorods‐like fillers such as cellulose nanocrystals (CNCs) is often interpreted by adapting the classical parallel–series model, assuming a simple hyperbolic dependence between the percolation threshold and aspect ratio. However, such assumptions are valid only for nanorods with high aspect ratio and often are misinterpreting the reinforcement obtained at low volume fraction of filler loading. To elucidate this intriguing scenario, we proposed a new approach and validated it by compiling and reinterpreting some of available literature that represent the experimental reinforcement with CNCs. Our approach showed better accuracy, specifically for the cases of CNC nanorods with lower aspect ratio. We conclude that this route permits a more realistic evaluation of the mechanical reinforcement, where a physical parameter accounting the polymer filler association is introduced. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45254. 相似文献
106.
107.
108.
Pablo Ares Hernán Santos Snežana Lazić Carlos Gibaja Iñigo Torres Sergio Pinilla Julio Gómez-Herrero Herko P. van der Meulen Pablo García-González Félix Zamora 《Advanced Electronic Materials》2021,7(7):2001177
Hexagonal boron nitride (hBN) has attracted a lot of attention in the past years, thanks to its many remarkable properties. These include the presence of single-photon emitters with superior optical properties, which make it an ideal candidate for a plethora of photonic technologies. However, despite the large number of experimental results and theoretical calculations, the structure of the defects responsible for the observed emission is still under debate. In this work, individual atomic-scale defects in hBN with atomic force microscopy under ambient conditions are visualized and multiple narrow emission lines from optically stable emitters are observed. This direct observation of the structure of the defects combined with density functional theory calculations of their band structures and electronic properties allows associating the existence of several single-photon transitions to the observed defects. The work sheds light on the origin of single-photon emission in hBN that is important for the understanding and tunability of high-quality emitters in optoelectronics and quantum technologies. 相似文献
109.
This paper presents a novel method for computing the multi-objective problem in the case of a metric state space using the Manhattan distance. The problem is restricted to a class of ergodic controllable finite Markov chains. This optimization approach is developed for converging to an optimal solution that corresponds to a strong Pareto optimal point in the Pareto front. The method consists of a two-step iterated procedure: (a) the first step consists on an approximation to a strong Pareto optimal point and, (b) the second step is a refinement of the previous approximation. We formulate the problem adding the Tikhonov's regularization method to ensure the convergence of the cost-functions to a unique strong point into the Pareto front. We prove that there exists an optimal solution that is a strong Pareto optimal solution and it is the closest solution to the utopian point of the Pareto front. The proposed solution is validated theoretically and by a numerical example considering the vehicle routing planning problem. 相似文献
110.
Zhekai Deng Paul B. Umbanhowar Julio M. Ottino Richard M. Lueptow 《American Institute of Chemical Engineers》2019,65(3):882-893
Predicting segregation and mixing of polydisperse granular materials in industrial processes remains a challenging problem. Here, we extend the application of a general predictive continuum model that captures the effects of segregation, diffusion, and advection in two ways. First, we consider polydisperse segregating flow in developing steady segregation and in developing unsteady segregation. In both cases, several terms in the model that were zero in the previously examined case of fully developed streamwise-periodic steady segregation in a chute are now non-zero, which makes application of the model substantially more challenging. Second, we apply the polydisperse approach to density polydisperse materials with the same particle size. Predictions of the model agree quantitatively with experimentally validated discrete element method (DEM) simulations of both size polydisperse and density polydisperse mixtures having uniform, triangular, and log-normal distributions. © 2018 American Institute of Chemical Engineers AIChE J, 65: 882–893, 2019 相似文献