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61.
Strengthening mechanisms of nickel-base superalloys have been discussed with the background of the Japanese research and development activities in this field. As candidates for materials of intermediate heat exchangers which will be used for a future programme of nuclear steelmaking systems, two kinds of alloys have successfully been developed in Japan. The designs of these alloys have been reviewed from metallurgical aspects including their composition and creep properties. In addition to the conventional methods to strengthen these alloys, such as solid solution hardening or particle precipitation hardening, a grain-boundary precipitation strengthening due to tungsten-rich 2 phase in the Ni-Cr-W system, would be expected as a further advanced method. 相似文献
62.
Using a Debye function analysis, the presence of icosahedral and face centered cuboctahedral gold in a 1 1 ratio has been found in freshly prepared Au/Mg(OH)2 catalyst. The results support earlier studies which suggest the icosahedral form to be more stable at small nanometer sizes. Interactions between the gold and the Mg(OH)2 support appear to be weak, with the gold rapidly coagulating over a period of three months. Re-analysis of the aged sample shows the gold to be mainly in the form of truncated decahedra. 相似文献
63.
The feeding and gustatory responses to ecdysone and 20-hydroxyecdysone were investigated in the silkworm,Bombyx mori. 20-Hydroxyecdysone reduced feeding response strongly in fourth- and fifth-instar larvae, whereas ecdysone had no effect on feeding response. 20-Hydroxyecdysone stimulated the R receptor, the receptor to feeding deterrents, to a great degree. By contrast, ecdysone was much less effective for stimulating the R receptor. These results indicate that ecdysone and 20-hydroxyecdysone have different effects on feeding response due to different interactions with mouthpart chemoreceptors. 相似文献
64.
高速气流冲击式粉体表面改性装置——HYBRIDIZATION系统及应用 总被引:4,自引:0,他引:4
利用高速气流冲击法进行粉体/粉体系表面改性技术,是迄今为止各种粉体材料开发中最为引人注目的技术之一。HYBRIDIZATION(下称HYB)系统是利用高速气流冲击法对微粉体进行干式/机械化处理,是使材料复合化的最实用的装置,可对各类有机物、无机物、金属等进行广泛组合,通用性很强,适用于许多行业领域。从本文所述的系统构成、型式,有关的典型球形化处理的运转特性,利用复合化高温粉体测定被处理粉体表面温度,利用颜料改变色调等的处理特点及该系统的适用性等(一部分是从已发表的学术论文及专利上摘录的),可以说明HYB系统的概况。 相似文献
65.
66.
Hui Gu Rowland M. Cannon Hans J. Seifert Michael J. Hoffmann Isao Tanaka 《Journal of the American Ceramic Society》2002,85(1):25-32
The nitrogen solubility in the SiO2 -rich liquid in the metastable binary SiO2 -Si3 N4 system has been determined by analytical TEM to be 1%–4% of N/(O + N) at 1973–2223 K. Analysis of the near edge structure of the electron energy loss peak indicates that nitrogen is incorporated into the silicate network rather than being present as molecular N2 . A regular solution model with a positive enthalpy of mixing for the liquid was used to match the data for the metastable solubility of N in the presence of crystalline Si3 N4 and to adjust the computed phase diagram. The solubility of Si3 N4 in fused SiO2 is far less than reported in liquid silicates also containing Al, Mg, and/or Y. Apparently, these cations act as modifiers that break anion bridges in the silicate network and, thereby, allow further incorporation of Si3 N4 without prohibitive amounts of network cross-linking. Finally, indications emerged regarding the diffuse nature of the Si3 N4 -SiO2 interface that leads to amorphous regions of higher N content. 相似文献
67.
Composite sheets composed of biodegradable polymers (BP) and paper were prepared, and their physical and biodegradable properties were investigated. The paper sheets were soaked in BP emulsions and cured at 100°C for 20 min. The wet strength of composite sheets with the same basis weight increased significantly with increasing BP content, although dry strength increased only moderately. A 0.5% addition of a common wet paper‐strengthening agent, poly(amidoamine‐epichlorohydrin) (PAE) resin, enhanced the wet strength, which reached 9.3 MPa, of composite sheets consisting of a BP : paper ratio of 20 : 80. Further enhancement was achieved by the addition of polyvinylamines (PVAm). The wet tensile strength of composite sheets consisting of BP and paper (20 : 80) increased by 27% with the addition of 0.2% PVAm and 0.5% PAE, whereas it was enhanced by only 3–4% with the addition of 0.7% PAE. The biodegradability of the composite sheets was somewhat retarded by the addition of PAE and PVAm. However, a 90% weight loss was observed 60 days after placing composite sheet samples in soil. A similar weight loss was observed after 45 days for composites without additives and after 30 days for base paper alone. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 861–866, 2005 相似文献
68.
Isao Tanaka Ken'ichiro Igashira Taira Okamoto Koichi Niihara Rowland M. Cannon 《Journal of the American Ceramic Society》1995,78(3):673-679
High-purity Si3 N4 (with 2.5 wt% glassy SiO2 ) doped with 0 to 450 at.ppm of Ca was prepared as a model system to investigate the effects of grain-boundary segregants on fracture phenomenology at 1400°C. Subcritical crack-growth (SCG) resistance as well as creep resistance was degraded significantly by the presence of a small amount of Ca. The internal friction of the doped materials exhibited the superposition of a grain-boundary relaxation peak and a high-temperature background, and the apparent viscosity of the grain-boundary film was determined from the peak. Based on these experimental data, the fracture mechanism at 1400°C was divided into three regions: "brittle," SCG, and creep failure as a function of both external strain rate and Ca concentration, C Ca . From the investigation of the C Ca dependence of the critical strain rate for the transition from "brittle" to SCG fractures, the SCG phenomenon is suggested to be triggered by small-scale, grain-boundary sliding. The C Ca dependence of "steady-state" creep rate was far from the theoretical dependence of diffusional creep via a solution-precipitation mechanism. The discrepancy was interpreted to be due to the presence of an impurity-insensitive creep component. This component may correspond to the lowest limit of the tensile creep rate in Si3 N4 polycrystalline materials containing intergranular glassy-SiO2 film. 相似文献
69.
Masashi Shou Hiroyuki Takekawa Dong-Ying Ju Tokio Hagiwara Da-ling Lu Ken-ichi Tanaka 《Catalysis Letters》2006,108(3-4):119-124
Catalytic activity of a 1 wt% Au/TiO2 catalyst is markedly improved by loading a large amount of FeOx, on which the oxidation of CO in excess H2 is selectively promoted at temperature lower than 60 °C. Oxidation of CO with O2 on the FeOx/Au/TiO2 catalyst is markedly enhanced by H2, and H2O moisture also enhances the oxidation of CO but its effect is not so large as the promotion by H2. We deduced that activation of Au/TiO2 catalyst by loading FeOx is not caused by the size effect of Au particles but a new reaction path via hydroxyl carbonyl intermediate is responsible
for the superior activity of the FeOx/Au/TiO2 catalyst. 相似文献
70.
Masahiro Tatsumisago Tsutomu Minami Masami Tanaka 《Journal of the American Ceramic Society》1981,64(7):97-C-
A new technique combining a thermal-image furnace and a twin roller is described for quenching the melt to form glass. The technique was applied to the simple system Li2 O-SiO2 , since its fundamental parameters in the estimation of critical cooling rate are available. Glass flakes were obtained in the composition Li4 SiO4 , for which a very large critical cooling rate (∼109 K·s−1 ) was needed for glass formation. 相似文献