Effect of Surface Morphology on Crack Growth at a Sol-Gel Reinforced Epoxy/Aluminum Interface

The Boeing sol-gel conversion coating (Boegel-EPII), derived from an acid-catalyzed aqueous solution of organofunctional silane and zirconium alkoxide precursors, is being used as an adhesion promoter for adhesive bonding and painting applications in the aerospace industry. A unique advantage of the sol-gel process is that strong and durable bonds are produced without the hazardous chemical usage and rinse-water requirements of conventional anodizing or etching processes. In this study, a fracture mechanics method was used to investigate the adhesion properties of sol-gel-reinforced epoxy/aluminum joints. The Hugh Brown asymmetric double cantilever beam (ADCB) wedge test was employed, which allowed the measurements of the critical energy-release rate, subcritical crack-growth kinetics, and threshold energy-release rate on a single sample in a reasonably short period of time. These experiments were carried out with aluminum substrates on which the surface morphology was systematically varied by polishing, sanding, grit-blasting, and chemical etching. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were used to identify the locus of failure. The surface morphology of the substrates was characterized with SEM, optical profilometry, and spreading kinetics. The macrorough structures drive the crack to within a thin epoxy layer close to the polymer/metal interface, which enhances the initial strength of the sol-gel-reinforced interface. The microroughness of the substrate is, however, more effective than the macroroughness in enhancing the durability. Lastly, an attempt has been made to correlate the energy-release rate with the fractal dimension for sol-gel-reinforced joints with macrorough substrates.     

Water sorption of poly(vinyl alcohol)/ poly(diallyldimethylammonium chloride) interpenetrating polymer network hydrogels

Temperature‐responsive interpenetrating polymer network (IPN) hydrogels constructed with poly(vinyl alcohol) and poly(diallyldimethylammonium chloride) using the sequential IPN method were studied. The characteristics of IPN hydrogels were investigated using the dynamic vapor sorption system. IPN hydrogels exhibited a relatively high sorption ratio, 180–360% at room temperature. The sorption ratio of hydrogels depended on temperature. Diffusion coefficients were calculated according to the Fickian Law at several temperatures. The apparent activation energy was 5.43 kJ mol^?1, which corresponds to typical diffusion processes. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1389–1392, 2003     

The characteristics of carbon nanotube‐reinforced poly(phenylene sulfide) nanocomposites

Multiwall carbon nanotube reinforced poly (phenylene sulfide) (PPS) nanocomposites were successfully fabricated through melt compounding. Structural, electrical, thermal, rheological, and mechanical properties of the nanocomposites were systematically studied as a function of carbon nanotube (CNT) fraction. Electrical conductivity of the polymer was dramatically enhanced at low loading level of the nanotubes; the electrical percolation threshold lay between 1 and 2 wt % of the CNTs. Rheological properties of the PPS nanocomposites also showed a sudden change with the CNT fraction; the percolation threshold was in the range of 0–0.5 wt % of CNTs. The difference in electrical and rheological percolation threshold was mainly due to the different requirements needed in the carbon nanotube network in different stages. The crystallization and melting behavior of CNT‐filled PPS nanocomposites were studied with differential scanning calorimetry; no new crystalline form of PPS was observed in the nanocomposites, but the crystallization rate was reduced. The thermal and mechanical properties of the nanocomposites were also investigated, and both of them showed significant increase with CNT fraction. For 5 wt % of CNT‐filled PPS composite, the onset of degradation temperature increased by about 13.5°C, the modulus increased by about 33%, and tensile strength increased by about 172%. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Local-scale analysis of carbon mitigation strategies: Tompkins County,New York,USA

