塔里木盆地塔中Ⅱ区奥陶系油气差异富集模式

针对塔里木盆地塔中Ⅱ区奥陶系油气多相态共存、产能差异和富集模式认识不清的问题,采用油藏地球化学方法分析了奥陶系流体性质、分布特征及成因。油藏pVT相态分析认为存在凝析气藏与轻质油藏沿走滑断裂共存的现象,原油的成熟度参数显示为成熟阶段的产物,天然气碳同位素和烃类比值揭示组分为原油伴生气和原油裂解气的混合,金刚烷化合物及天然气分析显示中寒武统盐下原油裂解气的充注是奥陶系凝析气藏形成的重要原因。结合高精度三维地震解释发现油气分布受到走滑断裂的控制,马尾、翼尾、走滑断裂带与逆冲断裂交汇部位具有较低的原油密度和含蜡量,以及较高的气/油比、干燥系数、4-MDBT/1-MDBT比值等,为油气充注的有利通道,走滑断裂周期性开启与膏盐层封堵机制耦合控制了塔中Ⅱ区奥陶系油气成藏。综合研究认为,塔中Ⅱ区油气具有侧生邻储、走滑断裂垂向输导、沿走滑断裂富集的特征,多期点状油气充注是造成奥陶系油气差异分布的重要原因。走滑断裂控制了奥陶系油气富集,马尾地堑、翼尾地堑、走滑断裂带与逆冲断裂交汇构造部位仍有较大的勘探潜力,中寒武统膏盐层下可能发育大规模气藏,需要进一步关注。     

不同标号沥青的流变性能

借助温度扫描、频率扫描、多重应力蠕变恢复等实验,对20号、30号、50号、70号沥青及其旋转薄膜烘箱老化后沥青的流变性能进行了评价。结果表明：随着温度升高,4种沥青老化前后复数剪切模量和车辙因子均降低,并且老化后的高于老化前;在60℃温度下,无论是在低频还是高频荷载作用下,标号越低,沥青耐剪切变形能力越强,耐车辙性越好,而应力敏感性降低;标号越低的沥青,G-R参数值越大,耐开裂性则降低。     

Bioelectrochemical sulfate reduction enhanced nitrogen removal from industrial wastewater containing ammonia and sulfate

Low organic carbon-to-nitrogen ratio and existing sulfate (SO₄²⁻) in industrial wastewater limited nitrogen removal. Coupling SO₄²⁻ reduction with sulfide autotrophic denitrification provides a novel strategy. Herein, bioelectrochemical sulfate reduction was coupled with heterotrophic sulfate reduction to drive sulfide autotrophic denitrification. In this coupled system, total nitrogen (TN) removal efficiency was increased from ~25% to ~85% by inputting −45 mA electricity. With the help of supplying electrons to denitrification through SO₄²⁻ reduction, coulomb efficiency was improved to 61.5%. Also, bioelectrochemical sulfate reduction could improve sulfur recovery and thus increase TN removal efficiency. Furthermore, through tuning turnover numbers of SO₄²⁻, high TN removal efficiency can be obtained at various concentrations of SO₄²⁻. Moreover, main functional bacteria in this system were identified. Finally, ~75% TN removal efficiency was achieved with real wastewater in this system. Overall, this work offered a new approach for efficient nitrogen removal from industrial wastewater containing SO₄²⁻.     

Low-fire processing and microwave dielectric properties of LB glass-doped Ba3.75Nd9.5Ti17.5(Cr0.5Nb0.5)0.5O54 ceramic

The effects of LB glass on the sintering behavior, structure, and dielectric properties for the Ba_3.75Nd_9.5Ti_17.5(Cr_0.5Nb_0.5)_0.5O₅₄ (BNTCN) ceramic were investigated. The results showed that the LB glass, as an effective sintering aid, successfully lowered the sintering temperature of BNTCN ceramic by formation of the liquid phase. Furthermore, the change of the structure and decrease in grain size had influences on the electrical conductivity, thermal stability, and microwave dielectric properties for the BNTCN ceramics doped LB glass. Finally, the excellent microwave dielectric properties with ε_r = 73.4, Q × f = 5277 GHz, and τ_f = +7.1 ppm/°C were obtained for samples sintered at 950°C when x = 5, indicating the BNTCN ceramic doped with 5 wt% LB glass is a promoting LTCC material.     

