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61.
Nobuko Onozawa-Komatsuzaki Masatoshi Yanagida Takashi Funaki Kazuyuki Kasuga Kazuhiro Sayama Hideki Sugihara 《Inorganic chemistry communications》2009,12(12):1212-1215
A new ruthenium(II)–polypyridine complex (1) having a 2,6-bis(4-carboxyquinolin-2-yl)pyridine ligand was synthesized as a sensitizer for dye-sensitized solar cells (DSCs). This complex exhibited remarkable light-harvesting properties in the near-IR region. DSCs sensitized with 1 showed a 35% incident photon-to-current conversion efficiency (IPCE) at 900 nm. 相似文献
62.
The rheological behavior and microstructure of bimodal suspensions of core‐shell structured swollen particles have been examined with changing volume ratio of two different sized particles. As the volume fraction of large particles increases, the viscosity, degree of shear‐thinning, and the critical shear stress σc decreases, while the interparticle distance ξ of the microstructure increases. The suspensions exhibit single mode rheological behavior and have a single diffraction peak in the SAXS profiles. These results suggest that the bimodal suspensions of the core‐shell structured swollen particles behave likely to unimodal suspensions of hard spheres with alloy like single mode microstructure composed of hypothetical intermediate size particle. The relationship between σc and ξ can be represented as σc = 3kT/4πξ3, which corresponds to the dynamics of the Brownian hard sphere model with ξ being the particle diameter. These findings indicate that the shear‐thinning of the suspensions can be attributed to dynamical competition between the thermal motion and the hydrodynamic motion under shear flow and that the mechanism can be applied to bimodal suspensions of the swollen particles as well as unimodal suspensions of hard spheres. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 102: 2212–2217, 2006 相似文献
63.
64.
Xianglan Li Jing Ma Yunjun Yao Shunlin Liang Guangbin Zhang Hua Xu Kazuyuki Yagi 《Nutrient Cycling in Agroecosystems》2014,100(1):65-76
Straw application and midseason drainage play role in controlling methane (CH4) and nitrous oxide (N2O) emissions from rice paddy fields, but little information is available on their integrative effect on CH4 and N2O emissions. A two-year field experiment was conducted to study the combined effect of timing and duration of midseason aeration and wheat straw incorporation on mitigation of global warming potential (GWP) of CH4 and N2O emissions from irrigated lowland rice paddy fields. Results showed that incorporation of wheat straw increased CH4 by a factor of 5–9 under various water regimes, but simultaneously decreased N2O emission by 19–42 % during the rice growing season. Without straw incorporation, prolonged aeration significantly reduced the net 100-year GWP of CH4 and N2O emissions by 6 %, but also decreased rice production when compared with normal aeration. With straw incorporation, the lowest GWP was found by early aeration, which reduced GWP by 7 and 20 % in 2007 and 2008, respectively. Estimation of net GWPs of CH4 and N2O emissions indicated that early midseason drainage with straw incorporation offered the potential to mitigate CH4 and N2O emissions from irrigated lowland rice paddies in China. 相似文献
65.
Tooru Kitagawa Kazuyuki Yabuki Andrew C. Wright Robert. J. Young 《Journal of Materials Science》2014,49(18):6467-6474
A detailed morphological study of the microstructure of poly(p-phenylene benzobisoxazole) (PBO) fibres (HM and HM+) and a polypyridobisimidazole (PIPD) (HT) fibre has been undertaken using transmission electron microscopy. Both PBO and PIPD fibres are composed of rigid-rod polymers having p-phenylene rings in the molecular backbone and show high modulus (280–360 GPa) and high strength (4–6 GPa). It is found that the PBO HM+ fibre has the highest degree of molecular orientation of the three fibres and the longest crystal length along the fibre axis, while the PIPD fibre shows a lower degree of orientation and a shorter crystal length than the PBO fibres. To understand the effect of crystalline size and fine structure of the fibres upon mechanical properties, dark-field and high-resolution lattice images were obtained and analysed in detail. 相似文献
66.
