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81.
Preparation of cationic polystyrene latexes has been investigated in the absence of emulsifiers. It is clarified that a stable latex can be obtained by using 2,2′-azobis(2-amidinopropane) hydrochloride as initiator (initiator process). The latex seems to be stabilized with the fragments of the initiator chemically bound to the surface of particles. More stable latexes can be obtained by copolymerizing cationic monomers such as dialkyl aminoethyl methacrylates (copolymerization process). The stability of these latexes may predominantly be attributed to cationic monomers chemically bound to the surface of particles. Stable latexes with high solids content can be obtained by using the two-step polymerization technique in the copolymerization process. The particle formation process in the initiator process and the copolymerization process is discussed. 相似文献
82.
Koichi Hatada Tatsuki Kitayama Shigeru Danjo Yutaka Tsubokura Heimei Yuki Kazuyuki Moriwaki Hiroaki Aritome Susumu Namba 《Polymer Bulletin》1983,10(1-2):45-50
Summary Polymer of α-substituted benzyl methacrylate was found to be used as a new type of positive electron-beam resist, which forms
methacrylic acid units in the polymer chain on the exposure to electron-beam and can be developed using alkaline solution
as a developer. The sensitivity was dependent on the bulkiness of the ester group and the number of ?-hydrogen atoms in the
ester group. The sensitivity and γ-value of atactic poly(α, α-dimethylbenzyl methacrylate) were improved by a factor of more
than three over poly (methyl methacrylate). 相似文献
83.
Carboxylated polystyrene latexes have been prepared by copolymerizing acrylic acid at the appropriate degree of neutralization in the absence or presence of sodium dodecyl sulfate (SDS), and the particle formation process was investigated from the number and uniformity of particles. In the absence of SDS or in a concentration range of SDS lower than 6.41 mmole/l., the formation of particles can predominantly be attributed to the precipitation of growing radicals formed in the aqueous phase; whereas in a concentration range of SDS higher than 6.41 mmole/l., the formation of particles can predominantly be attributed to the initiation of polymerization in the interior of SDS micelles containing solubilized styrene by the collision of growing radicals formed in the aqueous phase. In the former range, the number of particles increases linearly with increasing concentration of SDS below the critical concentration of 1.60 mmole/l., which is sufficient to stabilize particles formed by the precipitation of growing radicals, and remains constant above the critical concentration. The effect of initiator concentration as well as amount of styrene on the formation of particles also supports the particle formation process described above. 相似文献
84.
Kazuyuki Kakegawa Jun-Ichi Mohri Shin-Ichi Shirasaki Koichiro Takahashi 《Journal of the American Ceramic Society》1984,67(1):2-C-3
An organic chelation reagent, cupferron, was used to coprecipitate Ti4+ andZr4+ . After the materials were fired, they were mixed with PbO powder and fired again at high temperatures to obtain Pb(Zr,Ti)03 (PZT). It was confirmed that this method is useful for the preparation of homogeneous PZT having no compositional fluctuations. No coexistence range of the tetragonal and rhombohedral phases was observed in the PZT compositions near the morphotropic phase boundary. 相似文献
85.
Tetsuroh Tokoro Kazuyuki Tohyama Masayuki Nagao Masamitsu Kosaki 《Electrical Engineering in Japan》1992,112(6):10-19
Nonpolar polymers such as polyethylene or polypropylene are widely used as insulation materials, often under conditions involving strong electric fields and high temperatures. Under these conditions, the conduction loss due to DC-like carrier transport may give rise to a high-field AC dissipation factor (tan δ). This paper describes the high-field dielectric properties of polyethylene films at frequencies from 50 to 400 Hz and temperatures from room temperature to 100°C, as measured with a new type electrode design developed by the authors. In the high-temperature region, the AC dissipation current waveform at 50 Hz was also measured. At room temperature, the electric-field dependence of tan δ is almost unaffected by the frequency of the applied field. But at high temperatures and strong electric fields, tan δ tends to have a large field dependence and to be almost inversely proportional to the frequency. Thus the AC conductivity becomes independent of the frequency of the applied field in the region of strong fields and high temperatures. A theoretical analysis shows that the high-field dielectric loss is governed by two processes, namely, the dielectric relaxation loss inherent to the AC field and the DC-like carrier transport loss that becomes prominent in the high-temperature region, where AC dissipation current waveform becomes significantly nonsinusoidal. 相似文献
86.
