A novel method for suppressing silicidation of tungsten catalyzer during silane decomposition in Cat-CVD

Growth of tungsten silicide (WSi_x) on tungsten (W) catalyzer surface is investigated by monitoring resistance change of heated W wire in silane (SiH₄) atmosphere. To know a method suppressing the silicide formation, the effect of carbonization of W surface is also studied. Resistance change of heated W, observed in initial stage just after SiH₄ introduction, is brought about increase in power consumption due to decomposition of SiH₄. This power consumption can be drastically reduced when W surface is carbonized. Therefore, carbonization of tungsten surface is effective to stabilize the catalyzer temperature and to suppress W silicidation.     

Osteogenic activity of human periosteal sheets cultured on salmon collagen-coated ePTFE meshes

Our animal implantation studies have demonstrated that, after osteogenic processing, cultured human periosteal sheets form osteoid tissue ectopically without the aid of conventional scaffolding materials. To improve the osteogenic activity of these periosteal sheets, we have tested the effects of including a scaffold made of salmon collagen-coated ePTFE mesh. Periosteal sheets were produced with minimal manipulation without enzymatic digestion. Outgrown cells penetrated into the coated mesh fiber networks to form complex multicellular layers and increased expression of alkaline phosphatase activity in response to the osteoinduction. In vitro mineralization was notably enhanced in the original tissue segment regions, but numerous micro-mineral deposits were also formed on the coated-fiber networks. When implanted subcutaneously into nude mice, periosteal sheets efficiently form osteoid around the mineral deposits. These findings suggest that the intricate three-dimensional mesh composed of collagen-coated fibers substantially augmented the osteogenic activity of human periosteal sheets both in vitro and in vivo.     

Scandium-Doped Anatase (TiO2) Nanoparticles Directly Formed by Hydrothermal Crystallization

Anatase-type TiO₂ solid solutions doped with 0–10 mol% scandium were formed by hydrothermal crystallization under weak basic conditions above 180°C for 5 h from amorphous co-precipitates that were obtained from the aqueous precursor solutions of TiOSO₄ and Sc(NO₃)₃ using aqueous ammonia. The anatase particles were spindle-like and consisted of nanosized-crystallites (23–25 nm). The lattice parameter c ₀ of anatase and the length and width of the spindle-like anatase gradually increased when the scandium content was increased. The diffuse reflectance spectra of the as-prepared TiO₂ doped with scandium showed that the onset of absorption slightly shifted to longer wavelengths with increasing scandium content. The band gap of anatase was slightly increased by making solid solutions with scandium oxide.     

Frenkel pair accumulation induced crystallization of amorphous MgAl2O4

The epitaxial and homogeneous irradiation induced re-crystallization of amorphous MgAl₂O₄ was studied by means of continuous Frenkel pair accumulation in the molecular dynamics framework. Present results point out that the re-crystallization induced by Frenkel pair accumulation appears in both cases to be thermally enhanced but non diffusive. It is governed by a local rearrangement of each point defect in the homogeneous case, while spontaneous Frenkel pair recombination process in the crystalline part or at the interface drives the re-crystallization in the epitaxial case.     

Smoking and small, dense low-density lipoprotein particles: cross-sectional study

All forms of tobacco cause cardiovascular disease, and tobacco-related disease is a leading cause of death worldwide. Smoking oxidizes low-density lipoprotein (LDL) particles, and oxidized LDL particles are thought to play an early and critical role in atherosclerogenesis. Hyper-low-density lipoproteinemia is one of the risk factors for cardiovascular disease, but small, dense LDL particles have been associated with an increased risk for cardiovascular disease. Small, dense LDL correlates with some cardiovascular risk factors such as diabetes mellitus, hypertriglyceridemia, hypo-high-density lipoproteinemia, and hypertension. Although smoking is also a major risk factor for cardiovascular disease, the relationship between smoking and small, dense LDL particles has not been described previously. Our cross-sectional study examined this relationship in a population of 18 healthy young adult men (9 smokers and 9 never-smokers, aged 21-24 years) from the same college. Concentrations of blood lipids and the LDL migration index (LDL-MI) were examined. Although concentrations of blood lipids did not differ between smokers and never-smokers, the LDL-MI had a strong tendency to be lower in smokers. The LDL-MI is larger in the presence of a greater proportion of small, dense LDL particles. These results indicate that tobacco smoking is associated with a decrease in the proportion of small, dense LDL particles. Regardless of these surprising results, we do not recommend smoking, given that it is a major cause of cardiovascular disease.     

