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981.
Influence of various intermediate oxides on thermal, structural and crystallization kinetics of 30BaO–40SiO2–20B2O3–10A2O3 (A = Y, La, Al, Cr) glasses has been studied. The highest glass transition temperature (Tg) with high thermal stability is observed in Y2O3 containing glasses as compared to other glasses. The thermal expansion coefficient (TEC) increases with increasing heat treatment duration in all the glasses. The maximum increase in TEC is observed in Cr2O3 containing glass ceramics. FTIR study showed that transmission bands due to silicate and borate chains become sharper with splitting after heat treatment. A selected glass sample (BaCr) has been tested for interaction and adhesion with Crofer 22 APU interconnect material for its application as a sealant in solid oxide fuel cell. 相似文献
982.
Nikhil Kawachale Deepak M. KirpalaniAshwani Kumar 《Chemical Engineering and Processing: Process Intensification》2010
This study reports an analysis of membrane permeance and mass transfer coefficient in laboratory test cells for gas separation using computational fluid dynamics. Mass transfer coefficients and species concentration were computed across the membrane surface for gas mixture. The same test cells were examined for the fluid hydrodynamics in liquid separation. It was observed that the uniform flow distribution in the case of gas separation was responsible for improved permeance; whereas, a uniform flow had no significant effect on permeation rate for liquid separation. Also, the potential reasons for the difference in gas and liquid separation are discussed. 相似文献
983.
Debabrata Pradhan Akshya Kumar Guin Pankaj Raju Manindra Manna Monojit Dutta T. Venugopalan 《Journal of Materials Engineering and Performance》2014,23(9):3336-3346
Galvannealed steel sheets (GA) have become the mainstream steel sheet for automobile applications because of their superior corrosion resistance, paintability, and weldability. To impart specific properties, different coatings on GA steel sheet were reported to improve properties further. In this context, we have developed an electroplating process (flash coating) for bright and adherent Fe-Zn alloy coating on GA steel sheet to enhance performances such as weldability, frictional behavior, phosphatability, and defect coverage. A comparative study with bare GA steel sheet was carried out for better elastration. The electroplating time was reduced below 10 s for practical applicability in an industrial coating line by modulating the bath composition. Electroplating was performed at current density of 200-500 A/m2 which yielded with higher cathode current efficiency of 85-95%. The performance results show that Fe-10 wt.% Zn-coated GA steel sheet (coating time 7 s) has better spot weldability, lower dynamic coefficient of friction (0.06-0.07 in lubrication), and better corrosion resistance compared to bare GA steel sheet. Uniform phosphate coating with globular crystal size of 2-5 µm was obtained on Fe-Zn flash-coated GA steel sheet. Hopeite was the main phosphate compound (77.9 wt.%) identified along with spencerite (13.6 wt.%) and phosphophyllite (8.5 wt.%). 相似文献
984.
Surajit Kumar Paul 《Journal of Materials Engineering and Performance》2014,23(9):3100-3107
This paper has presented a life prediction model in the field of multiaxial low-cycle fatigue. The proposed model is generally applied for constant amplitude multiaxial proportional and non-proportional loading. Depending upon applied strain path the equivalent strain varies within a cycle. Equivalent average strain amplitude is considered as fatigue damage parameter in the proposed model. The model has requirement of only two material constants and no other tuning parameters. The model is examined by the proportional and non-proportional low-cycle fatigue life experimental data for eight different types of materials. The model is successfully correlated with multiaxial fatigue lives of eight different materials. 相似文献
985.
M. K. Punith Kumar Chandan Srivastava 《Journal of Materials Engineering and Performance》2014,23(10):3418-3424
In the present work, morphology, microstructure, and electrochemical behavior of Zn coatings containing non-toxic additives have been investigated. Zn coatings were electrodeposited over mild steel substrates using Zn sulphate baths containing four different organic additives: sodium gluconate, dextrose, dextrin, and saccharin. All these additives are “green” and can be derived from food contents. Morphological and structural characterization using electron microscopy, x-ray diffraction, and texture co-efficient analysis revealed an appreciable alteration in the morphology and texture of the deposit depending on the type of additive used in the Zn plating bath. All the Zn coatings, however, were nano-crystalline irrespective of the type of additive used. Polarization and electrochemical impedance spectroscopic analysis, used to investigate the effect of the change in microstructure and morphology on corrosion resistance behavior, illustrated an improved corrosion resistance for Zn deposits obtained from plating bath containing additives as compared to the pure Zn coatings. 相似文献
986.
