全文获取类型
收费全文 | 62408篇 |
免费 | 15498篇 |
国内免费 | 93篇 |
专业分类
电工技术 | 1059篇 |
综合类 | 72篇 |
化学工业 | 22931篇 |
金属工艺 | 877篇 |
机械仪表 | 1221篇 |
建筑科学 | 3522篇 |
矿业工程 | 168篇 |
能源动力 | 1546篇 |
轻工业 | 9370篇 |
水利工程 | 479篇 |
石油天然气 | 100篇 |
武器工业 | 1篇 |
无线电 | 8331篇 |
一般工业技术 | 15846篇 |
冶金工业 | 3825篇 |
原子能技术 | 172篇 |
自动化技术 | 8479篇 |
出版年
2023年 | 169篇 |
2022年 | 354篇 |
2021年 | 769篇 |
2020年 | 1740篇 |
2019年 | 3482篇 |
2018年 | 3565篇 |
2017年 | 3830篇 |
2016年 | 4414篇 |
2015年 | 4415篇 |
2014年 | 4541篇 |
2013年 | 6527篇 |
2012年 | 3814篇 |
2011年 | 3954篇 |
2010年 | 3769篇 |
2009年 | 3555篇 |
2008年 | 3391篇 |
2007年 | 3075篇 |
2006年 | 2646篇 |
2005年 | 2326篇 |
2004年 | 2189篇 |
2003年 | 2048篇 |
2002年 | 1960篇 |
2001年 | 1530篇 |
2000年 | 1486篇 |
1999年 | 924篇 |
1998年 | 538篇 |
1997年 | 482篇 |
1996年 | 417篇 |
1995年 | 367篇 |
1994年 | 380篇 |
1993年 | 374篇 |
1992年 | 324篇 |
1991年 | 268篇 |
1990年 | 280篇 |
1989年 | 277篇 |
1988年 | 231篇 |
1987年 | 231篇 |
1986年 | 221篇 |
1985年 | 299篇 |
1984年 | 268篇 |
1983年 | 231篇 |
1982年 | 218篇 |
1981年 | 239篇 |
1980年 | 163篇 |
1979年 | 190篇 |
1978年 | 185篇 |
1977年 | 191篇 |
1976年 | 178篇 |
1975年 | 162篇 |
1974年 | 159篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
901.
Jan‐Chan Huang 《应用聚合物科学杂志》2004,94(4):1547-1555
Experimental values of Flory–Huggins parameters, χ, between polymers and probes, are frequently used to determine the solubility parameters of the polymers by the method of DiPaola–Baranyi and Guillet. The solubility parameters of probes were usually estimated by using heat of vaporization. When χ is measured at a temperature near the critical temperature of the probes and used to determine the solubility parameter of polymers, the departure of enthalpy of the probe vapor from the ideal gas state should be considered. This study discussed the method to make the correction and its effect on the determination solubility parameter of polymers. Without correction in the vapor phase enthalpy, the solubility parameters of the probes and polymer tend to be underestimated and the error increases when the critical temperature is approaching. Analytical expressions for the effect of correction on the solubility parameter of probes and parameters of polymers were derived. By use of probes with a range of solubility parameters on both sides of the solubility parameter of polymers, the correlation between parameters of polymers was shown to be reduced. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1547–1555, 2004 相似文献
902.
Temperature measurements have been performed in the process of electron‐beam curing of EB‐I and EB‐II epoxy resin systems. The influence of initiator content, resin type, and dose rate on the temperature of the systems was studied. Transverse and longitudinal temperatures of samples in the glass vessel were also analyzed. The nature of temperature curves varied with the different epoxy resin systems in the steel mold, but did not change with different contents of the initiator. At the same time, the heat had no effect on the gel fraction of epoxy resin systems. The temperature curve was greatly affected by the dose rate, and its peak value, peak width, and plateau value also increased with it. The transverse temperature of EB‐II glass vessel samples increased as the radiation dose increased and, in the same sample, the temperature reduced as the distance between the radiation center and the test point increased. The longitudinal temperature of EB‐I and EB‐II resin systems in a glass vessel decreased as the radiation depth increased. As the radiation dose increased, the temperature of the EB‐I resin system increased simultaneously, while that of the EB‐II resin system initially increased and then kept constant when the dose reached a certain value. The temperatures of these two resin systems decreased rapidly when the radiation process stopped. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2217–2222, 2004 相似文献
903.
