Numerical modelling of honeycomb core crush behaviour

In this work several numerical techniques for modelling the transverse crush behaviour of honeycomb core materials were developed and compared with test data on aluminium and Nomex™ honeycomb. The methods included a detailed honeycomb micromechanics model, a homogenised material model suitable for use in FE code solid elements, and a homogenised discrete/finite element model used in a semi-adaptive numerical coupling (SAC) technique. The micromechanics model is shown to be suitable for honeycomb design, since it may be used to compute crush energy absorption for different honeycomb cell sizes, cell wall thicknesses and cell materials. However, the very fine meshes required make it unsuitable for analysis of large sandwich structures. The homogenised FE model may be used for such structures, but gives poor agreement when failure is due to core crushing. The SAC model is shown to be most appropriate for use in structural simulations with extensive compression core crushing failures, since the discrete particles are able to model the material compaction during local crushing.     

What determines static friction and controls the transition to sliding?

We studied the shear response of a confined lubricant layer on approach of the transition to sliding with a surface force apparatus modified for oscillatory shear. In a given experiment, we found that the transition to sliding occurred always around the same deformation amplitude although the shear stress needed to initiate sliding varied up to a factor of two depending on sample history. This suggests the concept of deformation-controlled switching from rest to sliding. The elastic spring-constant, in the stick state, weakened with increasing deformation amplitude. This decrease can be described by a power law when plotted versus the distance to a critical deformation amplitude. The build-up of solid-like behavior after sliding stopped was also gradual and was consistent with a logarithmic time dependence. We suggest a model relating the gradual decrease of stiffness to weakening of the boundary layer, specifically to destruction of some elastic links between molecules or between molecules and the solid surfaces. Static friction (the force that must be overcome at the onset of kinetic motion) is proportional to the number of such links formed during the time of stick.     

Prediction of the pH and the temperature-dependent swelling behavior of -alginate hydrogels by artificial neural networks

This paper considers the possibility of using artificial neural network models to identify model for swelling behavior as new techniques. Multi-layer feed-forward, radial basis function and generalized regression neural network models were employed to predict the swelling behaviors of Ca²⁺-alginate hydrogels under different environmental conditions of pH and temperature. The results show that an excellent correlation between the experimental and predicted swelling ratios was obtained by the artificial neural networks. Generalized regression neural network has a better performance than the other neural network models. The absolute mean error, the determination coefficient and the standard error of prediction were used as performance criteria. In addition, the performances of the neural network models are significantly superior compared with those of second-order swelling kinetics, quadratic and cubic models of response surface methodology.     

Effects of Ultrasonic Vibration on the Electroinitiated Copolymerisation of Styrene and Isoprene

Copolymerisation of styrene and isoprene by constant potential electrolysis in dichloromethane was achieved at different polymerisation potentials. Effect of ultrasonic vibration on the rate and the yield of polymerisation has been discussed. The composition of the copolymers was found to be affected by the vibration as well as the polymerisation potential (E_pol). At E_pol=+3.30 V we found that r₁=r₂ and mole percents of isoprene and styrene in copolymer were equal to each other. Equality was also observed on reacted monomer concentrations, at that potential, which can be called critical polymerisation potential. At E_pol values above or below the critical polymerisation potential none of the above-mentioned properties were equal. Monomer reactivity ratios were determined by the integrated Lewis-Mayo equation. Ultrasonic vibration as well as polymerisation potential was found to affect reactivity ratios.     

Electroinitiated and radiation-induced polymerisation of epoxycyclohexane

Liquid-state radiation-induced and electroinitiated polymerisations of epoxycyclohexane (ECH) have been investigated. The effect of temperature on the electroinitiated polymerisation rate was also studied. The decrease in monomer concentration during polymerisation was followed by gas chromatographic analysis of electrolysis solutions. The i.r. spectra of the polymers suggested polyether structure. N.m.r. spectra of products indicate that the polymerisation of ECH propagates through the opening of the epoxy rings. Poly(epoxycyclohexane) obtained by both methods are amorphous according to X-ray analyses.     

