全文获取类型
收费全文 | 7949篇 |
免费 | 129篇 |
国内免费 | 20篇 |
专业分类
电工技术 | 397篇 |
综合类 | 4篇 |
化学工业 | 1692篇 |
金属工艺 | 233篇 |
机械仪表 | 218篇 |
建筑科学 | 115篇 |
能源动力 | 256篇 |
轻工业 | 550篇 |
水利工程 | 33篇 |
石油天然气 | 8篇 |
无线电 | 693篇 |
一般工业技术 | 1379篇 |
冶金工业 | 1819篇 |
原子能技术 | 211篇 |
自动化技术 | 490篇 |
出版年
2023年 | 38篇 |
2022年 | 71篇 |
2021年 | 130篇 |
2020年 | 60篇 |
2019年 | 59篇 |
2018年 | 92篇 |
2017年 | 77篇 |
2016年 | 105篇 |
2015年 | 93篇 |
2014年 | 140篇 |
2013年 | 307篇 |
2012年 | 253篇 |
2011年 | 339篇 |
2010年 | 243篇 |
2009年 | 301篇 |
2008年 | 310篇 |
2007年 | 305篇 |
2006年 | 292篇 |
2005年 | 256篇 |
2004年 | 218篇 |
2003年 | 215篇 |
2002年 | 225篇 |
2001年 | 187篇 |
2000年 | 162篇 |
1999年 | 197篇 |
1998年 | 689篇 |
1997年 | 435篇 |
1996年 | 325篇 |
1995年 | 227篇 |
1994年 | 221篇 |
1993年 | 183篇 |
1992年 | 102篇 |
1991年 | 108篇 |
1990年 | 96篇 |
1989年 | 88篇 |
1988年 | 79篇 |
1987年 | 67篇 |
1986年 | 78篇 |
1985年 | 105篇 |
1984年 | 74篇 |
1983年 | 67篇 |
1982年 | 56篇 |
1981年 | 65篇 |
1980年 | 58篇 |
1979年 | 40篇 |
1978年 | 33篇 |
1977年 | 59篇 |
1976年 | 62篇 |
1975年 | 33篇 |
1973年 | 28篇 |
排序方式: 共有8098条查询结果,搜索用时 15 毫秒
81.
Films of alicyclic polyamic acid and polyimide containing cyclobutane ring in dianhydride moiety and aromatic ring with p- or m-linkages in diamine moiety were characterized by infrared (IR) spectroscopy, dynamic viscoelasticity, differential-scanning calorimetry (DSC), density, and wide-angle X-ray diffraction analyses. Partially and fully imidized polyimides were obtained by varying the imidization temperature, e.g., 150°C, 250°C, and 350°C. It was found from the results of IR spectra, dynamic viscoelasticity, and DSC measurements that the imidization of alicyclic polyamic acid was reduced at about 150°C and needed a higher imidization temperature than aromatic polyamic acid. Alicyclic polyimide with m-linkage in the diamine moiety had a higher density and a much more ordered structure than with p-linkage. © 1994 John Wiley & Sons, Inc. 相似文献
82.
Yujiro Watanabe Yusuke Moriyoshi Yasushi Suetsugu Toshiyuki Ikoma Takeshi Kasama Tadashi Hashimoto Hirohisa Yamada Junzo Tanaka 《Journal of the American Ceramic Society》2004,87(7):1395-1397
Type-A zeolite evenly covered with hydroxyapatite thin layers was prepared using hydrothermal treatment at 120°C for 8 h under autogenous pressure. The hydroxyapatite needlelike nanocrystals, 100–200 nm in diameter and 30 nm in thickness, were grown under the reaction between discharged Ca2+ ions from type-A zeolite and PO4 3− ions in (NH4 )3 PO4 solution. The preferential orientations of the c -axis of hydroxyapatite crystals perpendicular to a zeolite surface were observed using transmission electron microscopy. The crystal structure of type-A zeolite was not destroyed under the reaction, but the surface morphology was changed only with complete covering of scaly hydroxyapatite particles. 相似文献
83.
Summary Plasma-polymerized membranes for gas separation were prepared from 1-(trimethylsilyl)-1-propyne. The permeation data of He, H2 02, N2, CO2, and CH4 through the membranes showed plasma-polymerized 1-(trimethylsilyl)-1-propyne had high permselectivity but low permeability compared with poly[l-(trimethylsilyl)-1-propyne]. This behavior is considered to be due to the crosslinking structure of the plasma-polymerized membrane. The correlation between plasma polymerization conditions and the membrane performance was studied. The optimum condition at which the deposition rate of the plasma polymer is maximized agreed with the optimum value to yield maximum separation factor of gases through the membrane. 相似文献
84.