Orbit systematics in anisotropic Kepler problem

We revisit the Anisotropic Kepler Problem (AKP), which concerns with trajectories of an electron with anisotropic mass term in a Coulomb field. This is one of the most fundamental fields in Quantum Chaos. Nowadays various quantum systems are challenging us. Classical theories of these may have chaos. Quantum mechanics have developed from integrable cases and may have to be reformulated for such cases. AKP then serves as a suitable testing ground for quantum chaos. We first review a pioneering work by Martin Gutzwiller (J Math Phys (1977) 18:106). We shall show the systematics of the trajectories using ample figures from an extensive numerical analysis. Then we focus on the rolê of hyperbolic singularities and we comment on the approximations in an analytic formulation. This work was presented in part at the 13th International Symposium on Artificial Life and Robotics, Oita, Japan, January 31–February 2, 2008     

Lagrangian method for deriving electrically dual power converters applicable to nonplanar circuit topologies

This paper proposes a novel method for deriving dual converters, namely deriving current‐source converters from voltage‐source counterparts, and vice versa. The conventional derivation method is based on the transformation of circuit topology, in which series connections are converted into parallel connections, and vice versa. However, this method cannot be directly applied to nonplanar circuits because they do not allow perfect topological transformation, although many of them are known to have duals. Lagrangian dynamics does not depend on the topological relation to transform a system into another equivalent system; therefore, it possibly avoids problems related to topological transformation and may provide a universal and systematic method that can be consistently applied to nonplanar circuits. This paper discusses the derivation of duals using Lagrangian dynamics. Along with the theory, this paper presents two examples of Lagrangian derivation of duals. One derives a dual of a planar circuit, to which the topological transformation is applicable. The other derives two duals of a nonplanar circuit. Consequently, these examples suggest that the proposed method is a prospective candidate for universal and systematic derivation of duals. © 2016 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

工艺参数及稳定剂抗坏血酸对电沉积NiFeW合金的影响

为获得性能良好的镍铁钨合金镀层,研究了镀液pH 值、温度、电流密度、稳定剂抗坏血酸浓度对镍铁钨合金镀层成分和镀层沉积速率、显微硬度的影响。结果表明: 镀液pH 值对镀层W含量和镀层沉积速率影响较大;镀液温度对镀层沉积速率、镀层成分和镀层硬度影响均较大;随抗坏血酸浓度增加,镀层沉积速率逐渐降低,镀层表面形貌更加粗糙。在镀液pH = 4,温度60 ℃,电流密度4 A/dm2,抗坏血酸浓度3 g /L 时,镀层沉积速率和镀层的显微硬度较高,表面光亮致密,耐蚀性好。     

采用无偏振片反射式LCD及超低功耗驱动技术制造移动显示器件

我们通过对材料和制备条件的精细化处理,生产出一种在低刷新频率下无闪烁和图像迟滞现象的反射式显示器。该显示器的功耗非常低,且可在宽温度范围内工作,是未来移动显示器件的潜力平台。     

RETRACTED ARTICLE: Single-Phase <Emphasis Type="Italic">β</Emphasis>-Zn<Subscript>4</Subscript>Sb<Subscript>3</Subscript> Prepared by a Mechanical Grinding Method

Single-phase β-Zn₄Sb₃ materials were prepared by mechanical grinding (MG). Source materials for the Zn₄Sb₃ ingots were prepared using three different processes after the direct melting of constituent elements. In process 1, the ingot was obtained by quenching the melt in water within an evacuated quartz ampoule. In process 2, the ingot was heat-treated for 100 h at 723 K after process 1. In process 3, the ingot was heat-treated for a total of 200 h in two stages at 723 K and 673 K after process 1. The resultant ingots were mechanically ground and sintered at 623 K by hot pressing. The sintered materials were characterized by x-ray diffraction, differential thermal analysis (DTA), and thermoelectric property measurements. The thermal conductivity of the sintered materials was 0.88 W m⁻¹ K⁻¹ at room temperature, being slightly lower than that reported for the materials prepared by a conventional method. Results indicate that the dimensionless figure of merit of the single-phase β-Zn₄Sb₃ ranged from 1.06 to 1.31 at 573 K.