Photoinduced electron transfer in panchromatic zinc phthalocyanine–azobenzene dyad

A new unsymmetrical azobenzene–phthalocyanine dyad was designed and synthesized. Besides impressive panchromatic absorptivity both in solution and adsorbed on solid-state anatase TiO₂ substrate, efficient photoinduced electron transfer from azobenzene π* orbital to phthalocyanine S₁ orbital was elucidated for the first time by fluorescence spectroscopy and cyclic voltammetry. Such an interesting phenomenon as a dominant intra-molecular electronic communication process is attributed to the inefficiency of local deactivation pathway through orbital overlap forbidden π* → n transition. This may imply efficient collection of panchromatic photoelectrons by delicate molecular design and is expected to boost fields related to solar energy utilization.     

Influence of iodine concentration on the photoelectrochemical performance of dye-sensitized solar cells containing non-volatile electrolyte

The effect of iodine concentration in the electrolyte with non-volatile solvent of dye-sensitized solar cells (DSCs) on photovoltaic performance was studied. The electron transport and interfacial recombination kinetics were also systematically investigated by electron impedance spectroscopy (EIS). With the iodine concentration increased from 0.025 to 0.1 M, open-circuit voltage (V_oc) and photocurrent density (J_sc) decreased while fill factor (ff) increased significantly. The decline of the V_oc and J_sc was mainly ascribed to increased electron recombination with tri-iodide ions (I₃⁻). The increased fill factor was primarily brought by a decrease in the total resistance. From impedance spectra of the solar cells, it can be concluded that increasing the iodine concentration in electrolytes could decrease charge transfer resistance (R_ct) and the chemical capacitance (C_μ), increase the electron transport resistance (R_t), and hence decrease the electron lifetime (τ) and the effective diffusion coefficient (D_n) of electrons in the TiO₂ semiconductor. With optimum iodine concentration, device showed a photocurrent density of 16.19 mA cm⁻², an open-circuit voltage of 0.765 V, a fill factor of 0.66, and an overall photo-energy conversion efficiency of 8.15% at standard AM 1.5 simulated sunlight (100 mW cm⁻²).     

在386微机上移植结构分析软件SAP6

本文介绍了一个在３８６微机上用ＮＤＰ－ＦＯＲＴＲＡＮ－３８６开发的ＳＡＰ６程序，并讨论了其中的一些技术问题．     

万向接轴损伤容限评定模型

本文对万向接轴损伤容限评定的基本任务提出了建议，构造了Ⅰ－Ⅲ复合型半椭圆及角裂纹脆断临界裂纹尺寸的计算方法，提出了裂纹疲劳扩展过程中形貌变化方程的新解法，建立了疲劳寿命预测的循环续循环模型。     

CAPL焊接工艺规范的优化

本文提出了焊接工艺在线调整基本原理，运用作者已建立的实验－数模法，优化了冲压钢冷轧薄板田平缝焊工艺规范，探讨了焊件特征对焊接参数的影响规律。     

Multifunctional modification of Fe3O4 nanoparticles for diagnosis and treatment of diseases: A review

With the rapid improvements in nanomaterials and imaging technology,great progresses have been made in diagnosis and treatment of diseases during the pastdecades.Fe₃O₄ magnetic nanoparticles(MNPs)with good biocompatibility and super-paramagnetic property are usually used as contrast agent for diagnosis of diseases inmagnetic resonance imaging(MRI).Currently,the combination of multiple imagingtechnologies has been considered as new tendency in diagnosis and treatment ofdiseases,which could enhance the accuracy and reliability of disease diagnosis andprovide new strategies for disease treatment.Therefore,novel contrast agents used formultifunctional imaging are urgently needed.Fe₃O₄ MNPs are believed to be a potentialcandidate for construction of multifunctional platform in diagnosis and treatment ofdiseases.In recent years,there are a plethora of studies concerning the construction ofmultifunctional platform presented based on Fe₃O₄ MNPs.In this review,we introducefabrication methods and modification strategies of Fe₃O₄ MNPs,expecting greatimprovements for diagnosis and treatment of diseases in the future.     

1.44~1.68GHz 220W硅微波脉冲功率晶体管

南京电子器件研究所近期研制成功1.44～1.68GHz 220 W硅微波脉冲功率晶体管.该器件在1.44～1.68 GHz频带内,脉宽200 μs,占空比10%和40V工作电压下,全带内脉冲输出功率大于220 W,功率增益大于7.1 dB,效率大于45%.该器件采用高效梳条状结构,单元间距6μm,发射极和基极线宽1.9μm,金属条间距1.6μm.每个器件由6个面积为1 600μm×800 μm功率芯片组成,每个功率芯片含有2个大功率子胞.整个器件包含12个大功率子胞、20个内匹配电容和200多条连接金丝.     

20g钢焊接接头冷弯开裂及断裂行为的研究

本文考察了一侧经手弧焊,另一侧经埋弧自动焊焊接接头的显微组织,并用扫描电镜对断口进行了分析。在此基础上,研究了接头的冷弯开裂及断裂行为。结果表明:只有埋弧焊一侧产生冷弯开裂或断裂现象。冷弯初期,在过热区出现裂纹,但在随后的弯曲过程中无明显扩展,这是由于裂纹周围的显微组织具有较大的抗裂纹扩展阻力。冷弯后期,焊缝产生裂纹并迅速扩展而断裂,这主要是由于条虫状气孔的存在所致,而显微气孔及少量的球状显微夹杂对断裂仅起着促进作用。     

镍基合金表面激光熔覆CoNiCrAlY合金的组织与性能

在镍基合金上激光熔覆CoNiCrAlY合金，制备了单层、多层试样和工件。利用金相显微镜、X射线衍射仪、显微硬度计和高温电炉，对熔覆层的组织、相结构、硬度及抗氧化性进行了测试和分析。结果表明：熔覆层的组成相有γ-Co，Ni2Y和Cr3Ni2Sic，熔覆层的氧化物为CoAl2O4，Al2O3，CoNiO2，NiCr2O4，CoCr2O4；单层熔覆层组织细小致密；由于预热的作用，搭接熔覆的组织较粗大；界面处的结晶方向垂直于界面，层问、两道之间搭接区、重熔区和多层熔覆的近表面组织有等轴化的倾向；熔覆层具有较高的硬度，加入稀土元素Y，可以增大氧化物的表面附着力、改善熔覆层的抗氧化性能；熔覆层在1100℃是抗氧化的。     

铝合金/纳米碳管/钛复合层激光合金化组织

使用真空镀的方法在铝合金表面形成CNTs／Ti/Al/…多层复合，经激光合金化形成复合涂层。利用X射线衍射和扫描电镜对复合层的相构成及微观组织进行了分析。结果表明：铝合金表面复合层在激光合金化后存在着TiC颗粒和CNTs，TiC的含量随着激光功率的增加而增加；CNTs仍保留其原有的管状结构，且在复合层中相互缠绕呈网状均匀弥散分布；反应原位合成的TiC颗粒尺寸均匀细小，附着于CNTs上．从而改善了CNTs与基体之间的结合性能。