Atsushi Tanaka 《Carbon》2004,42(3):591-597
The present study confirmed that highly crystalline nanofibers with controlled structure may be prepared over Fe and Fe-Ni alloy catalysts. The degree of graphitization of various carbon nanofibers (CNFs) was analyzed by using C(0 0 2) peaks from the XRD profiles. The C(0 0 2) peaks of CNFs over Fe catalyst shifted to higher angle and became narrower as the preparation temperature increased from 560 to 620 °C. Tubular CNFs prepared at temperature higher than 630 °C showed lower 2θ angles compared to those of platelet fibers. CNFs prepared over Fe-Ni catalysts tended to resemble those prepared over Fe catalysts. The degree of graphitization of platelet CNFs resembled natural graphite, while d0 0 2 of the tubular CNFs showed values below the 3.39 Å reported as a theoretical minimum for a cylindrical alignment. Lc0 0 2 of platelet and tubular CNFs increased by heat treatment at 2000 and 2800 °C though d0 0 2 changed little. A transverse section of platelet and tubular CNFs had a hexagonal shape, not a round shape. The hexagonal column allows AB stacking of hexagonal planes that can give perfect hexagonal alignment. 相似文献
85.
Masahiko Shimada Ken'ichi Matsushita Shusei Kuratani Taira Okamoto Mjtsue Koizumi Koji Tsukuma Takaaki Tsukidate 《Journal of the American Ceramic Society》1984,67(2):23-C-
The temperature dependence of Young's modulus and internal friction (Q−1 )in alumina, silicon nitride, and partially stabilized zirconia (Y-PSZ) ceramics was studied. Little change in Q−1 was found for alumina, whereas Q−1 for silicon nitride ceramics increased above 700°C. The Q−1 of Y-PSZ increased markedly with increasing temperature up to a peak at ∼200°C. 相似文献
86.
α-Tocopherol was reacted with methyl linoleateperoxyl radicals at 37°C. The peroxyl radicals were generated by the reaction
of methyl linoleate with a free radical initiator, 2,2′-azobis(2,4-dimethylvaleronitrile). The primary products of α-tocopherol with methyl linoleate-peroxyl radicals were isolated by
reversephase and normal-phase high performance liquid chromatography (HPLC), and their structures were characterized by ultraviolet
(UV), infrared (IR),1H and13C nuclear magnetic resonance (NMR) and mass spectrometry (MS). There were four stereoisomers of methyl 13-(8a-peroxy-α-tocopherone)-9(Z),11(E)-octadecadienoate and four stereoisomers of methyl9-(8a-peroxy-α-tocopherone)-10(E),12(Z)-octadecadienoate. 相似文献
87.
In order to study the deformation mechanism of type II stretching, the change in orientation during the restretching and subsequent thermal contraction was investigated by x-ray diffraction method. When a uniaxially oriented film is restretched, the lamellae which are stacked in the stretching direction by the stretching rotate as a whole toward the restretching axis. They rotate backward nearly reversibly during the thermal contraction, unless the restretching exceeds a balancing state, where the orientation in the film plane are equal in all directions. However, when the restretching degree is so high and the film orientation exceeds the balancing state, the lamellar rotation is accompanied by a complex phenomenon. It is considered from the wide-angle and small-angle x-ray diffraction patterns that the lamellar surface becomes indented because of slippage between microfibrils composing the lamellae, and the microfibrils themselves bend at the boundary between the amorphous and crystalline regions within which the tilting of c-axis also occurs. Upon contracting of the film; these changes recover, but even in the last stage of contraction the orientation approaches the symmetrical biaxial orientation but not the uniaxial orientation from which the biaxial orientation is started. These orientation and disorientation behaviors are not affected basically by a slight change in the restretching temperature and the degree of stretching. 相似文献
88.
The configurational sequences of 1,2-unit in a series of hydrogenated syndiotactic 1,2-polybutadienes were determined in relation to the sequence distribution of 1,2- and 1,4-units on the basis of the 13C-n.m.r. signal assignment of the methyl carbons. The observed triad distributions of 1,2- and 1,4-units and configurational distributions of the 1,2-unit are in good agreement with the calculated distributions from transition probabilities. The number average sequence lengths of the 1,2-unit and the 1,2-unit in the racemic addition are 5.7 to 8.0 and 4.1 to 5.4, respectively. From the extrapolation of the plot of the number average sequence length against the crystallinity of the starting 1,2-polybutadienes, the minimum sequence length for crystallization is estimated to be 3.7 for the 1,2-unit in the racemic addition. 相似文献
89.
Pressure effects on the low temperature state of the α-(BEDT-TTF)2MHg(SCN)4 organic conductor family
X. Chen J. S. Brooks S. Valfells G. J. Athas S. J. Klepper M. Tokumoto N. Kinoshita H. Anzai Y. Tanaka 《Synthetic Metals》1995,70(1-3)
Systematic magnetotransport measurements as a function of hydrostatic pressure have been made on four members of the α-(BEDT-TTF)2MHg(SCN)4 organic conductor family (M = K, Tl, Rb, NH4). Applied pressure above about 6 Kbar removes the density wave state for M = K, Tl, and Rb. For M = NH4 the superconducting state is removed with pressure as dTc/dP = − 0.25 K/Kbar. In all cases the Shubnikov de Haas oscillation frequency increases with pressure, including the β orbit (which involves the entire Brillouin zone), and new orbits involving very small fractions of the Fermi surface are formed. 相似文献
90.