Identification and elimination by site-directed mutagenesis of thermolabile aspartyl bonds in Aspergillus awamori glucoamylase 总被引:2,自引:0,他引:2
Chen Hsiu-mei; Ford Clark; Reilly Peter J. 《Protein engineering, design & selection : PEDS》1995,8(6):575-582
Both Dative Aspergillus niger glucoamylase and wild-type Aspergillusawamori glucoamylase expressed in Saccharo-myces cerevisiae,which have identical primary structures, undergo hydrolysisat aspartyl bonds at low pH values and elevated temperatures.In native A.niger enzyme the Aspl26Glyl27 bond was preferentiallycleaved at pH 3.5,while at pH 4.5 cleavage of the Asp257Pro258and Asp293Gly294 bonds was dominant. In wild-type A.awamoriglucoamylase, cleavage of the latter was dominant at both pH3.5 and 4.5. Site-directed mutations Aspl26Glu and Glyl27Alain wild-type enzyme decreased specific activities by 60 and30%, respectively, and increased irreversible thermoinactivationrates 3- to 4-fold at pH 4.5. Replacement of Asp257 with Gluand Asp293 with Glu or Gin decreased specific activities by20%, but greatly reduced cleavage of the Asp257Pro258and Asp293Gly294 bonds. The Asp257Glu mutant was producedvery slowly and was more thermostable than wildtype glucoamylaseat pH 4.5up to 70°C. Replacement of Asp293 with either Gluor Gln significantly raised protein production and slightlyincreased thermostability at pH 3.5 and 4.5, but not at pH5. 相似文献
904.
Mei‐Rong Huang Sheng‐Xian Li Zhi‐Qing Dong Wei Feng Xin‐You Wang Shu‐Ying Gu Yan‐Hui Wu Xiang‐An Huang 《应用聚合物科学杂志》2002,83(14):3013-3021
Several multilayer thin low‐density polyethylene (LDPE) films were fabricated by blown thin film having a thickness of 7 μm and an area of 130 cm2. They were characterized for their oxygen‐enrichment performance from air by a constant pressure–variable volume method in a round permeate cell with an effective area of 73.9 cm2. The relationship between oxygen‐enrichment properties, including oxygen‐enriched air (OEA) flux, oxygen concentration, permeability coefficients of OEA, oxygen, nitrogen, as well as separation factor through the multilayer LDPE films, and operating parameters, including transfilm pressure difference, retentate/permeate flux ratio, temperature, as well as layer number, are all discussed in detail. It is found that all of the preceding oxygen‐enrichment parameters increase continuously with an increase of transfilm pressure difference from 0.1 to 0.65 MPa, especially for the trilayer and tetralayer LDPE films. The oxygen concentration and separation factor appear to rapidly increase within the retentate/permeate flux ratio below 200, and then become unchangeable beyond that, whereas the OEA flux and the permeability coefficients of OEA, oxygen, and nitrogen seem to remain nearly constant within the whole retentate/permeate flux ratio investigated, especially for the monolayer and bilayer LDPE films. The selectivity becomes inferior, whereas the permeability becomes superior, as the operating temperature increases from 23 to 31°C. The highest oxygen concentration was found to be 44.8% for monolayer LDPE film in a single step with air containing oxygen of 20.9% as a feed gas and operating pressure of 0.5 MPa at a retentate/permeate flux ratio of 340 and 23°C. The results demonstrate a possibility to prepare an oxygen‐enriching membrane directly from air, based on the easily obtained thin LDPE films. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 3013–3021, 2002; DOI 10.1002/app.2331 相似文献
905.
