High Temperature Oxidation Behavior of Conventional and Nb-Modified MAR-M246 Ni-Based Superalloy

The present investigations focused on the thermal oxidation of two variants of MAR-M246 alloy having the same contents of Ta and Nb in at. pct, considering the effects of total replacement of Ta by Nb. The alloys were produced by investment casting using high purity elements in induction furnace under vacuum atmosphere. The alloys were oxidized pseudo-isothermally at 800 °C, 900 °C and 1000 °C up to 1000 hours under lab air. Protective oxidation products growing on the surface of the oxidized samples were mainly Al₂O₃, Cr₂O₃. Other less protective oxide such as spinels (NiCr₂O₄ and CoCr₂O₄) and TiO₂ were also detected as oxidation products. The conventional alloy exhibited slight internal oxidation at 800 °C and an enhanced resistance at 900 °C and 1000 °C. The Nb-modified alloy presented an exacerbated internal oxidation and nitridation at 900 °C and 1000 °C and an enhanced resistance at 800 °C. At 1000 °C, Nb-modified alloy was particularly affected by excessive spalling as the main damage mechanisms. From a kinetic point of view, both alloys exhibit the same behavior at 800 °C and 900 °C, with k_p values typical of alumina forming alloys (2 × 10⁻¹⁴ to 3.6 × 10⁻¹³ g² cm⁻⁴ s⁻¹). However, Ta modified alloys exhibited superior oxidation resistance at 1000 °C when compared to the Nb modified alloy due to better adherence of the protective oxide scale.

     

Effect of Thermomechanical Fatigue on Precipitation Microstructure in Two Precipitation-Hardened Cast Aluminum Alloys

Thermal loading induces modifications of the precipitation microstructure of Al–Si–Cu–Mg alloys. This study focuses on the effect of deformation on precipitation microstructure during thermomechanical loadings. Several specimens were thermomechanically cycled while others were exposed to the same thermal cycles without any mechanical loading. The nature and morphological characteristics of the precipitation microstructure of the thermomechanically cycled specimens are compared to those of the thermally aged ones, using transmission electron microscopy (TEM), in order to assess the effect of deformation on the precipitation microstructure and especially on the kinetics of precipitate growth. The absence of any significant effect of superimposed straining during thermal cycling is discussed. Implications for the prevision of yield strength degradation during service operation are briefly presented.

     

Substrate Stimulated Orientation for Pure Aluminum

Oriented materials are of great importance, but their formation is rarely described. Here, nine Al/Al₂O₃ systems were designed to identify the dominant factors. Electron back-scattered diffraction indicates that the new Al crystal(s) with one or multiple orientation(s) can be stimulated by one single-crystal Al₂O₃ substrates. Synchrotron radiation diffraction shows that the preferred orientation(s) is/are determined based on the initial stage of the liquid–solid transition. The nonpreferred orientation can be suppressed through competition.

     

Buckling-Induced Delamination of TiN Film on Stainless Steel in the Presence of Stress Concentration

TiN coating is provided by reactive magnetron coating on a 304 stainless steel sample with a notch introduced at the edge of the sample. The sample is subjected to a tensile stress close to that of yield strength of the stainless steel. Optical and scanning electron microscopy characterization showed the distribution of buckled and delaminated regions around the notch. The distribution of the size of the partially delaminated regions of the film on the substrate is determined by transient thermo-reflectance. The stress field due to the notch is represented by that of a circular hole present at the tip and the variation of compressive and shear strain as a function of radial and angular coordinates is determined. The distribution of buckled and delaminated regions is found to follow the compressive strain variation around the notch. The size of the partially delaminated film is found to be larger near the notch and decreased with distance from the notch. The results illustrate that structures with regions of stress concentration should not be provided with brittle protective coatings that will delaminate.

     

Microstructural Features of Low-Alloy Pipeline Steels that Determine Impact Strength of Welded Joint Heat-Affected Zone

Metallurgist - Microstructural mechanisms reducing the impact strength values of a coarse grained heat-affected zone are studied for two K60 microalloyed steels. Research is conducted on specimens...     

Plastic Deformation Resistance of Steel Grades EP450-Sh and EP823-Sh in Hot and Cold State

Metallurgist - The article presents the results of plastometric studies on hot deformation and studies on the hardening curves in cold deformation of EP450-Sh (12H12M1BFR-Sh) and EP823-Sh...     

Cerium Effect on the Phase Composition and Crystallization Behavior of Aluminum Casting Alloys Based on the Al–Mg–Si System

Russian Journal of Non-Ferrous Metals - Using a Thermo-Calc software package (TCAl4.0 database), unexplored data concerning the phase composition and crystallization behavior of...     

Ensuring Strength in Laser Welds Made Using the Dispersion-Hardened EP693 Nickel Alloy

Russian Journal of Non-Ferrous Metals - The process of making a weld using the heat-resistant EP693 alloy (Ni–Cr–W–Co–Co–Mo system) to make assemblies and components...     

Grain Refinement of Casting Aluminum Alloys of the Al–Mg–Si System by Processing the Liquid Phase Using Nanosecond Electromagnetic Pulses

Russian Journal of Non-Ferrous Metals - In this paper, using the AA 511 alloy of the Al–Mg–Si system as an example, it is shown that the irradiation of aluminum melts with nanosecond...     

Production of Powdered α-Fe2O3 with Multilevel Gradient Porosity

Russian Journal of Non-Ferrous Metals - This article discusses methods for producing a material with gradient multilevel porosity by sintering layer-by-layer distributed α-Fe2O3 nanopowders...