Principle and basic characteristics of a hybrid variable‐magnetic‐force motor

Reducing the power consumed by motors is important for energy conservation in the case of electrical appliances and electric vehicles (EVs). The motors used for operating these devices operate at variable speeds. Further, the motors operate with a small load in the stationary mode and a large load in the starting mode. A permanent magnet motor can be operated at rated power with high efficiency. However, the efficiency is low under a small load or at high speeds because the large constant magnetic force results in substantial core loss. Furthermore, the flux‐weakening current that decreases the voltage at high speeds leads to significant copper loss and core loss. Therefore, we have developed a new technique for controlling the magnetic force of a permanent magnet on the basis of the load or speed of the motor. In this paper we propose a novel motor that can vary the magnetic flux of a permanent magnet and clarify the principles and basic characteristics of the motor. The new motor has a permanent magnet that is magnetized by the magnetizing coil of the stator. The results of analysis show that the magnetic flux linkage of the motor can be changed from 37% to 100% and that a high torque can be produced. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 183(2): 47–57, 2013; Published online in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/eej.22309     

Synthesis of an Enantiocomplementary Catalyst of β‐Isocupreidine (β‐ICD) from Quinine

Compound 20 , a pseudoenantiomer of β‐isocupreidine (β‐ICD), was synthesized from quinine employing a Barton reaction of nitrosyl ester 13 and acid‐catalyzed cyclization of carbinol 18 as key steps. The Baylis–Hillman reaction of benzaldehyde, p‐nitrobenzaldehyde, and hydrocinnamaldehyde with 1,1,1,3,3,3‐hexafluoroisopropyl acrylate (HFIPA) using 20 as a chiral amine catalyst was found to give the corresponding S‐enriched adducts in high optical purity (>91% ee) in contrast to the β‐ICD‐catalyzed reaction which affords R‐enriched adducts. This result suggests that compound 20 can serve as an enantiocomplementary catalyst of β‐ICD in the asymmetric Baylis–Hillman reaction of aldehydes with HFIPA.     

Gamma-Ray Spectrometer based on a Transition Edge Sensor for Nuclear Materials Analysis

We designed and fabricated a hard X-ray and gamma-ray TES spectrometer for nuclear materials analysis. The superconducting tin absorber is coupled to an Ir/Au TES by using a gold post to improve the thermal contact between the absorber and the TES. The reported energy resolution is 156 eV FWHM at 59.5 keV and 166 eV FWHM at 122 keV gamma-rays. We performed measurement of a Pu sample and clearly separated the \(^{239}\) Pu (56.828 keV) and the \(^{241}\) Am (59.5 keV) peaks by this TES microcalorimeter which cannot be resolved by the HPGe detector.     

Hematopoietic–Mesenchymal Signals Regulate the Properties of Mesenchymal Stem Cells

It is well known that the properties of hematopoietic stem/progenitor cells (HSCs), such as their self-renewal ability and multipotency, are maintained through interactions with mesenchymal stem/stromal cells (MSCs). MSCs are rare cells that are present in the bone marrow and are useful for clinical applications due to their functional ability. To obtain the necessary number of cells, MSCs must be cultured to expand, but this causes a remarkable decrease in stem cell properties, such as multipotency and proliferation ability. In this study, we show that the c-Mpl signal, which is related to the maintenance of hematopoietic stem cells, has an important effect on the proliferation and differentiation ability of MSCs. Utilizing a co-culture system comprising MSCs and HSCs, it is suggested that signaling from hematopoietic cells to MSCs supports cell proliferation. Interestingly, the enhanced proliferation ability of the HSCs was decreased in c-Mpl knock-out HSCs (c-Mpl-KO). In addition, the MSCs co-cultured with c-Mpl-KO HSCs had reduced MSC marker expression (PDGFRa and Sca-1) compared to the MSCs co-cultured with c-Mpl-wild-type HSCs. These results suggest that a hematopoietic–mesenchymal signal exists, and that the state of the HSCs is important for the stability of MSC properties.     

