Eddy current analysis of thin metal container in induction heating by line integral equations

In recent years, induction‐heating cookers have spread rapidly. It is desirable to commercialize flexible and disposable food containers that are suitable for induction heating. In order to develop a good‐quality food container for moderate heating, the eddy currents induced in a thin metal plate must be accurately analyzed. The integral equation method is widely used for solving induction‐heating problems. If the plate thickness approaches zero, the surface integral equations on the upper and lower plate surfaces tend to become the same and the equations become ill‐conditioned. In this paper, we first derive line integral equations from the boundary integral equations under the assumption that the electromagnetic fields in the metal are attenuated more rapidly than those along the metal surface. Next, to test the validity of the line integral equations, we solve for the eddy current induced in a thin metal container in induction heating and obtain the power density imparted to the container and the impedance characteristics of the heating coil. We then compare the computed results with those obtained by the FEM. © 2009 Wiley Periodicals, Inc. Electr Eng Jpn, 168(2): 20–27, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20813     

TEM Observations of the Initial Oxidation Stages of Nb-Ion-Implanted TiAl

Coupon specimens of TiAl were implanted with Nb ions at an acceleration voltage of 50 kV with a dose of 10²¹ ions m.^–2 They were then slightly oxidized during heating to 900 or 1200 K, or at 1200 K for 3.6 ksec (1 hr) in a flow of purified oxygen under atmospheric pressure. The implanted specimens and oxidized specimens were characterized and observed by AES, X-ray diffractometry, SEM, TEM, EDS, and EPMA. Implantation improves the oxidation resistance significantly by forming virtually -Al₂O₃ scales. The implanted layer is about 75 nm thick; the outer part of 30-nm thickness is -Ti phase and the rest of 45-nm thickness is amorphous. Heating to 900 K in O₂ results in partial crystallization of the amorphous layer to Ti₅Al₃O₂ (Z-phase) and to 1200 K results in oxide scales of 270 to 400 nm thickness consisting mainly of Al₂O₃. The fraction of Al₂O₃ in the scale increases toward the substrate. Oxidation at 1200 K for 3.6 ksec results in Al₂O₃-rich scales of about 400-nm thickness. The oxide grain size is very fine, about 80 nm in size, and becomes smaller toward the outer scale surface. This implies that implantation enhanced the nucleation of Al₂O₃ grains relative to the growth of TiO₂ grains. This finding and the formation of -Ti phase are thought to be responsible for the excellent oxidation resistance obtained.     

Hydrolysis of beta-glucosyl ester linkage of p-hydroxybenzoyl beta-D-glucose, a chemically synthesized glucoside, by beta-glucosidases

To investigate the hydrolysis of glucosyl esters by beta-glucosidase, p-hydroxybenzoyl beta-D-glucose (pHBG) was chemically synthesized. The hydrolytic activity of some beta-glucosidases for pHBG was compared to that for p-nitrophenyl beta-glucoside (pNPG). The Clavibacter michiganense and Flavobacterium johnsonae enzymes could hydrolyze pHBG and steviol glycosides which are natural glucosyl esters. The commercial beta-glucosidase originating from Caldocellum saccharolyticum also hydrolyzes pHBG despite having no activity for steviol glycosides. The beta-glucosidase from Aspergillus niger cleaved the glucosyl ester linkage much more weakly than the glucosidic linkage. The pH-activity profile for the hydrolysis of pHBG was similar to that of pNPG by the C. saccharolyticum beta-glucosidase. The similar profiles for these substrates suggested that the active site for the glucosyl ester chemically resembles that for glucoside with respect to catalysis. Kinetic analysis of the C. saccharolyticum beta-glucosidase for mixed substrates of pHBG and pNPG showed that the hydrolysis of pHBG competed with that of pNPG. This result indicated that there is only one active site for both the glucosyl ester and glucoside. Mass spectroscopic analysis of the hydrolysates of pHBG in H218O suggested that beta-glucosidase hydrolyzes glucosyl esters between the anomeric carbon of glucose and the carbonyl oxygen, not between the carbonyl carbon and the carbonyl oxygen.     

On-line derivative estimation for the multiclass single-serverpriority queue using perturbation analysis

Gradient estimation via smoothed perturbation analysis (SPA) is considered for the multiclass single-server priority queue. Although the problem like this requires additional subpaths, generally it is shown that the estimators can be derived without any additional sample paths     

Thin oxide films of silicon by high pressure oxidation

High pressure oxidation of silicon was performed at an oxidation temperature range of 650 to 800°C for thin oxide films with about 300 å thickness. The index of refraction was dependent on an oxidation temperature but independent of the oxidation pressure as 1.475 at 750°C. The dielectric breakdown strength of the oxide film was measured by the voltage ramping,method. The fixed oxide charge about 1.0 × 10¹¹ cm^?2 was also measured from the high frequency C-V measurement. The pulse scanning C-V measurement technique was used to measure the minority carrier generation rate in the depleted surface. The surface generation velocity was slightly dependent on the oxidation temperature and indicated that the fast surface states increased with decreasing oxidation temperature.     

