A Silicon–Silica Nanocomposite Material

The synthesis and characterization of a novel silicon–silica nanocomposite material are reported. A self‐assembly method allows the encapsulation of silicon nanoclusters within the channels of a periodic mesoporous silica thin film. The result is the formation of a silicon–silica nanocomposite film with bright, room‐temperature photoluminescence in the visible range, and a nanosecond luminescence lifetime. The properties of the nanocomposite material have been studied by several analytical techniques, which collectively show the existence within the channels of non‐diamondoid‐structure‐type silicon nanoclusters with various hydrogenated silicon sites. It is estimated that the silicon nanoclusters in the silica mesoporous films occupy up to 39 % of the accessible pore volume. The nanocomposite film shows improved resistance to air oxidation compared to crystalline silicon. The high loading and chemical stability to oxidation under ambient conditions are important advantages in terms of the development of silicon‐based light‐emitting diodes from this class of materials.     

反坦克导弹分布交互式训练仿真平台设计

文中阐述了反坦克导弹分布交互式训练仿真平台的设计与实现,概述了系统研制中一些主要环节的设计要点及实现方法.     

电磁性材质检测系统智能化的研究

在原有的检测系统的基础上加上一个由单片机为中心及外部器件构成的智能化电磁性材质检测系统,使得该系统的功能增强.过去需要人工控制的过程,变为由单片机为主的智能过程,该系统采用新的分选方法和算法,能自动控制仪器的工作流程、测试判断材质微小的差别、数据记录、数据输出以及能完成电磁性材料的混频分选、硬度分选、热处理状态分选等功能,具有较大的应用价值.     

Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

会计信息失真现象的博弈分析

在对现实进行合理假定的基础上建立了会计信息失真现象的有限完美信息动态博弈模型，并利用后退归纳法找到了五个满足不同条件的纳什均衡解。通过对均衡条件的分析，找出了导致会计信息失真的治理结构原因和法律制度因素，并提出了建设性的解决措施。     

Rheology of concentrated solutions of hyperbranched polyesters

The solution rheology of different generations of hyperbranched polyesters in N‐methyl‐2‐pyrrolidinone (NMP) solvent was examined in this study. The solutions exhibited Newtonian behavior over a wide range of polyester concentrations. Also, the relative viscosities of poly(amidoamine) (PAMAM) dendrimers in ethylenediamine were compared with those of the hyperbranched polyesters in NMP. Both types of dendritic polymers have relative viscosities that are exponential functions of their molar fraction in solution. The slopes of these relative viscosity curves show a linear relationship with respect to the generation number. PAMAM dendrimers have the greater slopes for each generation, reflecting their relatively larger intrinsic viscosity values.     

单源点法的一种改进

在应用能量线性叠加计算港内不规则波绕射系数时^[1,2]，通过假设不同的计算点具有不同的方向谱，从而增加单源点法考虑地形变化的能力。其中各计算点的方向谱由逆波向线追踪方向确定。本文由此观点建立数学模型。并通过实例计算。来验证这个想法。     

复合材料压缩破坏模式的缺陷敏感性

本文基于弹塑性分叉理论研究单向纤维增强复合材料的压缩破坏模式和压缩强度对缺陷的敏感性问题。对于常见复合材料,所得结论是:无缺陷或者小缺陷情况的破坏模式为倾斜破坏带;大缺陷情况的破坏模式为水平破坏带;形成水平破坏带的压力值小于形成倾斜破坏带的压力。     

被动式活性炭氡采样器扩散控制管设计参数的选择

本文介绍被动式活性炭氡采样器扩散控制管设计参数的选择方法。通过对活性炭吸附氡量与暴露时间的关系式的线性化处理,选择了适当的扩散控制管的参数,可以大大减小温度对测量结果的影响,同时可保持探测器有较高的灵敏度。