Kong H. Lee Pat M. Lee Yew S. Siaw Kazuyuki Morihara 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1993,56(4):375-381
Elastase isolated from Pseudomonas aeruginosa IFO 3455 was found to be an efficient protease to catalyse the synthesis of N-benzyloxycarbonyl-aspartyl-phenylalanine methyl ester, the precursor of the dipeptide sweetener, aspartame. The influence of methanol as a cosolvent in this synthetic reaction was investigated. It was found that the synthesis of the dipeptide precursor was most efficient in 25% (v/v) methanol, pH 7·0 at about 25°C for a reaction time of about 3 h. However, the activity of the enzyme was greatly reduced in 90% methanol. The values of K and k2 for N-benzyloxycarbonyl-aspartic acid were 0·17 mol dm?3 and 11·9 mol dm?3 s?1 respectively. 相似文献
87.
88.
Takenori Niioka Hideaki Kagaya Mitsuru Saito Takamitsu Inoue Kazuyuki Numakura Tomonori Habuchi Shigeru Satoh Masatomo Miura 《International journal of molecular sciences》2015,16(1):1840-1854
While CYP3A5 polymorphisms are used to predict the initial dosage of tacrolimus therapy, the predictive capability of genetic information for dosing at early stage post-renal transplantation is unknown. We investigated the influence of polymorphisms over time. An initial oral dose of modified-release once-daily tacrolimus formulation (0.20 mg/kg) was administered to 50 Japanese renal transplant patients every 24 h. Stepwise multiple linear regression analysis for tacrolimus dosing was performed each week to determine the effect of patient clinical characteristics. The dose-adjusted trough concentration was approximately 70% higher for patients with the CYP3A5*3/*3 than patients with the CYP3A5*1 allele before the second pre-transplantation tacrolimus dose (0.97 (0.78–1.17) vs. 0.59 (0.45–0.87) ng/mL/mg; p < 0.001). The contribution of genetic factors (CYP3A5*1 or *3) for tacrolimus dosing showed increased variation from Day 14 to Day 28 after transplantation: 7.2%, 18.4% and 19.5% on Days 14, 21 and 28, respectively. The influence of CYP3A5 polymorphisms on the tacrolimus maintenance dosage became evident after Day 14 post-transplantation, although the tacrolimus dosage was determined based only on patient body weight for the first three days after surgery. Tacrolimus dosage starting with the initial administration should be individualized using the CYP3A5 genotype information. 相似文献
89.
In this paper, we present a novel respirometer using the effect of piezo devices and show its application to triage. We found that blowing on the piezo device generated several 100 mV voltage and also synchronizes with the respiration. Our detailed investigations of the phenomena showed that it was caused by the pyroelectric effect. In general, the piezo device when used as a sensing device generates output voltage in a batteryless manner and also functions as a buzzer, which can lead to a compact, simple and low-power respirometer. Here, the piezo device was used as a base of respirometer and not only as a respirometer, but also as an alarm sound generator. Thus, the proposed respirometer was realized only by one piezo device and a low-powered microprocessor driven by a small battery. We applied the respirometer to triage and realized a triage sensing system. In the system, we employed the triage priority determination procedure defined as an international standard. The triage sensing system set in a mask detects respiration and displays its condition by turning an LED on and off, synchronizing the respiration and also generating the alarm sound when the respiration falls into the pre-specified ill conditions. 相似文献
90.
Takashi Fujikawa Hiroshi Kimura Kazuyuki Kiriyama Kazuhiko Hagiwara 《Catalysis Today》2006,111(3-4):188-193
Cosmo Oil has successfully developed a new CoMo HDS catalyst, C-606A, for production of ultra-low sulfur diesel fuels. This catalyst was prepared by an impregnation method using a solution containing Co, Mo, P, and citric acid on a HY-Al2O3. The resulting catalyst air-dried only without calcination. The HDS activity was measured with straight-run light gas oil feedstocks under industrial hydrotreating conditions. C-606A had a three times higher HDS activity compared with the conventional CoMoP/Al2O3 catalyst. Commercial operation with C-606A has successfully demonstrated high performance. This catalyst has superior activity, which enables <10-ppm sulfur content in products in a commercial hydrotreater designed to produce 500-ppm sulfur diesel fuels. 相似文献