QuEChERS前处理高效液相色谱-串联质谱法 同时测定食品中6种工业染料

目的建立食品中6种工业染料的QuEChER前处理高效液相色谱-串联质谱同时测定方法。方法均匀样品用水分散溶解后,加乙腈提取,经改进的QuEChERS方法净化,0.22μm微孔滤膜过滤,用0.1%甲酸-5mmol/L乙酸铵溶液和乙腈为流动相梯度洗脱,C_(18)柱分离,分别在电喷雾正、负离子模式下以多反应监测方式检测,外标法定量。结果结果表明,6种工业染料在0.5~40μg/L浓度范围内与其呈良好的线性关系(r0.999),检出限为1.0~2.0μg/kg,在添加水平为1.0、5.0、20μg/kg时,平均回收率为76.1%~114.8%,相对标准偏差(RSD)为2.0%~9.7%(n=6)。结论该方法分析速度快,灵敏可靠,重复性好,适用于调味品、豆制品、卤肉制品、红糖等食品中6种工业染料的测定。     

Effects of Tearing Conditions on the Crack Propagation in a Monolayer Graphene Sheet

The path of crack propagation in a graphene sheet is significant for graphene patterning via the tearing approach. In this study, we evaluate the fracture properties of pre-cracked graphene during the tearing process, with consideration of the effects of the aspect ratio, loading speed, loading direction, and ambient temperatures on the crack propagation in the monolayer sheet. Some remarkable conclusions are drawn based on the molecular dynamic simulation results, i.e., a higher loading speed may result in a complicated path of crack propagation, and the propagation of an armchair crack may be accompanied by sp carbon links at high temperatures. The reason for this is that the stronger thermal vibration reduces the load stress difference near the crack tip and, therefore, the crack tip can pass through the sp link. A crack propagates more easily along the zigzag direction than along the armchair direction. The out-of-plane tearing is more suitable than the in-plane tearing for graphene patterning. The path of crack propagation can be adjusted by changing the loading direction, e.g., a rectangular graphene ribbon can be produced by oblique tearing. This new understanding will benefit the application of graphene patterning via the tearing approach.     

碾压强化有限元建模及分析研究

碾压是强化金属表层的一种重要且很有发展潜力的强化方法,工件表层经碾压变形强化后会表层留有应力,能提高表层硬度和强度,同时还能改善工件表面粗糙度.对装备构件进行碾压模拟,模拟结果显示工件表层经碾压后产生较高应力且内部状态无明显变化,强化效果明显.接着改变下压量进行模拟,发现在一定范围内,随下压量增大,碾压强化效果愈好.     

骨素及其应用

介绍了骨素国内外发展现状,营养特点、加工工艺、生产过程中HACCP体系的建立,以及骨素的应用,并预测了骨素产品的开发前景。     

微波辐射合成葡萄糖五乙酸酯

在微波辐射下,对甲苯磺酸催化葡萄糖和乙酸酐反应合成了葡萄糖五乙酸酯。考察了微波辐射功率、微波辐射时间、原料配比和对甲苯磺酸用量对产率的影响。通过正交实验确定了最佳条件为:辐射功率462 W,反应时间7 min,葡萄糖与乙酸酐的摩尔比1∶9,对甲苯磺酸质量分数1.5%,产率可达71.8%。     

基于卷积神经网络的霉变烟叶图像识别方法研究

针对人工在线精选霉变烟叶时,存在效率低下、容易漏检等缺点,提出了一种基于卷积神经网络模型对霉变烟叶图像进行筛选、分类识别的方法.首先建立烟叶数据集,然后搭建卷积神经网络模型,利用卷积神经网络先初步提取特征,再筛选提取主要特征,然后进行各部分的特征汇总;最后实现图像的分类,从而实现了快速、准确的识别霉变烟叶图像和正常烟叶...     

应用散射时距关系的三维三分量VSP成像

由于观测系统的特殊性,无法采用地面地震技术处理三维三分量(3D3C)VSP数据.现有的VSP成像技术中,可借鉴的高精度成像方法较少,缺乏相匹配的处理软件,成像速度分析多需要迭代,成像难度大.为此,提出一种适用于3D3C-VSP数据的无需迭代的速度建模与基于散射时距关系的成像方法.首先,建立了适用于3D3C-VSP观测系...     

CCTV双向倾斜高强预应力锚栓安装施工技术

中央电视台新台址主楼外框筒钢柱脚锚栓具有直径大、单根柱锚杆分布数量不等、双向倾斜安装以及张拉空间狭小的特点。介绍了双向倾斜大直径高强预应力锚栓安装施工技术,包括定位埋设工艺、锚栓张拉和灌浆工艺等内容。     

柴油成膜润滑机制探讨

柴油是发动机燃料供给系统的润滑剂,其润滑性非常重要。在高频往复试验机上对不同柴油样品进行了润滑性评价,对试验后的金属件进行磨斑表面分析,通过对比研究,探讨了柴油成膜润滑机制。结果表明,柴油成膜组分少,不能形成良好润滑保护膜,或者因腐蚀反应不能形成有效润滑保护膜,是柴油润滑性差并导致偶件磨损的原因。     

Wake patterns of flow past a pair of circular cylinders in side-by-side arrangements at low Reynolds numbers

A flow past two side-by-side identical circular cylinders was numerically investigated with the unstructured spectral element method. From the computational results at various non-dimensional distances between cylinder centers T/D and the Reynolds number Re, a total of nine kinds of wake patterns were observed: four steady wake patterns, including single bluff-body steady pattern, separated double-body steady pattern and transition steady pattern for sub-critical Reynolds numbers and biased steady pattern for super-critical Reynolds numbers, and five unsteady wake patterns, including single bluff-body periodic pattern, biased quasi-steady pattern, quasi-periodic (flip-flopping) pattern, in-phase-synchronized pattern and anti-phase-synchronized pattern. Time evolution of lift and drag coefficients corresponding to each unsteady wake pattern was given.