Separation of nickel from copper in ammoniacal/ammonium carbonate solution using ACORGA M5640 by selective stripping

Separation of nickel from copper in ammoniacal/ammonium carbonate solution using ACORGA M5640 by selective stripping was carried out. The influence of equilibration time, equilibrium pH and extractant concentration on the extraction of both the metals was studied. It was found that the copper extraction equilibrium was reached in a shorter time than the nickel extraction equilibrium. Nickel extraction decreases above an equilibrium pH of 9.0, while the extraction of copper remains unaffected by the changes in the equilibrium pH range of 7–10. Co-extraction, ammonia scrubbing and the selective stripping of copper and nickel were performed for a solution containing 3 g/l each of copper and nickel and 60 g/l ammonium carbonate. The extraction and the percentage stripping of copper and nickel were almost quantitative.     

Relationship between normal load and dynamic co-efficient of friction on rock-rubber wear mechanism

In this study, rubber compounds were produced in varying proportions of carboxylated acrylonitrile butadiene rubber (XNBR) and natural rubber (NR) and the parameters such as cure characteristics, wear behavior against various surfaces at different normal loads, and frictional works were tested. The tensile strength and dynamic co-efficient of friction of sample containing 80 wt.% of XNBR was high compared to other samples by 2% and 10% respectively. The results of XNBR and NR vulcanizates under normal pressure ranging from 43 to 118 kPa were reported. Based on these results the relationship between normal load and dynamic co-efficient of friction has been proposed. It was also observed that sample containing 80 wt.% of XNBR exhibits lesser volume loss than compared to other samples.     

Strombus gigas inspired biomimetic ceramic composites via SHELL—Sequential Hierarchical Engineered Layer Lamination

Nature has produced remarkable structural designs based on many millennia of evolutionary optimization. Biological materials, such as the sea-shell, possess unique microstructures and properties that provide inspiration for the next generation of structural ceramics. Strombus gigas (Queen conch) shells contain a hierarchical, multilayered, crossed-lamellar architecture built with two natural materials (calcium carbonate and protein) with at least three identifiable scales (or orders) of structure. Drawing on Strombus gigas for inspiration, we have developed a new process to realize such complex micro-architectures in macroscopic form. SHELL (Sequential Hierarchical Engineered Layer Lamination) is a thermoplastic forming process that is capable of producing the third order structural complexity over the micron-millimeter length scales. We have fabricated silicon nitride—boron nitride ceramics via SHELL that are endowed with excellent damage tolerance, exhibit graceful failure, and exhibit toughening mechanisms similar to those observed in Strombus gigas.     

Mapping the total phosphorus concentration of biosolid amended surface soils using LANDSAT TM data

Conventional methods for soil sampling and analysis for soil variability in chemical characteristics are too time-consuming and expensive for multi-seasonal monitoring over large-scale areas. Hence, the objectives of this study are: 1) to determine changes in chemical concentrations of soils that are amended with treated sewage sludge; and 2) to determine if LANDSAT TM data can be used to map surface chemical characteristics of such amended soils. For this study, we selected two fields in NW Ohio, designated as F34 and F11, that had been applied with 34 and 11 ton acre^− 1 of biosolids, respectively. Soil samples from a total of 70 sampling locations across the two fields were collected one day prior to LANDSAT 5 overpass and were analyzed for several elemental concentrations. The accumulation of Ba, Cd, Cu, S and P were found to be significantly higher in the surface soils of field F34, compared to field F11. Regression equations were established to search for algorithms that could map these five elemental concentrations in the surface soils using six, dark-object-subtracted (DOS) LANDSAT TM bands and the 15 non-reciprocal spectral ratios derived from these six bands for the May 20, 2005, LANDSAT 5 TM image. Phosphorus (P) had the highest R² adjusted value (67.9%) among all five elements considered, and the resulting algorithm employed only spectral ratios. This model was successfully tested for robustness by applying it to another LANDSAT TM image obtained on June 5, 2005. Our results enabled us to conclude that LANDSAT TM imagery of bare-soil fields can be used to quantify and map the spatial variation of total phosphorous concentration in surface soils. This research has significant implications for identification and mapping of areas with high P, which is important for implementing and monitoring the best phosphorous management practices across the region.     

Physicochemical Investigation of Biocompatible Mixed Surfactant Reverse Micelles: III. Aqueous NaCl Solubilization, Thermodynamic Parameters of Desolubilization Process and Conductometric Studies