C. S. Naveen P. Raghu H. M. Mahesh K. Narasimha Rao R. Rakesh Kumar A. R. Phani 《稀有金属(英文版)》2014,33(5):578-582
TiO2thin films with 0.2 wt%, 0.4 wt%, 0.6wt%, and 0.8 wt% Fe were prepared on glass and silicon substrates using sol–gel spin coating technique. The optical cut-off points are increasingly red-shifted and the absorption edge is shifted over the higher wavelength region with Fe content increasing. As Fe content increases, the optical band gap decreases from 3.03 to 2.48 eV whereas the tail width increases from 0.26 to 1.43 eV. The X-ray diffraction(XRD) patterns for doped films at 0.2 wt% and0.8 wt% Fe reveal no characteristic peaks, indicating that the film is amorphous whereas undoped TiO2exhibits(101) orientation with anatase phase. Thin films of higher Fe content exhibit a homogeneous, uniform, and nanostructured highly porous shell morphology. 相似文献
987.
Lopamudra Sahu Awanish Kumar Mishra Krishna Dutta 《Journal of Materials Engineering and Performance》2014,23(11):4122-4129
Ratcheting fatigue behavior of a non-conventional stainless steel X12CrMnNiN17-7-5 has been investigated with varying combinations of mean stress (σm) and stress amplitude (σa) at room temperature using a servo-hydraulic universal testing machine. X-ray diffraction profile analysis has been carried out for assessing possible martensitic phase transformation in the steel subjected to ratcheting deformation. The results indicate that ratcheting strain as well as volume fraction of martensite increases with increasing σm and/or σa; the phenomenon of strain accumulation is considered to be governed by the associated mechanics of cyclic loading, increased plastic damage as well as martensitic transformation. A correlation between strain produced by ratcheting deformation and martensitic transformation has been established. 相似文献
988.
Deepa Mudgal Sanjeet Kumar Surendra Singh Satya Prakash 《Journal of Materials Engineering and Performance》2014,23(11):3805-3818
Cr3C2-25(NiCr) and Cr3C2-25(NiCr)+0.4%CeO2 coatings were deposited on nickel-based superalloy Superni 600 by Detonation-gun technique. Studies were conducted on bare and coated alloys in molten salt environment (Na2SO4-25%NaCl) at 900 °C under cyclic condition. Characterization of the corrosion product was done using field emission scanning electron microscopy/energy dispersive spectroscopy and x-ray diffraction techniques. The bare Superni 600 shows penetration of corrosion beneath the metal layer thereby indicating internal oxidation. The coating of Cr3C2-25(NiCr) with 0.4%CeO2 leads to the formation of adherent scale. 相似文献
989.
Harmesh Kumar Rajesh Choudhary Shankar Singh 《Journal of Materials Engineering and Performance》2014,23(4):1489-1497
In this study, a special experimental setup of EDSG using EDM and surface grinding machine has been developed in the laboratory to investigate the effect of seven input parameters namely tool polarity, peak current, pulse on-time, pulse off-time, rotational speed, abrasive particle size, and abrasive particle concentration on material removal rate (MRR) as performance measure of the process. The novelty of the present research work is that successful efforts have been made to machine the 6061Al/Al2O3p 10% metal matrix composites (MMC) by composite tool itself. The copper-based composite tool electrodes were fabricated by powder metallurgy route with different sizes of abrasives of silicon carbide, while 6061Al/Al2O3p 10% MMC were fabricated through stir-casting process. The research outcome will identify the important parameters and their effect on MRR of 6061Al/Al2O3p 10% composite in EDSG. The experimental results reveal that tool polarity, peak current, and rotational speed are the most influential parameters that affect MRR in EDSG process. The micro-structural and morphological analysis of machined surfaces has also been carried out to analyze the surface topography. It has been concluded that the abrasive particles substantially improves the MRR after removing the resolidified layer from the machined surface. 相似文献
990.