Kazuyuki Yagi Yukito Ebisu Joichi Sugimura Seiji Kajita Toshihide Ohmori Atsushi Suzuki 《Tribology Letters》2011,43(3):361-368
In this study, a direct observation of a point contact area was conducted to understand the scuffing phenomenon. The contact
area was produced between a rotating sapphire disc and a stationary steel ball and it was lubricated using n-hexadecane. The image detected by a colour digital CCD camera, load, and friction were synchronously recorded by a computer
during the test. It was found that wear debris produced in the contact area played an important role in the wear process,
which includes running-in and scuffing. In the test, debris particles accumulated in the inlet zone, and some particles entered
the contact area to cause abrasive wear of the ball surface, even in the light-load stages. During the running-in process,
the abrasive wear by debris particles changed the conformity between the sliding surfaces. In the high-load stage, just before
the occurrence of scuffing, the whole contact area was flattened at once. When scuffing occurred, the contact area suddenly
expanded. The conformity of the contact area was dramatically changed during its expansion. The flattening of the whole contact
area and dramatic expansion with changing the conformity seemed to play important roles in scuffing. 相似文献
67.
Mesoporous silica coated titania exhibited a substrate selective photocatalytic reaction; 4-nonylphenol and phenol were decomposed while nonane was not decomposed by the UV irradiation to their aqueous mixture. 相似文献
68.
Mitsuru Uesaka Takuya NatsuiKiwoo Lee Katsuhiro DobashiTomohiko Yamamoto Takeshi FujiwaraHaito Zhu Kazuyuki DemachiEiji Tanabe Masashi YamamotoNaoki Nakamura Joichi KusanoToshiyasu Higo Shigeki FukudaMitsuhiro Yoshida Shuji Matsumoto 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》2011,657(1):82-87
We are developing compact X-band linac X-ray sources for nondestructive evaluation and medicine. First, we develop a portable X-ray system by a 950 keV 9.4 GHz X-band linac to realize on-site inspection. We use a low power (250 kW) magnetron as an RF source for compactness of the whole system. Since the RF power source is quite small and the stored energy in the structure is also small, we faced the problem of beam loading and current/RF-power oscillation. We are analyzing the problem by the circuit model. We plan to use this system for erosion inspection of metal pipes of petrochemical complex. By adopting a side-coupling cavity design to avoid the oscillation, we have developed 6 MeV X-band (9.3 GHz) linac for pinpoint dynamic tracking cancer therapy. Furthermore, we are manufacturing 3.95 MeV X-band (9.3 GHz) linac X-ray source with flexible waveguides for on-site bridge inspection. Updated results and situations are presented. 相似文献
69.
Silica films with a single-crystalline mesoporous structure 总被引:1,自引:0,他引:1
Miyata H Suzuki T Fukuoka A Sawada T Watanabe M Noma T Takada K Mukaide T Kuroda K 《Nature materials》2004,3(9):651-656
Films of mesoporous materials attract broad interest because of their wide applicability in the fields of optics and electronics. Although many of these films have a regular local porous structure, the structural regularity has not been used practically yet because of difficulties in its control on macroscopic scales. Here, we demonstrate the preparation of mesoporous silica films whose porous structure can be described as a single crystal, that is, a long-range order of cage-like pores is maintained over centimetre scales. These films have a three-dimensional hexagonal (space group P6(3)/mmc) porous structure, and the in-plane arrangement of the pores is strictly controlled by a polymeric substrate surface that has been treated by rubbing. This new class of single-crystalline films with mesoscopic periodic structure is a significant breakthrough in bottom-up nanotechnology, and could lead to novel devices, for example, optics in a soft X-ray region, and quantum electronics. 相似文献
70.
Toshiaki Enoki Yousuke Kobayashi Chika Katsuyama Vladimir Yu. Osipov Marina V. Baidakova Kazuyuki Takai Ken-ichi Fukui Alexander Ya. Vul'' 《Diamond and Related Materials》2007,16(12):2029-2034
The structure, electronic and magnetic properties of nanodiamond and nanographite/nanographene are investigated. Detonation nanodiamond particles that are covered with amorphous graphitic composites are hydrothermally treated to remove the graphitic surface composites and to terminate the surface carbon atoms with hydrogen. The number of localized spins of dangling bonds and the hydrogen concentration increase upon the increase in the hydrothermal treatment time up to 40 h. Above 40 h, both drop discontinuously, a surface structural reconstruction was suggested. The creation of dangling bonds and an incomplete hydrogenation of the surface carbon atoms destabilize the surface, resulting in the structural reconstruction. Nanodiamond particles are thermally converted to nanographite/nanographene. A single nanographene sheet is successfully prepared by heat-treating nanodiamond particles. The edge of graphene sheet with its edge carbon atoms being hydrogen-terminated is investigated by UHV-STM/STS. Zigzag edges are found to have non-bonding π-state of edge origin, in good agreement with theoretical prediction. 相似文献