Mode I fracture toughness determination with straight notched disk bending method

A new method called the straight notched disk bending method is developed for mode I fracture toughness determination using rock cores. Disk specimens of andesite and marble having a single straight edge notch were subjected to three-point bending loads. Dimensionless stress intensity factor estimations and fracture toughness tests were conducted for different notch lengths, span lengths, thicknesses and diameters of the cylindrical rock specimens. Stress intensity factors were computed by three-dimensional finite element modeling and the results were presented for a wide range of specimen geometrical parameters. Results of experiments were compared to the results of well-known mode I fracture toughness testing methods. For specimens having thickness equal to the radius, mode I fracture toughness was lower and close to the results obtained by semi-circular bending method. When thickness was increased and doubled, mode I fracture toughness increased and approached to the value found by the suggested cracked chevron notched Brazilian disk method. Advantages of the new method included easy specimen preparation and testing procedure, stiffer specimen geometry, smaller fracture process zone, and flexibility of the specimen geometry for the investigation of the size effect behavior.     

Characterization of products evolved from supercritical water gasification of xylose (principal sugar in hemicellulose)

The catalyst decomposition of xylose (the principal sugar in hemicellulose) was examined in supercritical water for temperature from 400 to 600°C. Experiments were performed in the absence and presence of three main types of catalysts [alkali catalysts (K₂CO₃ and KOH) and metal impregnated activated carbons (Ni/AC) and (Ru/AC)] with a reaction time of 1h. Gasification yield reaches maximum values by using K₂CO₃ and KOH at the highest temperature of 600°C. The highest H₂ yield and the highest CH₄ yield were obtained by using Ru/AC and Ni/AC, respectively. Acetic acid and 5-methyl furfural were determined as the main aqueous products and reached maximum value by using Ru/AC.     

Extraction of Bioactive Compounds from Milled Grape Canes (Vitis vinifera) Using a Pressurized Low-Polarity Water Extractor

Trans-resveratrol and trans-ε-viniferin were extracted from milled grape canes using pressurized low-polarity water. The effects of temperature were significant for both compounds (p ≤ 0.05): extraction at 160 °C resulted in a 40% loss of trans-resveratrol compared to 95 °C while reduction of trans-ε-viniferin at both temperatures remained at 30%. Increasing ethanol concentration from 0% to 25% increased the extraction of total phenolics and trans-ε-viniferin by 44% and 489%, respectively. Solvent flow rate also influenced trans-ε-viniferin extraction. Antioxidant activity showed a strong correlation with total phenolic content of the extracts, and the two target phenolic compounds. Except for the modifier concentration, the extraction parameters studied were not statistically significant with respect to the antioxidant activity of extracts (p > 0.05). Effective diffusivities of trans-resveratrol multiplied from 3.3 × 10⁻¹¹ to 10.4 × 10⁻¹¹ m²/s by three times with increasing temperature. The modified Gompertz equation satisfactorily explained the extraction of the stilbenes investigated.     

Photovoltaic system assessment for a school building

The installation of photovoltaic panels (PVs) on the roof of residential and commercial buildings is getting widespread as these areas stand normally idle and can be used for another purpose without losing an inhabited space. Considering the solar potential of Turkey, a significant amount of electricity generation is possible using current PV technology. For this reason, a two-story detached school building located in ?zmir, Turkey was taken into consideration and monthly as well as annual coverage ratio of an on-grid PV system for its entire energy requirement (including heating, cooling and lighting) was investigated. The PVs were installed on the south face of the school building roof. A heat pump, with a typical coefficient of performance (COP) value of 2.5, was used for supplying required cooling and heating. The heating, cooling and lighting loads were determined on a monthly basis. The average monthly electrical energy generation of the mounted PVs was calculated using a written code in Energy Equation Solver (EES) software. As a result, the monthly as well as yearly electrical energy demand coverage ratio values for the school using the installed PVs were revealed. Since the school building has a large south faced roof, the installation of PVs is very suitable to meet the cumulative electrical energy need of the heat pump and the lighting load. For Case 1, 180 PVs, which supply the entire yearly demand (with a 110% coverage ratio), were taken into consideration, while for Case 2, 265 PVs, which cover 75% of the roof area, were evaluated. The results showed that between November and March, PV electrical energy generation is not sufficient to meet all energy need of the school for both cases. However, significant coverage ratio values were observed for the rest of the year. In a yearly basis, the PV generation exceeded the building demand by 62% for the Case 2. This conclusion points out that the school can meet its yearly electricity need with the considered PV system and can even have an additional financial profit by selling its surplus PV electricity to the grid. Economic and environmental payback time values as well as simple payback time value were also computed for both investigated cases. The results pointed out a simple payback time of 7.9 years for Case 1 and 7.6 years for Case 2. Energy payback time was determined as 5 years for both systems. The greenhouse gas payback time of 2.7 years and 5.9 years was encountered for coal based and natural gas based calculations.