Dyeing cotton with reactive dyes under neutral conditions

This paper describes a new method to dye cotton with selected reactive dyes by long-liquor – or so-called 'exhaustion'– processes under neutral conditions. Particularly promising results were obtained with reactive dyes containing free vinyl sulphone residues. Although there are dyes on the market that contain free vinyl sulphone groups, for example, the Novacron C (Huntsman) range of dyes, many of this class contain 'blocked' vinyl sulphone residues; examples include sulphatoethylsulphone or chloroethylsulphone precursor groups, and these may be preactivated to the highly reactive vinyl sulphone form simply by a mild alkali treatment. After this activation, neutral, long-liquor dyeings can be carried out at the boil in the presence of electrolyte. This new dyeing method gave very good results in terms of overall fixation efficiency values, without the need for alkali additions.     

Aging characteristics of high-power lithium-ion cells with LiNi0.8Co0.15Al0.05O2 and Li4/3Ti5/3O4 electrodes

The impedance rise that results from the accelerated aging of high-power lithium-ion cells containing LiNi_0.8Co_0.15Al_0.05O₂-based positive and graphite-based negative electrodes is dominated by contributions from the positive electrode. Data from various diagnostic experiments have indicated that a general degradation of the ionic pathway, apparently caused by surface film formation on the oxide particles, produces the positive electrode interface rise. One mechanistic hypothesis postulates that these surface films are components of the negative electrode solid electrolyte interphase (SEI) layer that migrate through the electrolyte and separator and subsequently coat the positive electrode. This hypothesis is examined in this article by subjecting cells with LiNi_0.8Co_0.15Al_0.05O₂-based positive and Li_4/3Ti_5/3O₄-based negative electrodes to accelerated aging. The impedance rise in these cells was observed to be almost entirely from the positive electrode. Because reduction products are not expected on the 1.55 V Li_4/3Ti_5/3O₄ electrode, the positive electrode impedance cannot be attributed to the migration of SEI-type fragments from the negative electrode. It follows then that the impedance rise results from mechanisms that are “intrinsic” to the positive electrode.     

Specificity of Systemically Released Cotton Volatiles as Attractants for Specialist and Generalist Parasitic Wasps

Cotton plants under herbivore attack release volatile semiochemicals that attract natural enemies of the herbivores to the damaged plant. The volatiles released in response to herbivory are not only released from the damaged leaves but from the entire cotton plant. We found that cotton plants that released myrcene, (Z)-3-hexenyl acetate, (E)--ocimene, linalool, (E)-4,8-dimethyl-1,3,7-nonatriene, (E)--farnesene, and (E, E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene systemically from undamaged leaves of caterpillar damaged plants were attractive to the generalist parasitoid Cotesia marginiventris and the specialist parasitoid Microplitis croceipes. Plants from which the caterpillar damaged leaves were removed and that released those compounds systemically were significantly preferred over undamaged control plants in two-choice experiments in a flight tunnel. Artificially damaged cotton plants that released green leafy volatiles and constitutive terpenoids were less attractive for M. croceipes and C. marginiventris. Only C. marginiventris preferred artificially damaged plants over undamaged control plants, whereas M. croceipes showed no preference. The apparent lack of specificity of systemically released compounds in response to different herbivores feeding on the lower leaves is discussed.     

Correlations between electrical resistance-hydrogen pressure relationships of the Pd/Pt/H system and alterations of structure with changes of hydrogen content in the Pd/H system

For higher Pt content alloys of the Pd/Pt series of alloys, relationships at 25 °C between hydrogen content, n, and incremental changes of specific electrical resistance, Δρ, seem representable to a good approximation by a common curve, with a maximum of Δρ near n = 0.5 of similar form to ‘Nordheim’ types of relationship between resistivity and composition appropriate to substitutional alloys. An attempt has been made to assess whether phase-transition-related deviations from this symmetrical form of Δρ-n relationship in the cases of palladium itself and Pd/Pt alloys with lower Pt contents may provide useful guidance concerning the sequence of hydrogen occupation of interstitial sites in and β(′) phases (domains) of these systems.     

Introduction to the Special Issue on Usability and User Experience: Psychometrics

This special issue on usability and the user experience focuses on the application of psychometrics to the development and evaluation of standardized usability and user experience questionnaires. The six articles cover advances in the measurement of perceived usability (assessment of the instruments themselves and their application to measuring the perceived usability of mobile applications), attitude toward the Internet, need fulfillment, and the emotional consequences of interaction. Given the benefits of measurement standardization and the new research presented in this issue, the articles should be of interest to human–computer interaction researchers and practitioners.     

Psychometric Evaluation of the EMO and the SUS in the Context of a Large-Sample Unmoderated Usability Study

This article describes the psychometric properties of the Emotional Metric Outcomes (EMO) questionnaire and the System Usability Scale (SUS) using data collected as part of a large-sample unmoderated usability study (n = 471). The EMO is a concise multifactor standardized questionnaire that provides an assessment of transaction-driven personal and relationship emotional outcomes, both positive and negative. The SUS is a well-known standardized usability questionnaire designed to assess perceived usability. In previous research, psychometric evaluation using data from a series of online surveys showed that the EMO and its component scales had high reliability and concurrent validity with loyalty and overall experience metrics but did not find the expected four-factor structure. Previous structural analyses of the SUS have had mixed results. Analysis of the EMO data from the usability study revealed the expected four-factor structure. The factor structure of the SUS appeared to be driven by item tone. The estimated reliability of the SUS (.90) was consistent with previous estimates. The EMO and its subscales were also quite reliable, with the estimates of reliability for the various EMO scales ranging from .86 to .96. Regression analysis using SUS, EMO, and Effort as predictors revealed different key drivers for the outcome metrics of Satisfaction and Likelihood-to-Recommend. The key recommendations are to include the EMO as part of the battery of poststudy standardized questionnaires, along with the SUS (or similar questionnaire), but to be cautious in reporting SUS subscales such as Usable and Learnable.     

Reviewing VTAM and NetView Security Controls

Abstract

The basic premise of developing any information system is to increase efficiency and manage information in an improved manner. Based on the definitions above, an information system is “a group of devices or artificial objects serving a common purpose to communicate knowledge or intelligence.” Most information systems evolve from processes that either manipulate much information or rely on complex calculations. In other words, information systems are developed either to manage information or to manipulate it. Systems are meant to receive input, manipulate the input, and provide output.     

DB2 Universal Database: A Case Study of a Successful User-Centered Design Program

This case study describes the application of user-centered design (UCD) principles to the development of a complex middleware software product-IBM's DB2(r) Universal Database. Motivated by trade press reviews highlighting ease-of-use problems, a multisite development team utilized IBM UCD to transform ease of use into a featured product attribute. This case study describes the initial application of UCD to DB21 and the positive business results that followed: critical acclaim, increased marketshare and user satisfaction, and increased support and adoption of UCD across the IBM database product family. Although ease-of-use objectives, target markets, and human factors practitioners' roles have evolved over 6 years and multiple versions of the product, DB2 continues to achieve positive results with UCD. In addition to the flexibility of the UCD methodology, other factors that influenced DB2's success included management support, resource commitment, cross-site communication and collaboration, detailed product specifications, and a focus on supporting user tasks.