Production of MAG of CLA in a solvent-free system at low temperature with <Emphasis Type="Italic">Candida rugosa</Emphasis> lipase

We attempted to produce MAG of CLA through lipase-catalyzed esterification of a FFA mixture containing CLA (referred to as FFA-CLA) with glycerol. Screening of lipases showed that MAG-CLA was produced efficiently at 5°C with Penicillium camembertii, Rhizopus oryzae, and Candida rugosa lipases. Among them, C. rugosa lipase was selected because the lipase is widely used as a catalyst for oils and fats processing. The reaction was conducted with agitation of a 300-g mixture of FFA-CLA/glycerol (1∶5, mol/mol), a 200-U/g mixture of C. rugosa lipase, and 2% water. When the reaction was conducted at 30°C, the esterification scarcely proceeded, owing to inhibition of the reaction by glycerol. But the reaction at 5°C eliminated the inhibition and produced MAG efficiently: The degree of esterification reached 93.8% after 58 h, and MAG content in the reaction mixture was 88.4 wt%. To reduce the reaction time, the reactor was connected with a vacuum pump after 24 h, and the reaction was continued with dehydration at 5 mm Hg. The degree of esterification reached 94.7% after 24 h of dehydration (48 h in total), and MAG content increased to 93.0 wt%. Candida rugosa lipase acted a little more strongly on cis-9, trans-11 CLA than on trans-10,cis-12 CLA, but the contents of the two isomers in MAG obtained from a 48-h reaction were the same as the contents in FFA-CLA.     

Physical Properties and Structure of rf-Sputtered Amorphous Films in the System Al2O3–Y2O3

Amorphous films in the system Al₂O₃–Y₂O₃ were prepared by the rf sputtering method in the range of 0–76 mol% Y₂O₃, and their density, refractive index, and elastic constants were measured. All of the physical properties of the amorphous Al₂O₃–Y₂O₃ films had a similar compositional dependence; that is, they increased continuously, but not linearly with increasing Y₂O₃ content. To confirm the coordination states of aluminum and yttrium ions in the amorphous Al₂O₃–Y₂O₃ films, the Al K α X-ray emission spectra and the X-ray absorption near edge structures (XANES) were measured. The average coordination number of aluminum ions in the amorphous films containing up to about 40 mol% Y₂O₃ content was 5, that is a mixture of 4-fold- and 6-fold-coordinated states. In the region of more than about 50 mol% Y₂O₃, the fraction of the 6-fold-coordinated aluminum ions increased with increasing Y₂O₃ content, while the results led to the conclusion that the coordination number of yttrium ions was always 6, regardless of composition. These results indicate that, in amorphous films in the system Al₂O₃–Y₂O₃, the change of the coordination state of aluminum ions has an important effect on physical properties.     

Development of x-ray laminography under an x-ray microscopic condition

An x-ray laminography system under an x-ray microscopic condition was developed to obtain a three-dimensional structure of laterally-extended planar objects which were difficult to observe by x-ray tomography. An x-ray laminography technique was introduced to an x-ray transmission microscope with zone plate optics. Three prototype sample holders were evaluated for x-ray imaging laminography. Layered copper grid sheets were imaged as a laminated sample. Diatomite powder on a silicon nitride membrane was measured to confirm the applicability of this method to non-planar micro-specimens placed on the membrane. The three-dimensional information of diatom shells on the membrane was obtained at a spatial resolution of sub-micron. Images of biological cells on the membrane were also obtained by using a Zernike phase contrast technique.     

具有反射率及亮度补偿功能的光纤振动计

介绍了一种结构简单、价格低、带有反射率和亮度补偿的光纤振动计。该光纤式振动计由发光二极管、光纤探头和两个光子探测器组成。光纤探头的光纤束分为三部分：一根发射光纤、第一邻近接收光纤组（组A）、第二邻近接收光纤组（组B）。光纤组A和光纤组B的输出信号平均值的比值取决于光纤探头和被测表面之间的平均距离，而与被测表面的反射率及亮度无关。根据这一比值可以实现探头与被测表面间距离的估计。然后根据光纤组A和B的标定曲线，对振动计的灵敏度进行了补偿。因为在比值运算中使用的是平均值，所以振动频率的提高不会限制这一技术的使用。实验结果表明，这一方法适宜于动态测量，可以实现被测表面反射率、入射亮度及探头与被测表面间平均距离的补偿。     

Factors influencing species diversity of ferns and fern allies in fragmented forest patches in the Kyoto city area

We investigated the relationship between species diversity of pteridophytes and the environmental factors of 39 fragmented forest patches in the Kyoto city area. There was a significant correlation between the number of species and the micro-landform diversity, artificial habitat diversity, and logarithm of the area of the forest patch. When we performed a multiple regression analysis to identify the best-fit model so as to optimize the amount of variation in species diversity explained by using stepwise selection, three species diversity indices (species richness or Shannon’s diversity index, logarithm of inverse Simpson index) had significant positive partial correlations with the logarithm of area of the forest patch, and negative correlations with the logarithm of isolation distance from mountain forest. Therefore, we conclude that pteridophyte species diversity depends on patch size and isolation distance from mountain forests. Comparison of the woody plant species–area curve with the pteridophyte species–area curve showed that the rate of increase of species number (inclination) with area was the same, but the Y-intercept of the pteridophyte species–area curve was lower than that of the woody plant curve. Therefore, the minimum conservation area required for ferns and fern allies is greater than that for woody plant species.     

Transmission analysis of electromagnetic induction RFID system

The transmission characteristics of the electromagnetic induction RFID systems are greatly influenced by the distance between the primary and secondary antenna coils and by the materials used in their design. In this paper the induced current of the secondary antenna coil is calculated by the 3D finite element method when both the primary and secondary antenna coils are operated in resonant circuits. The influences of the analyzed parameters on the transmission characteristics are demonstrated. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 173(4): 38–45, 2010; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21019     

The production of an electrochemical capacitor electrode using holey single-wall carbon nanohorns with high specific surface area

We prepared single-wall carbon nanohorns (SWCNHs) with a high specific surface area and fabricated an electrochemical capacitor electrode with good performance from them. Carbon impurities involved in the as-grown SWCNHs were thoroughly removed and the purified SWCNHs were oxidized to produce holes in them (SWCNHox). The specific surface area was estimated as 1720 m²/g, the largest surface area of SWCNHs ever reported. Capacitive properties were also investigated using the obtained SWCNHox. We found that an electrochemical device with SWCNHox showed an excellent specific capacitance of about 100 F/g, accelerating industrial progress for their uses in energy and environmental fields.     

Fabrication of flexible UV nanoimprint mold with fluorinated polymer-coated PET film

UV curing nanoimprint lithography is one of the most promising techniques for the fabrication of micro- to nano-sized patterns on various substrates with high throughput and a low production cost. The UV nanoimprint process requires a transparent template with micro- to nano-sized surface protrusions, having a low surface energy and good flexibility. Therefore, the development of low-cost, transparent, and flexible templates is essential. In this study, a flexible polyethylene terephthalate (PET) film coated with a fluorinated polymer material was used as an imprinting mold. Micro- and nano-sized surface protrusion patterns were formed on the fluorinated polymer layer by the hot embossing process from a Si master template. Then, the replicated pattern of the fluorinated polymer, coated on the flexible PET film, was used as a template for the UV nanoimprint process without any anti-stiction coating process. In this way, the micro- to nano-sized patterns of the original master Si template were replicated on various substrates, including a flat Si substrate and curved acryl substrate, with high fidelity using UV nanoimprint lithography.