Solubilization of water and aqueous NaCl in mixed reverse micelles (RMs) comprising sodium bis(2‐ethylhexyl) sulfosuccinate (AOT), and polyoxyethylene (20) sorbitan trioleate or polyoxyethylene (20) sorbitan monooleate has been studied at different compositions (X_nonionic = 0–1.0) at a total surfactant concentration, S_T = 0.10 × 10³ mol m^?3 in biocompatible oils of different chemical structures; viz., ethyl oleate (EO), isopropyl myristate (IPM) and isopropyl palmitate (IPP) at 303 K. The enhancement in water solubilization (i.e., synergism) has been evidenced by the addition of nonionic surfactant to dioctyl sulfosuccinate/oil(s)/water systems. Addition of NaCl in these systems at different X_nonionic enhances their solubilization capacities further until a maximum, ω_NaCl,max is reached. ω_NaCl,max and [NaCl]_max (concentration at which maximization of NaCl solubilization occurs) depend on type of nonionic surfactant, its content (X_nonionic) and oil. A new solubilization efficiency parameter (SP*_water or SP*_NaCl) has been proposed to compare solubilization phenomena in these oils. The energetic parameters of the desolubilization process of water or aqueous NaCl in single and mixed RMs have been estimated. Energetically, the water dissolution process in oil has been found to be more exothermic as well as more organized in IPP. Overall, the dissolution of water and aqueous NaCl in mixed RMs is entropically driven process. Conductance behavior of these systems in the presence of NaCl has been investigated under different [NaCl] at 303 K. An attempt has been made to give an insight to the mechanism of solubilization phenomena, percolation in conductance and microstructures vis‐à‐vis role of biocompatible oils in these systems.     

Removal of inorganic pollutants in rainwater by a peat-derived porous material

Although roof-top runoff water has been considered as an alternative water resource, the harvested rainwater needs to be treated for further use because it usually contains various contaminants such as heavy metals and microbes. The degree of the harvested rainwater quality depends upon its end use such as drinking water and irrigation. Especially, when harvested rainwater is to be used as gray water, a cost effective treatment system is required. Accordingly, the main purpose of this study was to examine the adsorption characteristics of peat, cost-effective biosorbent, for various inorganic pollutants such as ammonium, copper, cadmium and lead from roof-top runoff water. As part of efforts to investigate the sorption properties of peat, batch isotherm tests were carried out under various pH conditions. The characterization of peat was carried out with powder X-ray diffraction, Brunauer–Emmett–Teller, and scanning electron microscope measurements. Both heat-treated peat and non-treated peat appeared to have high sorption capacity for all inorganic contaminants (NH₄ ⁺, Cu²⁺, Cd²⁺, and Pb²⁺). An interesting finding is that the amount of NH₄ ⁺ sorbed on the sorbents was slightly higher compared to the other cations. Also, the sorption capacity of the peat sorbents increased with an increase of pH. On the other hand, kinetic data were well described by pseudo-second kinetic model, indicating that removal mechanism of cations by peat-derived sorbents is likely due to chemisorptions. The results of this study suggested that peat-derived porous materials can be used as effective sorbents for removal of cationic inorganic contaminants from harvested rainwater.     

An Approach for Estimation of Cathode Voltage Drop in an Aluminum Reduction Cell with an Inclined Carbon Block and a Copper Insert

Numerical models of a cathode block assembly in a Hall–Hèroult cell, comprising of liquid aluminium, carbon block, current collector, ramming paste and a copper insert were built and the finite element method simulations were carried out to model the cathode voltage drop (CVD), the current distribution and, the effect of geometrical parameters on the CVD. The objective of the study was to quantify the drop in the CVD for different cathode assembly design. Flat- and inclined-interface carbon block top-surface and a copper insert versus the conventional insert-free designs were simulated with a myriad of other geometrical parameters to optimise the design. The results informed about the optimum insert positioning to about 75 mm from the collector base and the energy saving possibilities due to reduction in the CVD with a cathode design with inclined-interface carbon block and copper insert in the collector bar.     

Geometric optimization of trapezoidal thermoelectric heat pump considering contact resistances through genetic algorithm

An alternate option for improving the performance of the thermoelectric heat pump (TEHP) is the variation in thermoelectric leg configuration. In this paper, the thermodynamic model based on first and second law of thermodynamics for an exoreversible TEHP including influence of Thomson effect as well as leg geometry on the coefficient of performance and heating load of the device has been developed and optimized. Modified expressions have been derived analytically for dimensionless heating load, irreversibilities, figure of merit, energy, and exergy efficiency. The effects of operating and geometry parameters such as shape parameter (A_c/A_h), temperature ratio (T_c/T_h), Thomson effect, thermal and electrical contact resistances on the coefficient of performance, and heating load of the TEHP have been analysed. The results indicate that the Thomson effect has adverse effect on heating load of the system. The optimal parameters obtained through GA optimization process have been compared with the optimal parameters obtained through analytical method which proved the validity of GA optimization method for optimization of TEHP. After the testing, the GA optimization has been performed to determine the optimum parameters corresponding to maximum energy efficiency and maximum heating load. It was found that the GA population converges quickly after 20 runs only which proved the GA as time and cost‐effective optimization tool. This study will be useful for designing of practical TEHP systems of different leg geometries.     

Toughness in synthetic and biological multilayered systems

Toughness in hard biological tissues is associated with fibrous or lamellar structures that deflect or stop growing cracks. In some cases, such as nacreous shell, protein interlayers absorb much of the crack energy. In other tissues, such as tooth enamel, the toughness derives from the mineral microstructure, and the small amount of residual protein apparently has little effect. There have been a number of efforts to make tough synthetic materials using layered structures. In this work, freeform fabrication has been used to make layered structures with a view to introducing similar toughness into brittle materials. Results are presented for epoxy-glass composites with glass fabric interlayers, porous alumina back-filled with aluminium metal, and layered glass-ceramic/silver materials.