Composite of Au nanoparticles and molecularly imprinted polymer as a sensing material

A molecularly imprinted polymer with immobilized Au nanoparticles (Au-MIP) is reported as a novel type of sensing material. The sensing mechanism is based upon the variable proximity of the Au nanoparticles immobilized in the imprinted polymer, which exhibits selective binding of a given analyte accompanied by swelling that causes a blue-shift in the plasmon absorption band of the immobilized Au nanoparticles. Using adrenaline as the model analyte, it was shown that molecular imprinting effectively enhanced the sensitivity and selectivity, and accordingly, Au-MIP selectively detects the analyte at 5 microM. The combination of molecular imprinting and the Au nanoparticle-based sensing system was shown to be a general strategy for constructing sensing materials in a tailor-made fashion due to wide applicability of the imprinting technique and the independence of the sensing mechanism from the analyte recognition system.     

Dose evaluation in criticality accident conditions using transient critical facilities fueled with a fissile solution

Neutron dose measurement and evaluation techniques in criticality accident conditions using a thermo luminescence dosemeter (TLD) was studied at the Transient Experiment Critical Facility (TRACY) of Japan Atomic Energy Research Institute (JAERI). In the present approach, the absorbed dose is derived from the ambient dose equivalent measured with a TLD, using the appropriate conversion factor given by computation. Using this technique, the neutron dose around the SILENE reactor of the Institute for Radioprotection and Nuclear Safety (IRSN) of France was measured in the Accident Dosimetry Intercomparison Exercise (June 10-21, 2002) organized by OECD/NEA and IRSN. In this exercise, the gamma dose was also measured with a TLD. In this report, measurements and evaluation results at TRACY and SILENE are presented.     

Investigation of the solution condition of lithium electrolyte solutions with LiCF3SO3 salt

Solution condition of the lithium electrolyte of LiCF₃SO₃ salt dissolved in propylene carbonate (PC), dimethoxyethane (DME) and tetrahydrofuran (THF) were investigated based on the measurements of the self-diffusion coefficients of lithium (D_Li) and anion (D_F) species using the pulsed-field gradient (PFG) NMR, viscosity and conductivity. D_Li and D_F decreased with the increase in the solution concentration for these electrolytes. This result reflects the change in the dissociation degree of the salt and the viscosity depending on the solution concentration. In the case of PC solution (the dielectric constant () of PC: 65), measured D_Li and D_F were separated each other with the decrease in the concentration because the dissociation of the salt was promoted to increase the content of dissociated ions. With an increase in the concentration, the dissociation would be restricted and D_Li and D_F approximated each other, which means that the associated ion pairs are dominant in the solution. The effective ionic radius (r_eff) of cation species of PC solution estimated from the Stokes-Einstein relation using the diffusion coefficient and the viscosity results was four times greater than that of the naked lithium ion and independent of the dissociation degree. On the other hand, the r_eff of anion species changed depending on the dissociation degree. This suggests that the dissociated lithium ions are solvated by the PC solvent in the solution. DME and THF solutions did not show the solvation effect from the result of the change in r_eff with the concentration. This suggests that the dissociation degree of the dissolved salt was low due to the low of their solvents ( 7.2) and the ion pairs would dominant in the solutions independent of the solution concentration.     

Study on chemical structures of poly (tetrafluoroethylene-co-perfluoroalkylvinylether) by soft-EB irradiation in solid and molten state

Poly (tetrafluoroethylene-co-perfluoroalkylvinylether) (PFA) was irradiated by soft electron beam (soft-EB) under nitrogen gas atmosphere in solid-state and its molten state, respectively. The changes of thermal property and chemical structures of irradiated PFA in solid-state and molten state were studied by differential scanning calorimetric analysis (DSC) and solid-state ¹⁹F magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. By DSC analysis, the melting temperature shifted to lower temperatures, and crystallinity decreased with increasing soft-EB dose. By solid-state ¹⁹F MAS NMR spectroscopy, the new signals was observed and the detected new signals in irradiated PFA at 315 °C and at 30 °C were due to the tertiary carbon group with branching site (Y-type crosslinking site), perfluoro-propylene site and chain end methylene groups, respectively.Moreover, the molar ratio of perfluoroalkylvinylether (FAVE) structure to -CF₂- units decreased with increasing dose.     

Construction of a learning environment supporting learners’ reflection: A case of information seeking on the Web

In this study, we design a learning environment that supports reflective activities for information seeking on the Web and evaluate its educational effects. The features of this design are: (1) to visualize the learners’ search processes as described, based on a cognitive schema, (2) to support two types of reflective activities, such as “reflection-in-action” and “reflection-on-action”, and (3) to facilitate reflective activities by comparing their own search processes to other learners’ search processes. We have conducted an experiment to investigate the effects of our design. The experimental results confirm that: (1) the participants’ search performance in the instructional group supported by our instructional design improved effectively than in the control group; (2) they changed their ideas about important activities when seeking information on the Web, and (3) they activated their search cycles more than the control group did.