Graft copolymerization of vinyl monomers on modified cottons. VI. Vinyl graft copolymerization initiated by manganese (IV)

The ability of potassium permanganate in the presence of different acids to induce grafting of methyl methacrylate and acrylonitrile onto sodium hydroxide-treated cotton, partially carboxymethylated cotton, partially cyanoethylated cotton, and partially acetylated cotton was investigated. The copolymerization reaction was carried out under a variety of conditions. The graft yields are greatly enhanced by increasing concentration of monomer, reaction time, and temperature. The opposite holds true for initiator at higher concentrations. The effectiveness of the acids was: nitric acid > sulfuric acid > perchloric acid > hydrochloric acid. The change in the physical and/or chemical structure of cellulose by its modification via etherification reaction or esterification reaction had a significant effect on the susceptibility of cellulose toward grafting. While partial carboxymethylation or partial cyanoethylation of cellulose prior to grafting increased the graft yield, partial acetylation caused a decrease.     

Graft polymerization of methyl methacrylate onto wool using dimethylaniline/copper(II) system

Dimethylaniline (DMA)/Cu^II-induced grafting of methyl methacrylate (MMA) onto wool fibres was studied under different conditions. The grafting reaction was found to be influenced by Cu^II, DMA, and MMA concentrations as well as polymerization temperature, reaction time, and polymerization medium. While the graft yield increased by increasing the amount of MMA from 100 to 500 mmol/L, maximum grafting occurred at 0.5 mmol/L CuSO₄, 10 mmol/L DMA. The graft yield increased by increasing the reaction time from 15 to 150 min and by raising the polymerization temperature from 60 to 80°C. Using dimethylformamide/water and ethyl alcohol/water mixture as a medium for grafting decreased the graft yield, while using isopropyl alcohol/water mixtures increased the graft yield as compared to pure aqueous medium.     

Heat transfer and fluid flow characteristics in flash desalination units

The present work investigates the effects of different operating and geometrical parameters on the flashing efficiency of water in a single stage flashing chamber. This chamber uses a submerged rectangular orifice as flow control area. Experiments were performed to investigate the effects of flow rate, liquid level in the flashing chamber, liquid inlet temperature and flashing range, on the flashing efficiency under various design conditions. These comprise flow with baffle placed in the flashing chamber, and wire meshes placed at the orifice to increase the turbulence level.It was found that the efficiency increased with the increase of the turbulence levels, flashing range and liquid inlet temperature; the efficiency deceased with the increase of the flow rate and liquid level in the flashing chamber. The application of numerical procedure to predict flow pattern and heat transfer in the flashing chamber is introduced as a powerful design tool.     

Eco-friendly electronics,based on nanocomposites of biopolyester reinforced with carbon nanotubes: a review

ABSTRACT

Fabrication of electronic materials from nanocomposite of biopolyesters reinforced with carbon nanotubes can be regarded as the effective alternative for conventional nanocomposites consisting of non-biodegradable polymers. Commercial availability of biopolyester-based nanocomposites is limited because of their high cost compared to other polymers, but the factor of their compostable nature is worthless for environmental protection. Such nanocomposites have potential applications in biodegradable sensors, EMI materials, etc. In this review, the current progress of biopolyester/CNTs nanocomposites in the field of biodegradable electronics is reviewed and also the impact of CNTs dispersion on electrical, thermal and mechanical properties of eco composites is stipulated.     

