环己烷液相无催化剂的氧化动力学研究

采用搅拌釜反应器,在确认已排除传质因素对反应速率影响的情况下,研究了环己烷液相无催化剂的氧化反应动力学。应用自由基理论及最优化计算技术,从导出的8个候选动力学模型中,确定了最佳的动力学模型,它能满意地描述环已烷氧化过程。该动力学可为环己烷氧化工业生产操作条件的优化、反应器的选型及工业设计提供依据。     

Cu2O/Cu Cermet as a Candidate Inert Anode for Al Production

Cu₂O/ x Cu ( x =0–25 wt%) cermets were evaluated as a novel partially inert anode for aluminum (Al) production. The physical and mechanical properties, including the compressive strength, flexural strength, thermal expansion coefficient, thermal conductivity, and dc electrical conductivity were tested at room temperature and at temperatures up to 950°C. The coefficient of thermal expansion, compressive strength, flexural strength, thermal conductivity, and electrical conductivity of Cu₂O/Cu cermets increased with increasing Cu content. High-temperature electrical conductivity measurements showed that with increasing temperature, the electrical conductivity increased when the Cu content was below the percolation threshold, while it decreased when the Cu content was above the percolation threshold. A relatively stable CuAlO₂ layer formed on the cermet surface during electrochemical testing, and the corrosion rate of this anode was estimated to be about 1.8–1.9 cm/year in Al production.     

Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

乙环唑的合成研究

介绍了以2,4-二氯苯乙酮为原料通过催化溴化、缩合反应、与三氮唑钠反应制得原药,原药含量达到92%以上.并对合成条件进行了研究,取得了较为满意的结果.     

广角摄像机在机器人视觉定位中的应用

为了保证广角摄像机在现代机器人视觉定位应用中的准确性,以广角摄像机像素坐标的反畸变过程为研究对象,提出一种在畸变对应表的基础上使用中心迭代法以及区域插值法确定物体实际位置的方法。通过实验证明了该方法能够测量物体的位置,其精度能够满足工业使用要求。     

入侵检测技术在消防信息网安全中的应用

消防信息网作为公安网子网,与互联网物理分隔,网络安全相对薄弱,自身的安全防护能力并不高。非法入侵、病毒破坏屡有发生,给消防信息网带来不可预测的后果。     

考虑过程能力和成本的刀具策略研究

为了提高定期维修的刀具所加工的产品质量,减少停机时间和生产成本.考虑生产过程中工件尺寸的残差是时间的函数,利用Glejser检验方法,拟合工件尺寸残差符合的递增型异方差模型,提出了刀具磨损过程的过程能力指数计算方法;使用Bernstein概率密度函数描述刀具寿命和刀具磨损过程的一般特征,在每一个维修周期内均满足顾客要求的最小过程能力指数基础上,考虑质量损失、换刀成本、由刀具的突然失效引发的惩罚成本及维修刀具所需的成本,将过程能力与成本相结合,提出了用于确定最佳刀具初始状态和维修周期的模型.该模型为实际生产提供了一种离线的刀具管理方法.     

Synchronization and channel estimation for MIMO OFDM wireless LAN systems

A new preamble structure is designed for wireless LAN based on MIMO OFDM systems, which can be used for both synchronization and channel estimation. Modulatable orthogonal polyphase sequence is utilized in training symbol design regarding its correlation properties. The time synchronization and channel estimation are achieved by measuring the correlation between the received training sequence and the locally generated training sequence. Repeated training symbols are used to get carrier frequency offset (CFO) estimation. It is shown from the analysis that the accuracy of frequency synchronization is close to the Cramér-Rao lower bound. The training sequences are optimal for channel estimation based on the minimum mean square error (MMSE).     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.     

米曲霉在牛乳中最适生长条件的研究

利用米曲霉对牛乳进行发酵,通过单因子及正交试验以菌丝体干重为指标对其在牛乳中的生长进行了研究．结果表明：接种量为4％,装液量为30mL,摇床转速为180r／min时菌丝体干重可达到最大．此外测得最大菌丝体干重时的蛋白质分解率可达35．6％．