Synthesis, structure and fluorescence properties of a highly stable indium(III)-2,5-pyridinedicarboxylate coordination polymer

The hydrothermal reaction of 2,5-pyridinedicarboxylic acid (H₂PDC), diethylene triamine and In(NO₃)₃·4.5H₂O gave rise to a two-dimensional (2D) coordination polymer In(OH)(2,5-PDC). This compound crystallizes in the orthorhombic space group Iba2, with cell parameters, a = 12.656(3) Å, b = 20.114(4) Å, c = 6.2216(1) Å, V = 1583.9(5) Å³ and Z = 8. Its structure contains one-dimensional In–O–In–O– chains, which are further linked by 2,5-PDC ligands into a 2D supramolecular neutral framework. The adjacent 2D layers are parallel with each other and construct a three-dimensional framework via hydrogen bands. At room temperature, the compound exhibits intense photoluminescence. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to 390 °C.     

骨料含水状态对施工配合比的影响分析

本文针对混凝土骨料的不同的含水状态对施工配合比的影响进行了分析论证,得出骨料含水量与单位用水量之和在相等的前提下,骨料所处状态对混凝土强度几乎没有影响,但是对混凝土拌和物的和易性有一定的影响;指出施工配合比应根据现场骨料处于的风干状态给出,并提出在进行混凝土施工配合比设计时,骨料选用何种状态,在参考相关设计规程、规范的前提下,还要根据浇筑混凝土运输距离的远近及现场的实际施工条件而定。     

云龙水库大坝表面变形观测资料分析

1工程概况云龙水库是昆明市掌鸠河引水供水工程的水源工程,位于昆明市西北部禄劝县的云龙乡岔河村附近,距昆明市区约86km。大坝坝址选在金沙江水系二级支流掌鸠河上游峡谷河段内,初期规模正常蓄水位2087.97m,校核洪水位2091.98m;终期规模水库正常蓄水位2089.67m,设计洪水位2092.59m,校核洪水位2093.58m。初期规模总库容4.48亿m3,终期规模总库容4.84亿m3,属大(2)型水库工程,工程等别为Ⅱ。水库枢纽建筑物由大坝,泄洪、导流隧洞,引水隧洞,溢洪道等组成。除溢洪道按初期规模兴建外,其余枢纽建筑物均按终期规模兴建。泄洪、导流和引水建筑物布置…     

大坳水库混凝土面板堆石坝利用软岩筑坝设计

随着混凝土面板堆石坝技术的不断发展,因地制宜地应用坝址区附近的堆石料已成为筑坝时普遍需考虑的问题,对于这个用量大、整体性能要求较高、边界条件较复杂的材料,如设计和施工方案考虑不周,极易造成增加工程投资、延长施工期、对环境造成影响等。文章阐述了成功利用软岩筑坝技术取得较好经济效益的实例。     

SWRH82B冶炼过程中几个工艺问题的探讨

通过对天津钢铁有限公司在SWRH82B钢冶炼过程中工艺数据的整理分析,就转炉冶炼终点如何实现高碳低磷和优化工序操作提出一些改进措施。     

Teaching-Material Design Center: An ontology-based system for customizing reusable e-materials

Use of electronic teaching materials (e-material) to support teaching is a trend. e-Material design is therefore an important issue. Currently, most e-material providers offer a package of solutions for different purposes. However, not all teachers and learners need everything from a single package. A preferable alternative is to find useful material from different packages and combine them for a particular course. Currently, most educators collect the material manually, which is time-consuming and may result in missed material. In this paper, we describe a system – the Teaching-Material Design Center, which follows the standard of Sharable Content Object Reference Model – to separate e-material for use as teaching templates and learning objects and to label the material with use of semantic metadata for searching. This system can find existing teaching templates and learning objects for e-material designers and provide a convenient environment for constructing customized e-material for different requirements. We describe the implementation and evaluation of the proposed system for a course. Our system is efficient in finding teaching templates and learning objects and shortening the e-material development process.     

四川仪陇县:饮水安全助推新农村建设

地处大巴山区的仪陇县是朱德元帅和张思德同志的故乡，属于川陕革命老区。全县辖58个乡镇843个村，总人口中106万人，其中农业人口91万人。地处渠江与嘉陵江分水岭．境内无大江大河，降雨主要集中在7—9月，十年九旱，十旱九灾，是一个资源性缺水、工程性缺水与水质性缺水并重的地区。     

PDA导航踏勘系统简介

PDA导航踏勘系统是一套运行于Pocket PC型掌上电脑的导航踏勘软件.它将GPS定位功能与PDA的移动处理、移动显示、交互操作紧密结合,除了具备常规定位导航功能外,还针对野外踏勘工作特点开发底图测线上装、野外草图绘制、自动锁定最近点、特征点记录、轨迹回放显示等功能.文中详细地介绍这些功能.     

Influence of ZnO and P2O5 Content on Modified HZSM-5 on Aromatization of FCC Gasoline

Catalytic properties of different content of ZnO and P₂O₅ supported on HZSM-5 zeolites were studied in the conversion of FCC gasoline (75°C-120°C) into aromatic hydrocarbons with a temperature of 430°C, a liquid hourly space velocity of 1.0 hr^-1, and a pressure of 0.1 MPa. In the reaction, when the contents of ZnO and P₂O₅ are 2% and 4%, respectively, Zn-P/HZSM-5 showed the highest selectivity and activity to aromatic hydrocarbons and conversion of olefins. The content of aromatics in the liquid product and the yield of aromatics reached as high as 94.53%, 68.87%, and 51.74%, respectively.     

Ziegler-Natta烯烃聚合催化剂进展

综述了Ziegler-Natta催化剂在乙烯聚合和丙烯聚合方面的研究开发现状，重点介绍了采用新型二醚化合物作为内给电子体的丙烯聚合催化剂的进展。随着合成树脂向功能化方向发展，开发综合性能优越的新型催化剂及给电子体将是今后的研究方向。