Synthesis and properties of new poly(amide imide)s containing trimellitic rings and hydantoin moieties in the main chain under microwave irradiation

Trimellitic anhydride was reacted with 4,4′‐diaminodiphenyl ether in a mixture of acetic acid and pyridine (3 : 2) at room temperature and was refluxed at 90–100°C, and N,N′‐(4,4′‐diphenylether) bistrimellitimide (3) was obtained in a quantitative yield. 3 was converted into N,N′‐(4,4′‐diphenylether) bistrimellitimide diacid chloride (4) by a reaction with thionyl chloride. Then, six new poly(amide imide)s were synthesized under microwave irradiation with a domestic microwave oven through the polycondensation reactions of 4 with six different derivatives of 5,5‐disubstituted hydantoin in the presence of a small amount of a polar organic medium such as o‐cresol. The polycondensation proceeded rapidly and was completed within 7–10 min, producing a series of new poly(amide imide)s in high yields with inherent viscosities of 0.27–0.66 dL/g. The resulting poly(amide imide)s were characterized by elemental analysis, viscosity measurements, differential scanning calorimetry, thermogravimetric analysis, derivative thermogravimetry, solubility testing, and Fourier transform infrared spectroscopy. All the polymers were soluble at room temperature in polar solvents such as N,N‐dimethylacetamide, N,N‐dimethylformamide, dimethyl sulfoxide, tetrahydrofuran, and N‐methyl‐2‐pyrrolidone. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3447–3453, 2004     

Sensor Fault Diagnosis and Unknown Disturbances Estimation of High Switching Frequency Single-phase PWM Rectifier

International Journal of Control, Automation and Systems - The fault and disturbances estimation has an important role in the modern traction railway system. This paper proposes a unique method for...     

Surface Modification of Ready-to-Use Hollow Fiber Ultrafiltration Modules for Oil/Water Separation

Reusing wastewater from oil-related industries is becoming increasingly important, especially in water-stressed oil-producing countries. Before oily wastewater can be discharged or reused, it must be properly treated, e.g., by membrane-based processes like ultrafiltration. A major issue of the applied membranes is their high fouling propensity. This paper reports on mitigating fouling inside ready-to-use ultrafiltration hollow-fiber modules used in a polishing step in oil/water separation. For this purpose, in-situ polyzwitterionic hydrogel coating was applied. The membrane performance was tested with oil nano-emulsions using a mini-plant system. The main factors influencing fouling were systematically investigated using statistical design of experiments.     

Performance tuning of glass fiber/epoxy composites through interfacial modification upon integrating with dendrimer functionalized graphene oxide

In this study, glass fiber/epoxy composites were interfacially tailored by introducing polyamidoamine (PAM) dendrimer functionalized graphene oxide (GO) into epoxy matrix. Two different composites each containing varying loading fraction (0.5, 1.0, and 1.5 wt%) of GO and GO-PAM were fabricated via hot press processing. Composites were evaluated for interlaminar shear strength (ILSS), dynamic mechanical properties and thermal conductivity. The inclusion of 1.5 wt% GO-PAM resulted ~57.3%, ~42.7%, and ~54% enhancement in ILSS, storage modulus and thermal conductivity, respectively. Almost, ~71% reduction in coefficient of thermal expansion was also observed at same GO-PAM loading. Moreover, higher glass transition temperature was observed with GO-PAM addition. GO-PAM substantially improved fiber/matrix interfacial adhesion, which was witnessed through scanning electron microscopy. The enhanced thermo-mechanical performance was attributed to interfacial covalent interactions engendered by ring opening reaction between epoxy and amine moieties of PAM dendrimers. These multiscale composites with extraordinary functional properties can outperform conventional counterparts with improved reliability and performance.     

Your comments matter: incorporating viewers’ comments for ranking online video content using bibliometrics

ABSTRACT

The quality of user-generated content over World Wide Web media is a matter of serious concern for both creators and users. To measure the quality of content, webometric techniques are commonly used. In recent times, bibliometric techniques have been introduced to good effect for evaluation of the quality of user-generated content, which were originally used for scholarly data. However, the application of bibliometric techniques to evaluate the quality of YouTube content is limited to h-index and g-index considering only views. This paper advocates for and demonstrates the adaptation of existing Bibliometric indices including h-index, g-index and M-index exploiting both views and comments and proposes three indices h_vc, g_vc and m_vc for YouTube video channel ranking. The empirical results prove that the proposed indices using views along with the comments outperform the existing approaches on a real-world dataset of YouTube.