High‐Tg Carbazole Derivatives as Blue‐Emitting Hole‐Transporting Materials for Electroluminescent Devices

A series of dicarbazolyl derivatives bridged by various aromatic spacers and decorated with peripheral diarylamines were synthesized using Ullmann and Pd‐catalyzed C–N coupling procedures. These derivatives emit blue light in solution. In general, they possess high glass‐transition temperatures (T_g > 125 °C) which vary with the bridging segment and methyl substitution on the peripheral amine. Double‐layer organic light‐emitting devices were successfully fabricated using these molecules as hole‐transporting and emitting materials. Devices of the configuration ITO/HTL/TPBI/Mg:Ag (ITO: indium tin oxide; HTL: hole‐transporting layer; TPBI: 1,3,5‐tris(N‐phenylbenzimidazol‐2‐yl)benzene) display blue emission from the HTL layer. The EL spectra of these devices appear slightly distorted due to the exciplex formation at the interfaces. However, for the devices of the configuration ITO/HTL/Alq₃/Mg:Ag (Alq₃ = tris(8‐hydroxyquinoline)aluminum) a bright green light from the Alq₃ layer was observed. This clearly demonstrates the facile hole‐transporting property of the materials described here.     

Flaw density examinations of a clad boiling water reactor pressure vessel segment

As part of the Oak Ridge National Laboratory's Heavy-Section Steel Technology Program, studies have been conducted to determine flaw density in a section of reactor pressure vessel cut from the Hope Creek Unit 2 vessel. This boiling water reactor vessel was never in service. One objective was to evaluate the approximate 0.7- by 3-m (2- by 10-ft) segment of the vessel provided using ultrasonic flaw detection methods performed with both ASME Code techniques and supplemental ultrasonic methods. A second objective was to evaluate the inner surface stainless steel cladding for cracks with a high sensitivity penetrant examination. Both objectives were successfully completed. Five Code-recordable indications were detected ultrasonically; however, all were found to be anomalies associated with the cladding. One flaw was detected by the supplemental ultrasonic tests, and it was analyzed destructively. This flaw was pipelike indication, about 20 mm (0.8 in.) long extending along the length of the longitudinal weld in which it was located and was about 20 mm below the cladding surface. The flaw had a through-wall dimension (or length) of about 6 mm (0.24 in.) for an approximate 3-mm (0.1-in.) distance along the 20-mm major length. No flaws were detected by the penetrant examination of the cladding surface.     

Architectures for Silicon Nanoelectronics and Beyond

Although nanoelectronics won't replace CMOS for some time, research is needed now to develop the architectures, methods, and tools to maximally leverage nanoscale devices and terascale capacity. Addressing the complementary architectural and system issues involved requires greater collaboration at all levels. The effective use of nanotechnology calls for total system solutions     

A probe for making near-field measurements with minimaldisturbance: the optically modulated scatterer

We describe an optically modulated scatterer as an electric-field probe for measuring radio-frequency and microwave fields. It has a high spatial resolution and the ability to operate very close to conducting and dielectric objects without appreciable distortion of the field to be measured. Thus, it can scan close to antennas and diffracting metal structures. We describe how the electric field is deduced from the measurements and present gain measurements and far-field patterns deduced from near-field scans of antennas. The results are tested by comparing them with those obtained by established measurement techniques     

On system design

The general, multiple attribute system design problem is formulated in total quality space which includes all of the microeconomic factors that influence the net value of a product to society. A hypothetical system design task—the development of improved system specifications and new subsystem requirements for the redesign of an automobile—is used to illustrate the approach. A new format is also given for describing design of experiment arrays which facilitates their use in spreadsheet calculations.     

Complexity theory of parallel time and hardware

The parallel resources time and hardware and the complexity classes defined by them are studied using the aggregate model. The equivalence of complexity classes defined by sequential space and uniform aggregate hardware is established. Aggregate time is related to (bounded fanin) circuit depth and, similarly, aggregate hardware is related to circuit width. Interelationships between aggregate time and hardware follow as corollaries. Aggregate time is related to the sequential resource reversal. Simultaneous relationships from aggregate hardware and time to sequential space and reversal are shown (and conversely), and these are used as evidence for an “extended parallel computation thesis.” These simultaneous relationships provide new characterizations for the simultaneous parallel complexity class NC and for the complementary class SC. The evaluation of monotone planar circuits is shown to be in NC, in fact in LOGCFL.     

Vascular rejection post heart transplantation is associated with positive flow cytometric cross-matching

28 isolates of canine parvovirus type-2 (CPV-2) were obtained from dogs with hemorrhagic gastroenteritis in Italy. The antigenic structure of CPV-2 isolates was characterized, using four discriminating monoclonal antibodies. In addition, four vaccinal strains were examined. Similar to reports from Australia and the United Kingdom, a much higher prevalence of CPV-2a (25/28 isolates) was observed than the other variant type, CPV-2b (3/28 isolates). DNA fragments (2.2 kbp) of representative strains of CPV-2, CPV-2a and CPV-2b were amplified by the polymerase chain reaction (PCR) and the products were digested by the restriction enzymes (RE) RsaI, HpaII, HindIII and PvuII. The RvaI enzyme allows the differentiation of CPV-2 from CPV-2a and CPV-2b.     

A brief review of the ionic conductivity enhancement for selected oxide electrolytes

The advantages of lowering the operation temperature of SOFCs have attracted great interest worldwide. One of the major barriers to decreasing the operation temperature is the ohmic loss of the electrolyte. Maximizing the electrolyte ionic conductivity is of significant importance, especially in the absence of new electrolyte materials. The ionic conductivity of electrolytes can be influenced by many parameters. There has been an enormous effort in the literature for the improvement of the electrolyte ionic conductivity. From a practical point of view, this paper reviews various approaches to enhancing the ionic conductivity of polycrystalline zirconia- and ceria-based oxide electrolytes in the light of composition, microstructure, and processing. Suggestions are given for future work.