Solution-Processable Pure Green Thermally Activated Delayed Fluorescence Emitter Based on the Multiple Resonance Effect

Thermally activated delayed fluorescence (TADF) materials based on the multiple resonance (MR) effect are applied in organic light-emitting diodes (OLEDs), combining high color purity and efficiency. However, they are not fabricated via solution-processing, which is an economical approach toward the mass production of OLED displays. Here, a solution-processable MR-TADF material (OAB-ABP-1), with an extended π-skeleton and bulky substituents, is designed. OAB-ABP-1 is synthesized from commercially available starting materials via a four-step process involving one-shot double borylation. OAB-ABP-1 presents attractive photophysical properties, a narrow emission band, a high photoluminescence quantum yield, a small energy gap between S₁ and T₁, and low activation energy for reverse intersystem crossing. These properties are attributed to the alternating localization of the highest occupied and lowest unoccupied molecular orbitals induced by the boron, nitrogen, and oxygen atoms. Furthermore, to facilitate charge recombination, two novel semiconducting polymers with similar ionization potentials to that of OAB-ABP-1 are synthesized for use as interlayer and emissive layer materials. A solution-processed OLED device is fabricated using OAB-ABP-1 and the aforementioned polymers; it exhibits pure green electroluminescence with a small full-width at half-maximum and a high external quantum efficiency with minimum efficiency roll-off.     

Conditional activation of Janus kinase (JAK) confers factor independence upon interleukin-3-dependent cells. Essential role of Ras in JAK-triggered mitogenesis

Cytokines play crucial roles in the growth and differentiation of hematopoietic cells. They bind to specific cell membrane receptors that usually do not possess intrinsic protein-tyrosine kinase activity. Janus kinases (JAKs) are cytoplasmic protein-tyrosine kinases that physically interact with intracellular domains of the cytokine receptors and have been implicated in playing important roles in signal transduction triggered by the cytokine-cytokine receptor interaction. However, it is still uncertain whether JAK activation alone suffices to induce cell proliferation. In this work, we modified Tyk2, a member of the JAK family, by adding a membrane localization sequence and a chemical dimerizer (coumermycin)-dependent dimerization sequence. The modified Tyk2 was activated in a coumermycin-dependent manner, and the activated Tyk2 conferred cytokine independence upon interleukin-3-dependent pro-B lymphoid cells. This cytokine-independent proliferation was completely inhibited by dominant-negative Ras. These results indicate that activation of JAK through membrane-proximal dimerization is sufficient to induce cell cycle progression and that Ras is essentially involved in JAK-triggered mitogenesis.     

Simultaneous Edge‐on to Face‐on Reorientation and 1D Alignment of Small π‐Conjugated Molecules Using Room‐Temperature Mechanical Rubbing

In this study, room‐temperature mechanical rubbing is used to control the 3D orientation of small π‐conjugated molecular systems in solution‐processed polycrystalline thin films without using any alignment substrate. High absorption dichroic ratio and significant anisotropy in charge carrier mobilities (up to 130) measured in transistor configuration are obtained in rubbed organic films based on the ambipolar quinoidal quaterthiophene (QQT(CN)4). Moreover, a solvent vapor annealing treatment of the rubbed film is found to improve the optical and charge transport anisotropy due to an increased crystallinity. X‐ray diffraction and atomic force microscopy measurements demonstrate that rubbing does not only lead to an excellent 1D orientation of the QQT(CN)4 molecules over large areas but also modifies the orientation of the crystals, moving molecules from an edge‐on to a face‐on configuration. The reasons why a mechanical alignment technique can be used at room temperature for such a polycrystalline film are rationalized, by the plastic characteristics of the QQT(CN)4 layer and the role of the flexible alkyl side chains in the molecular packing. This nearly complete conversion from edge‐on to face‐on orientation by mechanical treatment in polycrystalline small‐molecule‐based thin films opens perspectives in terms of fundamental research and practical applications in organic optoelectronics.     

A Survey of Autonomous Human Affect Detection Methods for Social Robots Engaged in Natural HRI

In Human-Robot Interactions (HRI), robots should be socially intelligent. They should be able to respond appropriately to human affective and social cues in order to effectively engage in bi-directional communications. Social intelligence would allow a robot to relate to, understand, and interact and share information with people in real-world human-centered environments. This survey paper presents an encompassing review of existing automated affect recognition and classification systems for social robots engaged in various HRI settings. Human-affect detection from facial expressions, body language, voice, and physiological signals are investigated, as well as from a combination of the aforementioned modes. The automated systems are described by their corresponding robotic and HRI applications, the sensors they employ, and the feature detection techniques and affect classification strategies utilized. This paper also discusses pertinent future research directions for promoting the development of socially intelligent robots capable of recognizing, classifying and responding to human affective states during real-time HRI.