Solar Energy Triggered Clean Water Harvesting from Humid Air Existing above Sea Surface Enabled by a Hydrogel with Ultrahigh Hygroscopicity

Water scarcity is a ubiquitous problem with its magnitude expected to rise in the near future, and efforts to seek alternative water sources are on the rise. Harvesting water from air has intrigued enormous research interest among many groups with Scientific American listing this technology as the second most impactful technology that can bring about a massive change in people's lives. Though desalination offers a huge prospect in mitigating water crisis, its practicality is limited by exorbitant energy requirement. Alternatively, the air above sea water is moisture rich, with the quantity of vapor increasing at the rate of 0.41 kg m^?2. Herein, a method to sustainably harvest water from this moisture rich zone is demonstrated by employing a nanoporous superhygroscopic hydrogel, which is capable of absorbing water from highly humid atmospheres by over 420% (highest) of its own weight. The desorption process from the hydrogel, occurring at 55 °C (lowest), is triggered by natural sunlight (A.M 1.5) thereby ensuing an external energy‐less water harvesting approach. The hydrogel exhibits excellent stability even after 1000 absorption/desorption cycles. Through multiple absorption/desorption cycles, it is possible to harvest over 10 L water per kg of hydrogel daily.     

FERNN: An Algorithm for Fast Extraction of Rules from Neural Networks

Before symbolic rules are extracted from a trained neural network, the network is usually pruned so as to obtain more concise rules. Typical pruning algorithms require retraining the network which incurs additional cost. This paper presents FERNN, a fast method for extracting rules from trained neural networks without network retraining. Given a fully connected trained feedforward network with a single hidden layer, FERNN first identifies the relevant hidden units by computing their information gains. For each relevant hidden unit, its activation values is divided into two subintervals such that the information gain is maximized. FERNN finds the set of relevant network connections from the input units to this hidden unit by checking the magnitudes of their weights. The connections with large weights are identified as relevant. Finally, FERNN generates rules that distinguish the two subintervals of the hidden activation values in terms of the network inputs. Experimental results show that the size and the predictive accuracy of the tree generated are comparable to those extracted by another method which prunes and retrains the network.     

Strong,Compressible, and Ultrafast Self-Recovery Organogel with In Situ Electrical Conductivity Improvement

Coordination complexes are widely used to tune the mechanical behaviors of polymer materials, including tensile strength, stretchability, self-healing, and toughness. However, integrating multivalent functions into one material system via solely coordination complexes is challenging, even using combinations of metal ions and polymer ligands. Herein, a single-step process is described using silver-based coordination complexes as cross-linkers to enable high compressibility (>85%). The resultant organogel displays a high compressive strength (>1 MPa) with a low energy loss coefficient (<0.1 at 50% strain). Remarkably, it demonstrates an instant self-recovery at room temperature with a speed >1200 mm s⁻¹, potentially being utilized for designing high-frequency-responsive soft materials (>100 Hz). Importantly, in situ silver nanoparticles are formed, effectively endowing the organogel with high conductivity (550 S cm⁻¹). Given the synthetic simplification to achieve multi-valued properties in a single material system using metal-based coordination complexes, such organogels hold significant potential for wearable electronics, tissue-device interfaces, and soft robot applications.     

Avoiding the uncanny valley: robot appearance,personality and consistency of behavior in an attention-seeking home scenario for a robot companion

This article presents the results of video-based Human Robot Interaction (HRI) trials which investigated people’s perceptions of different robot appearances and associated attention-seeking features and behaviors displayed by robots with different appearance and behaviors. The HRI trials studied the participants’ preferences for various features of robot appearance and behavior, as well as their personality attributions towards the robots compared to their own personalities. Overall, participants tended to prefer robots with more human-like appearance and attributes. However, systematic individual differences in the dynamic appearance ratings are not consistent with a universal effect. Introverts and participants with lower emotional stability tended to prefer the mechanical looking appearance to a greater degree than other participants. It is also shown that it is possible to rate individual elements of a particular robot’s behavior and then assess the contribution, or otherwise, of that element to the overall perception of the robot by people. Relating participants’ dynamic appearance ratings of individual robots to independent static appearance ratings provided evidence that could be taken to support a portion of the left hand side of Mori’s theoretically proposed ‘uncanny valley’ diagram. Suggestions for future work are outlined.

The analysis and applications of adaptive-binning color histograms

Histograms are commonly used in content-based image retrieval systems to represent the distributions of colors in images. It is a common understanding that histograms that adapt to images can represent their color distributions more efficiently than do histograms with fixed binnings. However, existing systems almost exclusively adopt fixed-binning histograms because, among existing well-known dissimilarity measures, only the computationally expensive Earth Mover’s Distance (EMD) can compare histograms with different binnings. This paper addresses the issue by defining a new dissimilarity measure that is more reliable than the Euclidean distance and yet computationally less expensive than EMD. Moreover, a mathematically sound definition of mean histogram can be defined for histogram clustering applications. Extensive test results show that adaptive histograms produce the best overall performance, in terms of good accuracy, small number of bins, no empty bin, and efficient computation, compared to existing methods for histogram retrieval, classification, and clustering tasks.     