The costs and potential for several carbon mitigation options were analyzed for Tompkins County, NY, within several categories: terrestrial carbon sequestration, local power generation, transportation, and energy end-use efficiency. The total county emissions are about 340 Gg C/year, with current biomass sequestration rates of about 121 Gg C/year. The potential for mitigation with the options examined, assuming full market penetration, amounts to at least 234 Gg C/year (69%), with 100 Gg C/year (29%) at no net cost to the consumer. Effective carbon mitigation strategies for this county based on costs per mg carbon and maximum potential include reforestation of abandoned agricultural lands for terrestrial carbon sequestration, biomass production for residential heating and co-firing in coal power plants, changes in personal behavior related to transportation (e.g., carpooling or using public transportation), installation of numerous residential energy-efficient products and development of local wind power. The principal barriers to the implementation of these approaches are discussed and policies for overcoming these barriers are analyzed.     

Small-scale lacustrine drifts in Lake Champlain,Vermont

High resolution CHIRP (Compressed High Intensity Radar Pulse) seismic profiles reveal the presence of two lacustrine sediment drifts located in Lake Champlain's Juniper Deep. Both drifts are positive features composed of highly laminated sediments. Drift B sits on a basement high while Drift A is built on a trough-filling acoustically-transparent sediment unit inferred to be a mass-transport event. These drifts are oriented approximately north–south and are parallel to a steep ridge along the eastern shore of the basin. Drift A, located at the bottom of a structural trough, is classified as a confined, elongate drift that transitions northward to become a system of upslope asymmetric mudwaves. Drift B is perched atop a structural high to the west of Drift A and is classified as a detached elongate drift. Bottom current depositional control was investigated using Acoustic Doppler Current Profilers (ADCPs) located across Drift A. Sediment cores were taken at the crest and at the edges of the Drift A and were dated. Drift source, deposition, and evolution show that these drifts are formed by a water column shear with the highest deposition occurring along its crest and western flank and began developing circa 8700–8800 year BP.     

The dependence of natural graphite anode performance on electrode density

The effect of electrode density for lithium intercalation and irreversible capacity loss on the natural graphite anode in lithium ion batteries was studied by electrochemical methods. Both the first-cycle reversible and irreversible capacities of the natural graphite anode decreased with an increase in the anode density though compression. The reduction in reversible capacity was attributed to a reduction in the chemical diffusion coefficient for lithium through partially agglomerated particles with a larger stress. For the natural graphite in this study the potentials for Li (de)insertion shifted between the first and second formation cycles and the extent of this shift was dependent on electrode density. The relation between this peak shift and the irreversible capacity loss is probably due to the decrease in graphite surface area with compression.     

A pilot study of the efficacy of residuum lodges for managing sediment delivery to impoundment reservoirs

Residuum lodges comprise small dams constructed on feeder streams immediately before they enter a reservoir, behind which ponds form, where sediment is deposited. Despite their construction on many impoundment reservoirs (IRE) and catchwaters, little research has previously investigated their efficacy at removing sediments from feeder streams. The current pilot study has, therefore, been carried out at an IRE supplying Halifax, West Yorkshire, UK, where a residuum lodge was recently cleaned out. Sediment concentrations reaching the reservoir were reduced by up to 42% although no certain impacts were noted on the other water quality variables that were measured. Moreover, it was found that the clearance operation did not result in the release of excessive quantities of sediment into the reservoir. It was estimated that the cleared residuum lodge would take 12 years to refill. A survey of other residuum lodges in the Yorkshire region showed there to be considerable differences in their remaining capacities.     

Do natural amenities influence undergraduate student migration decisions?

The primary objective of this paper is to examine the influence of natural amenities on student migration decisions using institution-level data from the National Center for Education Statistics’ Integrated Postsecondary Education Data System. We surpass the scope of previous studies focused on natural amenities, which rely on a limited selection of state-level measures, by matching interpolated weather station- and county-level climate data to each post-secondary institution. Results suggest that students consider natural amenities in their migration to college decision and, in a number of cases, preferences for natural amenities vary based on origin state amenity conditions. Nonetheless, migration decisions are dominated by origin state educational opportunities and by proximity of the student’s origin state to the state of college attendance.