Numerical and experimental investigations of laser shock forming aluminum alloy sheet with mold

Laser shock forming (LSF) technology employs shock waves to form sheet metal into three-dimensional complex parts, and has application potential in manufacturing sheet metal parts. In this paper, the forming of 2024 aluminum alloy sheet with LSF was investigated through numerical and experimental methods. The numerical model was established with the commercial code ABAQUS/Explicit. The formed conical cup was obtained from the simulation, and validated by the experiment. With the verified numerical model, the deformation behaviors, including deformation velocity, sheet thickness variation and strain distribution, were studied. In addition, the influence of different shock wave pressures on the forming precision was also investigated. The experimental and numerical results show that the metal sheet loaded by shock wave can take the shape of the mold, and the non-uniform thickness is distributed in the formed cup. The investigations also display that there exists reverse deformation at the central region of deforming sheet owing to severe collision during LSF. In order to obtain formed part with better quality, an appropriate pressure of applied shock waves is required.     

Unique role of non-mercapto groups in thiol-pinning-mediated Ag growth on Au nanoparticles

Owing to the strong affinity of thiols to Au and Ag, they are often employed to modify the surfaces of nanoparticles (NPs). Recently, these strong ligand-interface interactions have been employed to control NP growth, and this technique has emerged as a unique modulation strategy for creating unconventional plasmonic hybrid nanostructures. In these systems, the roles of the non-mercapto components of the thiol molecules and their structures are still unknown. Therefore, we herein present our investigation into this phenomenon. Primary amino (–NH₂) groups in thiols are found to play a key role in regulating growth kinetics, i.e., in accelerating Ag deposition on Au NPs. The–NH₂ groups are thought to bring Ag ions to the particle surface by coordinating to them, and thereby assist their reduction. The effect of molecular structure is non-trivial and thus provides the possibility of selective thiol detection. Based on the dependence of kinetic modulation on the non-mercapto components and molecular structures of molecules, we demonstrate the highly sensitive and specific detection of cysteine (limit of detection: 6 nM) in a mixture of 19 natural amino acids based on Ag growth on Au nanospheres. In addition, based on this modulation effect, we reveal the entrapping of chiral thiols within the growth layer through their plasmonic circular dichroism (PCD) responses. We believe that thiol-based growth regulation has great potential for creating plasmonic nanostructures with novel functionalities.

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Synthesis of ultrathin semicircle-shaped copper nanowires in ethanol solution for low haze flexible transparent conductors

Nano Research - Copper nanowires (CuNWs) are becoming an indispensable item for next-generation transparent optical devices due to their excellent conductivity and transparency. In this work,...     

Reliability analysis on systems with self-healing and self-repairing under different environments and shock models

Inspired by the process of self-healing of biological damage, high technology materials with self-healing and self-repairing mechanisms have been developed for high reliability and long lifetime. Therefore, the reliability modeling on intelligent systems with healing performance has become a research hotspot. Based on the diversity of healing mechanisms, this paper proposes a two-phase reliability model method on self-healing and self-repairing systems. Impacts of environments, shock loads, self-healing, and self-repairing mechanisms are taken into account in this novel model. Besides, system lifetime and some reliability indexes under two shock models are derived, respectively. Moreover, Monte Carlo simulations are conducted to verify the accuracy of reliability under two models. Finally, an engineering case of metallized film capacitor is provided to illustrate the effectiveness and applicability of the proposed models by comparing numerical results and simulation results.     

二溴对甲基偶氮甲磺光度法测定钢中微量锶

研究了二溴对甲基偶氮甲磺与锶生成2:1兰色络合物进行钢中微量锶的测定.该法λ_(max)=638nm,摩尔吸光系数E_(638)=5.01×10~4,锶量在0.02～0.34μg/L范围内服从比尔定律.方法已用于钢中微量锶的测定,结果满意.     

"震网"引发网络安全新思考

本文概述了近期发生的"震网"事件.同时分析了"震网"的特点和行为特征.并根据我国的具体情况给出了安全警示和安全防范建议.     

平面设计Photoshop教学的探索与研究

计算机平面设计行业作为知识型的服务产业,在竞争日益激烈的商业社会中发挥着举足轻重的作用。Photoshop(以下简称PS)是一门实践性很强的课程,使用传统的教学方法无法达到满意的教学效果。在教学方法的探索与实践中,采用抛砖引玉引导学习法、案例教学法、情景教学法、先成果后教学法等多种教学方法,引发学生的学习兴趣,培养学生的模仿和创新能力。同时,采用分阶段教学方法,使学生更好地掌握该软件,进一步提高教学质量。     

网络监察民警培训中教学质量提升途径的探索

在新形势新任务要求下,网络监察民察的培训存在很大的难度。本文首先介绍了网络监察民警培训的必要性,然后重点从培训课程体系、师资队伍建设、教学的方式方法和实训教学环节等方面进行了探讨,以确保培训教学质量的稳步提升。