Vanadium oxide supported γ-alumina with bimodal porous structure for intra-particle diffusion enhancement in styrene oxidation reaction

Porous γ-alumina with well arranged secondary mesopores has been contrived using nanosized templating units. The pore size of templated mesopores is precisely controlled as the pore shrinkage is insignificant. The primary pore diameter is ca. 4 nm and the secondary pore diameter is ca. 50 nm. The porous material was characterized using N₂ adsorption/desorption, TEM, XRD and FT-IR. γ-alumina with bimodal pore size distribution shows improved intra-particle diffusion compared to γ-alumina with unimodal pore size distribution in a simple dye adsorption test. γ-alumina with different porous structures were then impregnated with vanadium oxide for catalytic effect comparison. It was perceived that secondary pores improve the styrene oxidation rate after the conversion of styrene reaches 30%.     

Chitosan Functionalized with Carboxyl Groups as a Recyclable Biomaterial for the Adsorption of Cu (II) and Zn (II) Ions in Aqueous Media

The modification of chitosan represents a challenging task in obtaining biopolymeric materials with enhanced removal capacity for heavy metals. In the present work, the adsorption characteristics of chitosan modified with carboxyl groups (CTS-CAA) towards copper (II) and zinc (II) ions have been tested. The efficacy of the synthesis of CTS-CAA has been evaluated by studying various properties of the modified chitosan. Specifically, the functionalized chitosan has been characterized by using several techniques, including thermal analyses (differential scanning calorimetry and thermogravimetry), spectroscopies (FT-IR, XRD), elemental analysis, and scanning electron microscopy. The kinetics and the adsorption isotherms of CTS-CAA towards both Cu (II) and Zn (II) have been determined in the aqueous solvent under variable pH. The obtained results have been analyzed by using different adsorption models. In addition, the experiments have been conducted at variable temperatures to explore the thermodynamics of the adsorption process. The regeneration of CTS-CAA has been investigated by studying the desorption process using different eluents. This paper reports an efficient protocol to synthesize chitosan-based material perspective as regenerative adsorbents for heavy metals.     

Modification of Rice Starch through Thermal Treatment with Urea

Modification of starch with urea was carried out at 165 °C according to solid state, paste and film techniques. With the solid state and paste techniques the extent of the reaction, expressed as % N, increased by increasing the time of treatment. Samples prepared by the film technique showed, during the first 15 min reaction time, significantly higher nitrogen content which, however, decreased by prolongation of the treatment. Infra-red spectrum of the reaction products indicated involvement of both starch and urea in a chemical reaction. Examination of the swelling properties of the products revealed that these properties are dependent upon the technique used for preparation rather than the extent of the reaction. Samples prepared by the paste and film techniques acquired higher apparent viscosity than those prepared by the solid state technique irrespective of the rate of shear. For a given rate of shear, the apparent viscosity increases by increasing the temperature.     

Performance Analysis and Optimization Based on Adaptive Modulation and Chaotic Interleaving for Helicopter-Satellite Communications

Overcoming periodic blockage of the received signal and the carrier frequency fluctuations caused by rotor blades and Doppler shift, respectively, are considered the most challenging issues in helicopter-satellite communication systems. In this study, we propose an automatic frequency control method based on an adaptive modulation scheme. We employ a hybrid modulation not only depending on quadrature phase shift keying, but also based on binary phase shift keying for accurate cancellation of periodic blockage. On the other hand, we apply a chaotic interleaving scheme with a hybrid modulation scheme in order to achieve a better Bit Error Rate (BER) performance in LOS and NLOS environments. Finally, we validate the mathematical analysis of the proposed scheme through simulations. We evaluated the performance of the proposed scheme and performed a comparison with conventional schemes. Our results show that the proposed scheme is significantly capable of reducing the acquisition time and working with various velocities of helicopter blades in addition to providing a better BER performance in shadow fading environments.     

