Mg-doped LiNi0.5Mn1.5O4 spinel for cathode materials

Lithium-ion batteries are becoming more and more important not only for portable electronic devices, but also in prevision of high power electric vehicles. In such an optic, deep studies regarding all the components of a secondary battery are in development. In this study, high voltage cathode materials have been selected. Crystals with spinel structure have a 3D vacancy pathway suitable for Li-ions transport. The material under study was LiNi_0.5Mn_1.5O₄ doped with magnesium replacing the nickel. Various samples were synthesized via three different routes: a solid-state method, a modified sol–gel method and a xerogel method. The structure and morphology of the powders were analyzed with HRTEM and XRD. Electrochemical tests were also performed. A wide range of particle sizes (from micro to nanosize) was the result of the different synthesis routes. Unfortunately pure materials were not always obtained. The electrochemical tests showed improvement of the material's cyclability, by reducing the particle size. The electrochemical tests further confirmed the existence of a Li_1+dMn_2−dO₄ impurity. The results are quite promising, however, further improvement of the purity of the electrode composition are needed.     

Analysis of the turbine deblading in an HTGR with the CATHARE code

The direct coupling of a Gas Cooled Reactor (GCR) with a closed gas-turbine cycle leads to a specific dynamic plant behaviour. This behaviour is described and illustrated through computer analyses performed at CEA with the computer code CATHARE. This analysis requires a 1D code able to simulate the whole reactor, including the core, the vessel, the piping and the components (turbine, compressors, heat exchangers).This paper is devoted to deblading accidents. The problems and solutions encountered in various types of gas-turbines are presented: aero engines, steam turbines (EDF-Porcheville steam turbine accident feedback) and finally the feedback from previous High Temperature Gas Reactor experiments (EVO helium loop, HHT project and other HTR projects) are displayed. From this literature survey, some recommendations are drawn for a future High Temperature Reactor. It is shown that for safety reasons in case of deblading, a horizontal shaft aligned with the reactor vessel is recommended for the turbomachinery.This paper presents simulations of different scenarii performed with CATHARE code:

(a) Turbine deblading with and without reactor trip. In these calculations, a pessimistic assumption has been made: all turbine blades break off.

(b) Total flow blockage. The flow area is entirely blocked by the turbine blades.

(c) Partial flow blockage. Previous conclusions consider the worst cases of deblading and total flow blockage. An intermediate case based on a partial deblading has also been performed.

CATHARE results illustrate that the loss of turbine blades is accompanied by abrupt changes in the Power Conversion System and reactor flow conditions: large axial pressure drop, reverse flow through the core and high rate de-pressurization.     

排气结构对导叶式旋风管分离性能的影响

通过对比实验测定了不同排气结构下导叶式旋风管的分离效率及压降,同时用智能型五孔球探针测试仪测定了不同排气结构的旋风管内流场分布,结合性能实验与流场测量的结果,研究了排气芯管内径及其结构型式对分离性能的影响,为旋风管结构优化和开发及其分离机理的研究提供了一定的实验基础。     

Performance of a non‐load‐bearing steel stud gypsum board wall assembly: Experiments and modelling

A gypsum wall assembly was exposed to an intense real‐scale compartment fire. For the wall assembly, temperatures were measured at the exposed face, within the stud cavity, and at the unexposed face during the fire exposure. Total heat flux gauges were used to measure the temporal variation of the energy incident on the walls, and cameras, both visual and infrared, were used to image the unexposed face of the wall assembly during the fire exposure. The behaviour of the wall assembly under the fire load is discussed as are current model results for a simulation of the fire test. Copyright © 2006 John Wiley & Sons, Ltd.     

Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

New high-silicon zeolites of the TsVN series

Translated from Khimiya i Tekhnoloyiya Topliv i Masel, No. 3, pp. 3–5, March, 1989.