High extinction-ratio microstructure fiber based on chalcogenide glasses

Extinction ratio (ER) is one of the important parameters to characterize the polarization-maintaining (PM) performance of the fiber. In this paper, we report the preparation and properties of a novel chalcogenide microstructure fiber with a high ER. We fabricate a preform using a peeled-off extrusion method. The core and cladding material of the fiber are Ge₉As₂₃Se₆₈ and Ge₁₀As₂₂Se₆₈. The preform was drawn into a fiber with an average ER of −17.08 dB. The loss of the fiber is less than 2 dB over 5.20–8.55 μm, and the minimum loss of the fiber is 0.57 dB/m at 6.2 μm. Moreover, a flat mid-infrared supercontinuum spectrum spanning from 1.53 to 12.50 μm is generated by pumping an 18-cm-long PM fiber for the first time.     

MWCNTs reinforced conductive,self-healing polyvinyl alcohol/carboxymethyl chitosan/oxidized sodium alginate hydrogel as the strain sensor

The preparation and application of hydrogel has been a hot research field in recent years. Here in, a composite hydrogel based on poly(vinyl alcohol) (PVA), carboxymethyl chitosan (CMCS), oxidized sodium alginate (OSA), and oxidized multiwall carbon nanotubes (OMWCNTs) was successfully prepared. Hydrogen and imine bonds of the hydrogel endowed the composite hydrogel with self-healing property and pH sensitivity. The fracture strength of the hydrogel was enhanced to about 0.8 MPa with the help of OMWCNTs, which was about 2.5 times compared with the one without OMWCNTs. Meanwhile, a new conductive network inside the hydrogel was constructed by OMWCNTs, which improved the conductivity of the hydrogel from 1.75 × 10⁻⁴ to 7.02 × 10⁻⁴ S/cm. The sensing test of the hydrogel showed that it could produce profound feedback signals for the deformation caused by external force and response to human body movements, such as finger bending, swallowing, and speaking.     

Preparation and study of stable fluorine-free superhydrophobicity of cotton fibers

This paper proposes a method of directly modifying the surface of cotton fiber to achieve super-hydrophobic properties. The process was directly utilized the long-chain alkyl siloxane and the nano-SiO₂ modified cotton cloth, which was simple to operate, low in cost and environmentally friendly. This study discussed the influence of solvent ratio, reactant content and ammonia content on hydrophobicity. The solvent ratio had the greatest influence, and the maximum water contact angle (CA) changes were70° ± 1°. The maximum water CA of the superhydrophobic cotton fabric prepared after process selection was 162 ± 1.5°; it had good acid, alkali and salt resistance. After 24 h in a solution with a pH of 1–14, CA remained almost unchanged; After 144 h in a 3.5% salt solution, CA stabilized above 132°; it had self-cleaning properties; it had good selective adsorption performance, which can quickly separate oil and water; it had good mechanical stability. After 300 times abrasion of sandpaper, which still shows hydrophobic properties.     

六分量大阻力复合式结构天平研制与应用

着陆巡视器和探月返回舱等短钝体风洞试验模型具有更大的阻力测量范围和更短的长度尺寸,为了提高该类模型在风 洞试验中的测量精准度,研制了一种新型复合式结构大阻力六分量应变天平。 与传统串联式结构天平相比,复合式结构天平结 构紧凑而阻力承载能力更强,能够完全安装于模型内部从而减少温度对天平测量精准度的影响;数值模拟结果表明,复合式结 构天平的平均应变、灵敏度、强度等能够满足风洞试验要求;复合式结构天平静态校准综合校准准度优于 0. 21%,满足国军标相 关技术指标。     

中性点经小电阻接地风电场集电线路单相接地故障测距研究

风电场集电线路呈现多分支、多电源接入的形态。线路发生单相接地故障后,不同分支上风机依据感受到的电压降的不同而自动投入不同的低穿控制策略,从而会导致输出不同的分支电流,使得基于阻抗原理的测距方法失效。该文巧妙地利用风机箱变高压侧采用三角形接线的现实,无零序电流回路,提出基于故障区段逐次搜索的单相接地故障测距方法,并引入描述故障点弧光接地的对数电弧模型,实现了较高的测距精度。仿真算例和实际案例数据验证了算法的有效性。该算法可同时求解得到故障点电弧的长度,为后续的故障类型辨识奠定了基础。     

全半桥混合MMC启动特性研究及实验验证

目前,对模块化多电平换流器(MMC)的启动特性研究主要集中在半桥MMC的启动方法的研究与分析,未对全半桥混合型MMC启动过程进行过多分析.从全半桥混合型MMC的基本结构及交流侧不控充电的原理出发,详细分析了换流器启动过程中直流侧的电压及功率模块电压.提出了一种全半桥混合MMC启动方法.在PSCAD/EMTDC中搭建了全半桥混合型MMC充电仿真模型,对全半桥混合型MMC的充电过程进行仿真研究,仿真研究结果在±10 kV混合型换流阀样机实验中得到了验证.