Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006     

冷41-平14"L"型水平井轨迹优化与控制技术

冷41-平14井受地面条件的限制,靶前位移小,为保证中间套管和完井管柱的顺利下入,剖面设计为“反向造斜-稳斜-降斜-正向造斜-水平段”的“L”型。简要介绍了冷41-平14“L”型水平井的设计概况,详细介绍了该井井眼轨道优化设计原则和设计结果,以及实钻井眼轨迹连续控制技术。该井精确命中A、B靶,两靶处的井斜角、方位角和垂深等达到了设计要求,在A靶实现了软着陆。该井井眼轨道优化设计和井眼轨迹控制技术为类似水平井的井眼轨道设计和轨迹控制提供了有益的借鉴。     

彩色等离子体显示屏中运动失真现象的研究

本文研究了等离子体显示屏在显示动态的画面时产生运动失真现象的原因，并在比较国内外各种解决方法的基础上提出了一种优化的ADS驱动方式。在优化的ADS驱动方式基础上开发的14时彩色等离子体原型样机表明优化的ADS驱动方式在视觉闪烁感和运动图像质量方面都有了很大的提高。     

Selective oxidation of alcohols using octahedral molecular sieves: influence of synthesis method and property–activity relations

Manganese oxides having a tunnel structure (OMS-2) have been utilized as selective catalysts for alcohol oxidation. In this study manganese oxide catalysts were synthesized in different media and modified by exchanging the tunnel cation by H⁺, using acid treatment or exchanging with NH₄⁺ followed by thermolysis. Various alcohol oxidations were performed using these catalysts to ascertain the influence of synthesis method on their activity. A correlation is made between lattice oxygen instability and activity of the catalysts, which indicates involvement of the lattice oxygen in the mechanism. The exchange of the tunnel cation with the smaller H⁺ ions leads to weakening of the Mn–O bond, as verified by temperature programmed desorption (TPD) results. Only the chemisorbed oxygen on the surface (O⁻) and the lattice oxygen in the layers close to the surface is involved in the oxygen transfer during the reaction.     

大庆油田助剂厂3500kt／a常减压减压塔的管道设计

简述了大庆油田助剂厂3500kt/a常减压减压塔的管道布置设计特点,体现出塔类设备的管道设计原则,并结合管道设计的经济性、安全性展开论述。     

立式旋风锅炉的燃烧自适应控制

分析了立式旋风锅炉的燃烧特点和燃烧系统动态特性，讨论了它的软硬件构成及其功能。     

基于子结构法的升船机主传动系统的动力学建模

用动态子结构法对三峡升船机的主传动系统建立动力学模型。把整个系统分为8个一级子系统,每个一级子系统又分为4个二级子系统,建立每个二级子系统的动力学模型,利用边界条件,层层组装,最后组合成完整的动力学方程。     

环缝洗涤工艺在本钢高炉煤气除尘中的应用

阐述了PW公司高炉煤气环缝洗涤工艺,介绍了技术、设备和备件的引进范围,简述了生产中遇到的问题,探讨了解决办法和今后新建项目应注意的问题.     

基于LonWorks和DSPs的智能节点

本文提出了一种基于LonWorks和DSPs的智能节点设计方案，并给出了具体的实现方法。该方案简单、可靠，充分利用了LonWorks强大的网络性、可靠性和DSPs强大的数据处理能力，大大提升了节点的智能化程度。     

丙烯酸酯与甲基丙烯酸酯的共聚及性能研究

采用悬浮聚合法，以丙烯酸－２－乙基－己酯与甲基丙烯酸十二酯为单体，合成了共聚型高吸油性树脂。研究了共聚单体的配比、交联剂用量、引发剂用量诸因素对高吸油性树脂的性能影响。制得的树脂可以吸其自身质量的１１．８倍的煤油、１４．７倍的苯、６．５倍的泵油。