The present study reports the titanium dioxide (TiO2) films synthesized from TiCl3 precursor on ITO glass substrates using two electrochemical techniques, namely direct electro-deposition (DE) and pulse electro-deposition (PE). The synthesis potential during the time-on (Ton) period was fixed at ?1.5 V. However, the open-circuit potential was applied during the time-off (Toff) period. The effect of the technique of electro-deposition and Toff duration on the properties of TiO2 films and their photoelectron-catalytic activity were investigated. The obtained films were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-VIS spectrometer, and photocurrent measurement respectively. It is found that the use of the PE technique at different Toff improves the properties of TiO2 films compared to the DE technique. The XRD patterns show the anatase phase with a marked preferential orientation along the (101) direction for all samples. From the SEM analysis, it is seen a significant change from big multigrain agglomerates at DE to a dense film structure and small multigrain agglomerates at different Toff. As the Toff decreases from 3 s to 1 s, the photocurrent response rises and reaches a high value of about 12 mA/cm2. Compared with DE, and under UV light the photocatalytic property of TiO2 film synthesis via PE has been improved in the degradation of methyl orange (MO). Finally, the films deposited at low Toff (Toff =1 s) show a faster degradation of MO. 相似文献
Wireless sensor networks (WSNs) are susceptible to many security threats and are specifically prone to physical node capture in which the adversary can easily launch the so-called insider attacks such as node compromise, bypassing the traditional security mechanisms based on cryptography primitives. So, the compromised nodes can be modified to misbehave and disrupt the entire network and can successfully perform the authentication process with their neighbors, which have no way to distinguish fraudulent nodes from trustworthy ones. Trust and reputation systems have been recently suggested as a powerful tools and an attractive complement to cryptography-based schemes in securing WSNs. They provide ability to detect and isolate both faulty and malicious nodes. Considerable research has been done on modeling and managing trust and reputation. However, trust topic issue in WSNs remains an open and challenging field. In this paper, we propose a Risk-aware Reputation-based Trust (RaRTrust) model for WSNs. Our novel framework uses both reputation and risk to evaluate trustworthiness of a sensor node. Risk evaluation is used to deal with the dramatic spoiling of nodes, which makes RaRTrust robust to on–off attack and differ from other trust models based only on reputation. This paper contributes to model the risk as opinion of short-term trustworthiness combining with traditional reputation evaluation to derive trustworthiness in WSNs.
Laurus nobilis essential oils from Tunisia, Algeria and Morocco were analyzed for their chemical composition and assessed for their repellent and toxic activities against two major stored product pests: Rhyzopertha dominica and Tribolium castaneum. The three oils showed quantitative rather than qualitative differences in their chemical compositions. 1,8-cineole, linalool and isovaleraldehyde, were identified as the major common compounds whereas, α-pinene, α-terpineol, eugenylmethylether, β-pinene, spathulenol and β-myrcene were also well represented in all three oils. Results showed that L. nobilis essential oils were repellant and toxic to adults of R. dominica and T. castaneum. Repellent and fumigant toxicities were highly dependent upon insect species and oil origin.In filter paper tests, L. nobilis essential oil from Morocco was more effective compared to Tunisian and Algerian oils. RD50 values were respectively 0.013 μl/cm2, 0.036 μl/cm2 and 0.033 μl/cm2 for R. dominica versus 0.045 μl/cm2, 0.139 μl/cm2 and 0.096 μl/cm2 for T. castaneum. Moreover, fumigant activity tests showed that both R. dominica and T. castaneum were more susceptible to L. nobilis essential oil from Morocco than that from Algeria or Tunisia. The corresponding LC50 values were respectively 68, 99 and 113 μl/l air for R. dominica against 172, 194 and 217 μl/l air for T. castaneum. Our work clearly vindicates interest in the efficacy of essential oils from plants of Mediterranean origin both as insecticides and repellents against stored product pests. 相似文献
Six Tunisian durum wheat genotypes (4 landraces and 2 improved) were evaluated for protein content, gluten strength, rheological characteristics, and HMW-GS patterns using a LabChip system. Variance analysis identified genotypic variation. The landraces Azizi, Mahmoudi, Chili, and Arbi exhibited the highest protein concentrations and gluten contents, and best dough tenacity and extensibility values. The Mahmoudi and Chili varieties had the highest protein contents (17.06 and 17.32% dry mass, respectively). Arbi and Chili had the highest gluten contents (60.88 and 60.59%, respectively). Azizi, Mahmoudi, and Chili were characterized by higher dough tenacity, lower dough extensibility, and a greater alveograph configuration ratio P/L. The high molecular weight glutenin subunits 6+8 (Azizi and Mahmoudi) and 7+15 (Chili), coded by the Glu-B1 locus, improved gluten strength and viscoelastic dough properties. Calculated HMW to LMW-GS ratios were within a narrow range of 0.17–0.29. Some genotypes have potential to be used as parents in breeding programs. 相似文献
The problem of transient stability and voltage regulation for a single machine infinite bus (SMIB) system is addressed in this paper. An improved Backstepping design method for transient stability enhancement and voltage regulation of power systems is discussed beginning with the classical Backstepping to designing the nonlinear excitation control of synchronous generator. Then a more refined version of this technique will be suggested incorporating the sliding mode control to enhance voltage regulation and transient stability. The proposed method is based on a standard third-order model of a synchronous generator connected to the grid (SMIB system). It is basically implemented on the excitation side of the synchronous generator and compared to the classical Backstepping controller as well as the conventional controllers which are the automatic voltage regulator and the power system stabiliser. Simulation results prove the effectiveness of the proposed method which ameliorates to a great extent the transient stability compared to the other methods. 相似文献
Journal of Materials Science: Materials in Electronics - Pure and doped ZnO thin films with different monovalent elements (Li+, Na+, Ag+ and Cs+) are deposited onto glass substrates using a... 相似文献
Silicon - Silicon is one of the most used materials in semiconductors and electronic devices. Its miniaturization in two-dimensional (2D) scale is now a great challenge to improve and/or extend its... 相似文献
In this paper, we consider the problem of feedback stabilization for the distributed bilinear system y′(t)=Ay(t)+u(t)By(t). Here A is the infinitesimal generator of a linear C0 semigroup of contractions on a Hilbert space H and B:H→H is a linear bounded operator. A sufficient condition for feedback stabilization is given and explicit decay estimate is established. Applications to vibrating systems are presented. 相似文献