Amphiphilic Pentablock Copolymers Prepared from Pluronic and ε-Caprolactone by Enzymatic Ring Opening Polymerization

Amphiphilic copolymers are appealing materials because of their interesting architecture and tunable properties. In view of their application in the biomedical field, the preparation of these materials should avoid the use of toxic compounds as catalysts. Therefore, enzymatic catalysis is a suitable alternative to common synthetic routes. Pentablock copolymers (CUC) were synthesized with high yields by ring-opening polymerization of ε-caprolactone (ε-CL) initiated by Pluronic (EPE) and catalyzed by Candida antarctica lipase B enzyme. The variables to study the structure–property relationship were EPEs’ molecular weight and molar ratios between ε-CL monomer and EPE macro-initiator (M/In). The obtained copolymers were chemically characterized, the molecular weight determined, and morphologies evaluated. The results suggest an interaction between the reaction time and M/In variables. There was a correlation between the differential scanning calorimetry data with those of X-ray diffraction (WAXD). The length of the central block of CUC copolymers may have an important role in the crystal formation. WAXD analyses indicated that a micro-phase separation takes place in all the prepared copolymers. Preliminary cytotoxicity experiments on the extracts of the polymer confirmed that these materials are nontoxic.     

Thermodynamic interpretation of solute–polymer interactions at infinite dilution

Heats of solution at infinite dilution of solutes in poly(ethyl methacrylate) were estimated using gas–liquid chromatography over a temperature range of 417.74 K–427.55 K. The heat of solution is related to solute polarizability and dipole moment. Contributions of specific interactions such as hydrogen bonding and charge-transfer complexing to the enthalpy of solution were also determined.     

Effect of Gamma Rays on Starch Extracted from Irradiated Wheat Flour

Irradiated starch was more retrograded than the unirradiated samples. The amylose fractions were increased on the expence of the amylopectin fractions of starch under the influence of gamma rays. Oxidation of starch with periodate ions was enhanced by gamma irradiation as indicated by the formation of greater amounts of formic acid in the irradiated samples. This result indicated that destruction in amylopectin had occured and formed small branched fragments. The decrease in intrinsic viscosity due to radiation, showed a straight line relation, when plotted versus irradiation doses, with a slope of 5.2 × 10⁻⁷. This indicates that a specific slope could be obtained which characterized gamma ray doses on wheat flour.     

Synthesis of telechelic monodispersed diols

Summary The synthesis of telechelic monodispersed diols produced from the radical telomerization of an excess of undecylenol with commercialy available , -dithiols HSC₂H₄XC₂H₄SH (X=0, S or CH₂) initiated by peroxides is presented. In each case, the diols were obtained selectively and quantitatively and they were characterized by both ¹H and ¹³C NMR. Their physical characteristics (Tg, T_m and decomposition temperatures) were determined. Such compounds are thermally more stable than polydispersed telechelic commercially available diols.     

Polymer electrolyte membrane modification in direct ethanol fuel cells: An update

Direct ethanol fuel cells (DEFCs) offer a high degree of design flexibility, ranging from a single cell to a massive multi-cell that can be used in various applications, including portable devices, transportation, and stationary applications. Unfortunately, the most significant barrier to the commercialization of DEFCs is getting low-cost and ethanol permeability, high conductivity performance, and extended durability of polymer electrolyte membranes, as key components that highly influence the overall performance. In this paper, the recent progress in developing the polymer electrolyte membrane for the application of DEFCs has been comprehensively reviewed. Focusing on an updated modification of polymeric materials in the last 5 years, including Nafion-based membrane, polyvinyl alcohol-based membrane, polybenzimidazoles-based membrane, chitosan-based membrane, and sodium alginate-based membrane, as well as factors and challenges that affected the performance of polymer electrolyte membranes have been discussed, including the main characterization, catalyst selection, cell design, and work in membrane and cell performance of DEFCs. All discussion addresses the strategy to improve the performance of polymer electrolyte membranes in DEFCs in order to penetrate the commercialization stages.