The thermokinetic behavior of blocked polyurethane (PU)–unsaturated polyester (UP)–based composites during the pultrusion of glass‐fiber‐reinforced composites was investigated utilizing a mathematical model that accounted for the heat transfer and heat generation during curing. The equations of continuity and energy balance, coupled with a kinetic expression for the curing system, were solved using a finite difference method to calculate the temperature profiles and conversion profiles in the thickness direction in a rectangular pultrusion die. A kinetic model, dP/dt = A exp(?E/RT)Pm(1 ? P)n, was proposed to describe the curing behavior of a blocked PU–UP resin. Kinetic parameters for the model were obtained from dynamic differential scanning calorimetry scans using a multiple regression technique, which was able to predict the effects of processing parameters on the pultrusion. The effects of processing parameters including pulling speed, die wall temperature, and die thickness on the performance of the pultrusion also were evaluated. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1996–2002, 2003 相似文献
906.
Two-dimensional correlation relaxometry studies of cement pastes performed using a new one-sided NMR magnet 总被引:1,自引:0,他引:1
Peter J. McDonald Jonathan Mitchell Peter S. Aptaker Luc Monteilhet 《Cement and Concrete Research》2007,37(3):303-309
We present preliminary results of the first NMR T1-T2 two-dimensional relaxation correlation experiments performed using a one-sided NMR system in cement based materials. Two-dimensional correlation relaxometry has itself only recently been demonstrated in cement paste where it proved to be a particularly sensitive probe of pore-water dynamics providing direct information on exchange of water between the gel and capillary pore networks. Further to this we have observed differences in the structural development of a selection of cement pastes throughout the early stages of hydration and verified the theoretical frequency dependence of the ratio T1 / T2. When coupled with instrumentation developments in one-sided NMR magnets the way is opened to detailed, spatially resolved studies of the development of hydration and porosity in the surface layers (top 50 mm) of cementitious materials. A new magnet, suitable for such applications, is discussed. 相似文献
907.
Fabienne Fay Isabelle Linossier Valérie Langlois Karine Vallee‐Rehel Michal Y. Krasko Abraham J. Domb 《应用聚合物科学杂志》2007,106(6):3768-3777
This article describes the synthesis and in vitro analysis of poly(ester anhydride) antimicrobial protection coatings. Poly(ester anhydride)s composed of ricinoleic acid, sebacic acid, terephthalic acid, and isophthalic acid were used in this study. The polymers were compatible with various fillers commonly used in paint preparation. The in vitro experiments showed that the polymers are able to release diuron, an antimicrobial agent, for months. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
908.
The kinetics of curing for a modified bismaleimide (BMI) resin was investigated to ascertain a suitable cure model for the material. The resin system used in this study was composed of 4,4′‐bismaleimidodiphenylmethane (BMIM) and 0,0′‐diallyl bisphenol A (DABPA, DABA). The BMIM was the base monomer and the DABPA was the modified agent. A series of isothermal DSC runs provided information about the kinetics of cure in the temperature range 170–220°C. Regardless of the different temperatures, the shape of the conversion curves was similar, and this modified BMI resin system underwent an nth‐order cure reaction. Kinetic parameters of this BMI resin system, including the reaction model, activation energy, and frequency factor, were calculated. From the experimental data, it was found that the cure kinetics of this resin system can be characterized by a first‐order kinetic model. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3338–3342, 2004 相似文献
909.
910.
Poly(ethylene terephthalate) (PET) was blended with two different poly(oxybenzoate‐p‐trimethylene terephthalate) copolymers, designated T28 and T64, with the level of copolymer varying from 1 to 15 wt %. All samples were prepared by solution blending in a 60/40 (by weight) phenol/tetrachloroethane solvent at 50°C. The crystallization behavior of the samples was studied by DSC. The results indicate that both T28 and T64 accelerated the crystallization rate of PET in a manner similar to that of a nucleating agent. The acceleration of PET crystallization rate was most pronounced in the PET/T64 blends with a maximum level at 5 wt % of T64. The melting temperatures for the blends are comparable to that of pure PET. The observed changes in crystallization behavior are explained by the effect of the physical state of the copolyester during PET crystallization as well as the amount of copolymer in the blends. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1599–1606, 2002 相似文献