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101.
The activities of several commercial nickel catalysts were determined by measuring their activation energies. Among these
catalysts, G95E, Resan 22, Nysosel 222 and 325, all with low activation energy, were more active than DM3 and G95H, which
had higher activation energy. However, the less active catalysts increased the linoleate selectivity of soybean oil during
hydrogenation. The yields of bothtrans isomers and winterized oil were higher for the more selectively hydrogenated oil catalyzed by the less active catalysts.
In the sensory evaluation, the fractionated solid fat that contained moretrans isomers was lower in flavor scores than the fractionated liquid oil after hydrogenation and winterization of soybean oil. 相似文献
102.
103.
Effects of Stearic Acid on the Injection Molding of Alumina 总被引:1,自引:0,他引:1
This research investigated the influence of stearic acid on the injection molding of alumina, by varying the concentration of stearic acid. The interaction between stearic acid and alumina was identified using transmission infrared spectroscopy, indicating stearic acid preferentially adsorbed onto the alumina powder surface. In addition to slightly modifying the intrinsic binder viscosity, stearic acid adsorbed onto the powder surface changed the flow behavior of the mixtures from dilatant flow to pseudoplastic flow at low temperatures. As a result, inhomogeneous distribution of binder in the injection-molded parts was minimized with increased stearic acid concentration. However, the possibility of forming bubbles in the mixtures arising from vaporization of stearic acid was enhanced. Additionally, the binder burnout temperature range was broadened with the increase of stearic acid concentration. 相似文献
104.
C. C. Lin 《Polymer Engineering and Science》1983,23(3):113-116
The value of tmax in differential scanning calorimetry is correlated with the crystallization kinetics of poly(ethylene terephthalate) (PET). The Avrami exponent, n, obtained varies as a result of a change in slope of the curve at the point tn, a secondary crystallization transition. The plot of tn vs. tmax shows a linear relationship. The rate of crystallization depends upon both molecular weight and crystallization temperature. Under a nucleation controlling step, the plot of log tmax vs. \documentclass{article}\pagestyle{empty}\begin{document}$ t_{\max } vs.\frac{1}{{T^2 \Delta T}} $\end{document}gives a linear relationship. Theoretical concepts of the treatment are discussed. 相似文献
105.
以枯草杆菌为菌种液体培养制备碱性磷酸酶,研究确定了培养的最佳工艺条件,并对碱性磷酸酶的酶促反应动力学性质进行了初步探讨。结果表明,枯草杆菌制备碱性磷酸酶的最佳工艺条件为:40℃,pH值7.4振荡培养10h,酶活最高。对碱性磷酸酶的动力学性质研究表明,该酶催化底物磷酸苯二钠水解反应的最适pH值8.8,最适温度52℃,米氏常数Km值为2.94mmol/L。 相似文献
106.
107.
The effect of free radical desorption is studied by using a mathematical model of particle size distribution in continuous emulsion polymerization. By comparing the theoretical prediction with experimental data, the value of Do for the vinyl acetate (VAc) system is best chosen as 0.19 × 10?7 cm2/h. The effect of radical desorption as well as mean residence time on the absolute particle size distribution, total concentration of polymer particles, conversion, and average number of radicals per polymer particle are analyzed by the model proposed. 相似文献
108.
The hydrogenation of diene‐based polymers via diimide is a very attractive alternative to the conventional catalytic hydrogenation route based on gaseous molecular hydrogen. However, serious crosslinking always accompanies it and limits the end‐use properties of the polymers. Gel formation in polymers that are hydrogenated via diimide has been investigated in detail through an inspection of all the chemical reactions involved in the process. The results indicate that hydrogen peroxide decomposition, some reactions related to oxygen, and the redox reaction between hydrogen peroxide and hydrazine are capable of generating radicals. However, radicals generated in the aqueous phase do not appear to initiate the crosslinking of diene‐based polymers in the latex form. It is proposed that the primary radicals giving rise to crosslinking are generated in the polymer phase in situ, and the step responsible for generating these organic radicals is possibly the diimide disproportionation reaction. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1122–1125, 2005 相似文献
109.
A brown coal, peat and oil shale were subjected to a rapid pyrolysis process and medium-heat-value gases together with tar were collected. The char residue was of high activity and suitable for gasification to create a two-stage gasification system. The coal-tar is used for manufacturing liquid fuels and chemicals. 相似文献
110.
The diversities existing among published kinetic studies on activated anionic polymerization of ε-caprolactam are closely examined. A kinetic model derived from a regular, linear reversible reaction mechanism is employed to explain the experimentally observed autocatalytic character of the polymerization system and to examine the dependence of the apparent activation energy on the experimental method. Several existing kinetic models tested with our experimental data show that the autocatalytic type rate equation best describes the polymerization process. 相似文献