Removal of endocrine disrupting chemicals (EDCs) using low pressure reverse osmosis membrane (LPROM).

Endocrine disrupting chemicals (EDCs) are the focus of current environmental issues, as they can cause adverse health effects to animals and human, subsequent to endocrine function. The objective of this study was to remove a specific compound of EDCs (i.e. pentachlorophenol, C(6)OCL(5)Na, molecular weight of 288 g/mol) using low pressure reverse osmosis membrane (LPROM). A cross flow module of LPROM was used to observe the effects of operating parameters, i.e. pH, operating pressure and temperature. The design of the experiment was based on MINITAB(TM) software, and the analysis of results was conducted by factorial analysis. It was found that the rejection of pentachlorophenol was higher than 80% at a recovery rate of 60 to 70%. The rejection was subjected to increase with the increase of pH. The flux was observed to be increased with the increase of operating pressure and temperature. This study also investigated the interaction effects between operating parameters involved.     

The impact of cleaner processing on nutrient availability in the bleached kraft industry.

The pulp and paper industry has invested heavily over recent years in cleaner processing, to reduce losses and minimise its impact on the environment. Over the past fifteen years, a New Zealand integrated bleached kraft mill has undergone a comprehensive programme of upgrades to increase production, reduce water consumption and streamline its biological treatment process. Whilst the overall discharge of contaminants from the site decreased, the treatment system performance did not show a concurrent improvement as may have been expected. Reduced BOD removal, low dissolved oxygen levels, and poor solids settlability were symptomatic of phosphorus limitation in the aerated lagoon treatment system. The wastewater entering the system was found to be phosphorus limited at a BOD:P ratio of 100:0.2. Mono-ammonium-phosphate was supplemented, at approximately 30 kg P/d, to raise the phosphorus levels to a BOD:P ratio of 100:0.3. Treatment efficiencies improved very quickly after phosphorus dosage, with a 50% reduction in BOD and TSS discharge, a significant increase in dissolved oxygen levels, and improved BOD removal (85% to 93%). This case study demonstrates that whilst more closed operation can result in reduced discharge of organic loads, there may be negative impacts on the availability of nutrients for balanced biological growth.     

Measurement and modeling of the sidewall threshold voltage ofmesa-isolated SOI MOSFETs

Five-terminal silicon-on-insulator (SOI) MOSFETs have been characterized to determine the threshold voltage at the front, back, and sidewall as a function of the body bias. The threshold voltage shift with the body bias at the front and back interfaces can be explained by the standard bulk body effect equation. However, the threshold voltage shift at the sidewall is smaller than predicted by this equation and saturates at large body biases. This anomalous behavior is explained by two-dimensional charge sharing between the sidewall and the front and back interfaces. An analytical model that accounts for this charge sharing by a simple trapezoidal approximation of the depletion regions and correctly predicts the sidewall threshold voltage shift and its saturation is discussed. The model makes it possible to measure the sidewall threshold even when it is larger than the front threshold voltage     

Kinetics of zinc oxide formation from zinc sulfide by reaction with lime in the presence of water vapor

A novel reaction scheme for transforming certain metal sulfides to the corresponding oxides has been developed. In this process, steam oxidizes the sulfide into the oxide, and the hydrogen sulfide produced reacts with lime to form calcium sulfide and regenerate steam. There is no net consumption or generation of gaseous species. Thus, the overall reaction can be carried out in a closed system as far as the gas phase is concerned. This eliminates the possibility of emitting hydrogen sulfide out of the reactor. Only certain metal sulfides are thermodynamically amenable to this treatment. In this paper, the reaction of ZnS to ZnO by this scheme is described, together with a detailed formulation of the rate equation for the overall reaction based on the kinetics of the component gas-solid reactions. Although the present work was done with CaO, other suitable oxides may be used in its place. A further potential application of this process is to the selective oxidation of certain sulfide(s) from complex sulfide ores as a treatment prior to the separation of minerals.     

Organ distribution of bovine serum albumin administered intragastrically in the rat

Radioimmunoassay was employed to examine distribution of antigenic structures of bovine serum albumin (BSA), absorbed by the gastrointestinal tract, in the blood serum and organs of intact rats. It was shown that 3 h after administering 3H-BSA an appreciable amount of its antigenic structures could be identified in the blood serum, liver, spleen, and carcass of the animals. The total amount of antigenic determinants of BSA which got into the internal environment of the body from the intestine amounted to about 0.2% of the dose administered. The highest specific content of antigenic structures of BSA supplied via the intestinal barrier was detected in the spleen.     

Preliminary model of the Ribeira Grande geothermal field (Azores Islands)

On the basis of a geological - volcanological - geophysical survey, integrated with petrological and geochronological data, a structural model, including a shallow magmatic body, was defined for the Ribeira Grande area, Sao Miguel island (Azores). Two series of production tests were carried out in the Pico Vermelho 1 and Ribeira Grande 1 wells, which led to a preliminary definition of the deep fluid circulation. The data obtained from these studies were used to reconstruct a preliminary model of the Ribeira Grande geothermal field.     

LaK747/509璃璃配方的研究

本工作中我们选择了B₂O₃-La₂O₃-Y₂O₂-ZrO₂系统作为玻璃基础组成。最后获得的LaK747/509玻璃组成中,不含有钍的成份。由于该玻璃具有一系列好的性质,如析晶范围窄、析晶速度慢以及粘度大等等,因此可以成功地在12-30L铂埚中进行熔制,并获得了尺寸为φ200×25mm的高质量玻璃。     

Corrosion protection of iron by polypyrrole coatings electrosynthesised from a surfactant solution

This work is a study of the electropolymerisation of pyrrole onto iron electrodes in the presence of sodium bis(2-ethylhexyl) sulfosuccinate in a wide pH interval. The characterisation of the films was done using electrochemical techniques, SEM/EDX and IR spectroscopy. We show that it is possible to synthesise homogeneous, adherent and very compact films in the pH range between 7 and 12 under potentiodynamic, galvanostatic and potentiostatic conditions without substrate dissolution. The effects of various parameters on electrodeposition were investigated. The new procedure for the electrochemical synthesis of polypyrrole results in improved anticorrosion properties. The inhibition is proposed to be due to the sum of a repulsion of chloride ions because AOT remains entrapped in the polymer matrix and the presence of the iron oxide. Advantages of the use of surfactants in the electropolymerisation solution are discussed.