Sorption of chromium (VI) by spent grain under batch conditions

Batch experiments were performed to evaluate the ability of spent grain to remove chromium (VI) from aqueous solution. Parameters investigated include pH, contact time, sorbent dosage, agitation rate, and the presence of other anions. Application of the Langmuir isotherm to the Cr(VI)–spent grain system provided a maximum sorption capacity of 18.94 mg/g. This value compares favorably with other reported values for low‐cost materials. Anions such as phosphate, arsenate, nitrate, and sulfate were antagonistic toward the uptake of Cr(VI) by spent grain. It was successful in removing Cr(VI) from a sample of electroplating waste. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 2128–2134, 2001     

Fabrication of flexible carbon dioxide gas sensor with conductive polymer/reduced graphene oxide hybrids: Effects of substrate type and mass ratio

Flexible gas sensors made of polyaniline (PANI)-reduced graphene oxide (rGO) nanocomposite were prepared using three different substrates, namely filter paper, cotton fabric, and weighing paper, through in-situ reduction of GO and in-situ polymerization of aniline. Preliminary analysis showed that the PANI/rGO coated on filter paper possesses a superior electrical conductance than PANI/rGO coated on cotton fabric and weighing paper. Such observation was attributed to the good attachment of the PANI/rGO nanocomposites onto the high-density mesh-like structure of the filter paper with rough surfaces. In contrast, PANI/rGO coated onto weighing paper and cotton fabric of different surface structures presented lower-to-almost negligible conductance. Accordingly, PANI/rGO filter paper was selected for the subsequent evaluation of gas sensing properties. The gas-sensing performances of the PANI/rGO filter paper sensors indicated that the 5 wt% PANI/rGO (i.e., 5 wt% rGO) sample exhibited the best response of 306% for 500 ppm carbon dioxide (CO₂) gas at room temperature with a recovery rate of 41.5%. On the other hand, the optimum recovery rate of 59.5% was identified at 0.5 wt% PANI/rGO sample which exhibited a response of 155%. Owing to the synergy effect, the PANI/rGO sensor outperformed the sensor made of pure PANI or pure rGO.     

Preliminary study of a polycaprolactone membrane utilized as epidermal substrate

Solvent-cast sheets of polycaprolactone were biaxially stretched to produce 10–15 m thick films. PCL films were found to have a tensile strength of 55 MPa which is about two and a half times stronger than native skin. One of our previous studies using non-coated PCL membranes showed that only 36% of the membrane surface was covered with keratinocytes after 9 days of culture. The present study examined the effects of coating the surface of PCL membranes with fibrin on the proliferation of keratinocytes. Qualitative analysis revealed that the cells attached and proliferated better on coated PCL films. Keratinocytes exhibited healthy cobblestone morphology and proliferated as continuous monolayers over a period of 16 days. The results indicated that fibrin coated PCL films would support the attachment and proliferation of human keratinocytes and have the potential to be applied as a matrix material for tissue engineering an epidermal equivalent.     

H(2)O(2)/UV degradation kinetics of isoprene in aqueous solution

Hydrogen peroxide and UV radiation have been used in the photochemical degradation of isoprene in aqueous solutions. A kinetic study is carried out taking into account the contribution of the UV radiation reaction and the combined reaction with hydrogen peroxide. An empirical reaction rate expression, which considers the two reactions taking place in parallel, is suggested. Pseudo-first order rate constants are obtained from batch reactor data. As the molar ratio of H(2)O(2):isoprene increases, the rate of reaction increases linearly while the concentration of H(2)O(2) is observed to be nearly constant throughout the reaction; suggesting that the H(2)O(2) acts as a pseudo-catalyst. Nearly complete oxidation of isoprene is achieved. These results indicate that the H(2)O(2)/UV process appears to be a competitive alternative destructive treatment for removing isoprene from water present at low levels.     

Characteristics of rain and ice depolarization for a 19- and 28-GHz propagation path from a Comstar satellite

Relationships between rain and ice attenuation and depolarization for several incident polarizations have been determined experimentally for the first time. The relationships are based on measurements made using 19- and 28-GHz beacon transmissions from a Comstar satellite. Vertical and horizontal incident polarizations experience much less depolarization on the average than circular polarization or linear polarization incident at45deg. The measurements confirm that the usual orientations of the major symmetry axes of nonspherical raindrops and ice crystals are nearly horizontal. Joint cumulative distributions of attenuation and depolarization for one year of continuous measurement at 19 and 28 GHz are also presented. These distributions are useful for determining joint attenuation and depolarization margins required to meet outage objectives of specific satellite communication systems. For example, the outage of a 19-GHz dual-polarized system received with a polarization angle21degfrom horizontal and having an attenuation margin of 20 dB would be depolarization-dominated unless the system could also tolerate at least -15-dB depolarization.