加氢装置加热炉易爆管部位的分析

重点介绍韩国蔚山炼油厂分馏塔底重沸炉火灾事故、中国石油化工股份有限公司洛阳分公司催化裂化柴油加氢装置反应进料加热炉火灾事故、茂名分公司渣油加氢脱硫装置分馏炉火灾事故、镇海炼油化工股份有限公司加氢裂化装置脱丁烷塔底重沸炉火灾事故的情况,找出加氢装置加热炉的易爆管部位,并通过分析总结,提出了易爆管部位的选材原则、设计改进方案及维护措施.     

Myoglobin/gold nanoparticles/carbon spheres 3-D architecture for the fabrication of a novel biosensor

A novel biosensor based on a myoglobin/gold nanoparticles/carbon spheres (Mb-AuNPs-CNs) 3-D architecture bioconjunction has been fabricated for the determination of hydrogen peroxide (H₂O₂). Cyclic voltammetry (CV), Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM) were used to characterize the bioconjunction of the AuNPs-CNs with Mb. Experimental results demonstrate that the AuNPs-CNs hybrid material is more effective in facilitating electron transfer of the immobilized enzyme than CNs alone, which can be attributed to the unique nanostructure and larger surface area of the bioconjunction. The biosensor displayed good performance for the detection of H₂O₂ with a wide linear range from 0.28 μmol/L to 116.5 μmol/L and a detection limit of 0.12 μmol/L. The Michaelis-Menten constant K _M^app value was estimated to be 0.3 mmol/L. The resulting biosensor exhibited fast amperometric response, and good stability, reproducibility, and selectivity to H₂O₂. This article is published with open access at Springerlink.com     

人工水晶的压痕断裂行为及其 K_(1c)测量

藉助于声发射技术,研究了在 Vickers 钻石压头作用下人工水晶的压痕断裂行为。压头对角线与晶体试样的相对取向是,使得水晶Ⅰ和水晶Ⅱ的压痕诱发径向/中位断裂,分别沿着(10(?)0)/(1(?)10)和(11(?)0/(1(?)00)晶面对发展。压痕断裂过程中的声发射特征表明,除了随着压痕特征参数的发展所引起的准静态—声发射外,有三个相互独立的,与径向/中位裂纹的成核、径向/中位裂纹突入试样表面、以及裂纹分岔或侧向裂纹萌生等过程相关的声发射效应。以 Vickers 压痕技术测得 K_(c2)的结果与以一般力学法及 Knoop 压痕技术的测试结果作了比较。断裂韧性与晶体学取向的关系亦作了分析。实验表明,水晶Ⅰ和水晶Ⅱ具有相同的 K_(1c)值。其原因是,两种试样的径向/中位裂纹实际上沿着同样的{1100}/{1120}晶面对扩展。至于从缺口梁法或 Knoop 压痕技术得到的 K_(1c)值,由于水晶Ⅰ和水晶Ⅱ的主裂纹分别沿着(1(?)10)和(1(?)00)晶面扩展;它们的 K_(1c)值与断裂能随着晶体学取向而变有关,因而也就各不相同。     

热声系统内交变流动特性的数值模拟

对热声系统中交变流动的声场与流场分布进行了数值模拟,得到了热声谐振管和回热器(板叠)内的压力和速度分布及二者之间的相位关系.数值模拟表明:在谐振管内,在模拟的边界条件下,径向速度分布出现"环形效应",流动分为核心区的完全湍流流动和湍流边界层内的粘性流动;对于水力半径和粘性渗透层深度相当的热声板叠,其内速度分布逐步出现"环形效应",流动介于层流和湍流的过渡区,为过渡态流动,在流道的大部分区域压力和速度振荡的相位差趋向于π/2;对于水力半径和粘性渗透层深度之比较小的热声回热器,其内交变流动的流动特性与稳态流动的相似,速度的径向分布为抛物线形,类似于定常流动的层流速度分布.     

浙江省硫酸工业进展

介绍近6年来浙江省的硫酸产能和产量及下游耗酸产业结构.浙江省2005年硫酸产量占全国总产量的3%,预计2006年产量将达到1 600 kt.建议缓建硫酸装置,积极发展耗酸行业,控制进口酸量,加强企业间的协调,以使浙江省的硫酸市场在新的供需形势下建立起新的平衡.     

建龙化工新建150 kt/a硫磺制酸装置的几个特点

为保证原有4 500 kW发电机组满负荷运行的蒸汽供给及考虑当地硫酸市场的需求,新建一套150 kt/a硫磺制酸装置.该装置以原120 kt/a硫磺制酸装置的设计为蓝本,进行一定改进.在装置设备的选型配套、熔硫工序的挖潜改造、严冬季节土建施工、风机噪音消除等方面采取了相应措施.装置开车以来运行良好,达到设计要求.     

天基发射与载人登月初探

登月是载人航天向深空探测的延续，它与载人飞船工程相比，可靠性要求更高，工程规模更大，资金投入更多。结合国外登月历程和我国航天事业取得的重大成就，探讨了利用现有运载技术，分批次将登月飞船和航天员送入近地轨道，并在天基发射平台上进行组装发射，实现载人登月的设想；并就天基发射平台和天基发射方式进行了初步探讨。     

基于故障树的计算机安全性分析模型

提出了通过分析计算机系统的资源实体、访问者权限、安全需求和弱点等安全属性,按照不同的安全需求构造出安全故障树来直观地反映攻击者可能选取的攻击手段的安全状况评价方法;分析安全故障树,使用潜在攻击路径和系统安全失效概率从定性和定量两个方面表达计算机系统的安全状况,为系统的安全改进提供指导和建议。     

Truly Concomitant and Independently Expressed Short‐ and Long‐Term Plasticity in a Bi2O2Se‐Based Three‐Terminal Memristor

Concomitance of diverse synaptic plasticity across different timescales produces complex cognitive processes. To achieve comparable cognitive complexity in memristive neuromorphic systems, devices that are capable of emulating short‐term (STP) and long‐term plasticity (LTP) concomitantly are essential. In existing memristors, however, STP and LTP can only be induced selectively because of the inability to be decoupled using different loci and mechanisms. In this work, the first demonstration of truly concomitant STP and LTP is reported in a three‐terminal memristor that uses independent physical phenomena to represent each form of plasticity. The emerging layered material Bi₂O₂Se is used for memristors for the first time, opening up the prospects for ultrathin, high‐speed, and low‐power neuromorphic devices. The concerted action of STP and LTP allows full‐range modulation of the transient synaptic efficacy, from depression to facilitation, by stimulus frequency or intensity, providing a versatile device platform for neuromorphic function implementation. A heuristic recurrent neural circuitry model is developed to simulate the intricate “sleep–wake cycle autoregulation” process, in which the concomitance of STP and LTP is posited as a key factor in enabling this neural homeostasis. This work sheds new light on the development of generic memristor platforms for highly dynamic neuromorphic computing.