Concentrations and patterns of organochlorine pesticides and PCBs in Mediterranean monk seals (Monachus monachus) from Western Sahara and Greece

Blubber from Mediterranean monk seals (Monachus monachus) from the Western Sahara coast (Atlantic), sampled during 1996-1999, and from the Greek coast (Mediterranean), sampled during 1995-1999, was analyzed for organochlorine pollutants (OCs). In both populations, no significant difference was found between sexes. In the Atlantic population, mature females presented greater percentages of higher chlorinated PCB (polychlorinated biphenyl) congeners in relation to total PCBs (sum of 25 congeners) than pups, indicating a differential transfer of PCB congeners through lactation. In the Mediterranean, the reduced sample size of adult individuals precluded proper statistical investigation of age-related variation. Significant differences in concentrations and pollutant patterns were found between populations. Thus, Mediterranean individuals presented significantly higher levels of HCB (hexachlorobenzene), tPCB, and DDTs (dichlorodiphenyltrichloroethane) concentrations and DDE/tDDT and tDDT/tPCB ratios than their counterparts from the Atlantic. Moreover, the relative proportion of different congeners in relation to the total PCB load (congener/tPCB) was also different between the two areas. The 100*tDDT/tPCB ratio in Atlantic seals was 38.46, which indicates a predominance of industrial inputs over those associated with agriculture. Conversely, in the Mediterranean seal population, the 100*tDDT/tPCB ratio was 177.1, denoting a proportionally higher contribution of pollutants of agricultural origin.     

Evaluation of the antiradical and reducing properties of selected Greek white wines: correlation with polyphenolic composition

The total hydroxycinnamate (THC) and total flavanol (TF) contents were determined in 26 selected Greek white wines of ‘Appellation of Origin of High Quality’ using well‐established spectrophotometric methodology. Furthermore, two parameters related to the antioxidant capacity of wines, the antiradical activity (A_AR) and the reducing power (P_R), were also determined using the stable DPPH· radical and a ferric reducing power assay respectively. THC content varied from 64.4 to 197.1 mg l^?1 chlorogenic acid equivalents (CGAE), whereas TF content exhibited larger variation, ranging from 3.3 to 205.3 mg l^?1 catechin equivalents (CTE). A_AR and P_R were found to range from 0.47 to 0.60 mM Trolox equivalents (TRE) and from 0.32 to 2.05 mM quercetin equivalents (QE) respectively. Regression analysis at 95% significance level indicated that reducing effects are likely to be exerted by the flavanol fraction (SF < 0.05), as opposed to antiradical efficiency which is primarily affected by the sum of THC and TF contents (SF < 0.05), suggesting that synergistic phenomena account for the overall antioxidant status of white wines. © 2002 Society of Chemical Industry     

Studies on the usability of recycled PET for food packaging applications

The need of and opportunities for recycling of plastics for food packaging have been recognized, and a lot of work to find meaningful and cost-effective solutions to this issue is in progress. The safety of recycled plastics for food contact use is largely dictated by the ability of post-consumer contaminants to absorb into recycled materials and later diffuse from recycled plastics into the food. The objective of the present study was to establish a suitable analytical approach to identifying and quantifying any chemical substances that derive from the earlier use and remain in the polyethylene terephthalate (PET). A simple gas chromatographic technique using flame ionization detection was developed to allow quantification of solvent extractable compounds in a series of recycled PET samples. Identification of the nature and extent of contaminants in the PET samples was also attempted using GC/MS analysis.     

Numerical investigation of the oxy-fuel combustion in large scale boilers adopting the ECO-Scrub technology

The present paper presents a three-dimensional numerical investigation of a pulverized-fuel, tangentially-fired utility boiler located at Florina/Greece under air, partial and full oxy-fuel conditions. Heat and mass transfer and major species concentration, such as CO₂, CO and O₂ are calculated; whilst the results for the reference air case scenario studied are in good agreement with the corresponding operational data measured in the plant, both for combustion calculations and NO_x emissions. Results for the partial and full oxy-fuel operation scenarios are in line with similar experimental and numerical investigations found in the recent literature. This numerical investigation of oxy-fuel conditions scenarios prior to their implementation under real scale conditions demonstrates the utmost of its importance, since significant results regarding the operation of a boiler in terms of lignite particle trajectories and burning rates are attained. Furthermore, NO_x calculations have been performed for all the examined case studies.     

Barcode High Resolution Melting (Bar-HRM) analysis for detection and quantification of PDO “Fava Santorinis” (Lathyrus clymenum) adulterants

Legumes considered as one of the most important crops worldwide. Due to high price as a PDO product, commercial products of “Fava Santorinis” are often subjected to adulterations from other legume products coming from other Lathyrus or Vicia and Pisum species. Using plant DNA barcoding regions (trnL and rpoC) coupled with High Resolution Melting (Bar-HRM) we have developed a method allowing us to detect and authenticate PDO “Fava Santorinis”. Bar-HRM proved to be a very sensitive tool able to genotype Lathyrus and its closed relative species and to detect admixtures, being sensitive enough to as low as 1:100 of non-“Fava Santorinis” in “Fava Santorinis” commercial products. In conclusion, Bar-HRM analysis can be a faster, with higher resolution and cost effectiveness alternative method to authenticate PDO “Fava Santorinis” and to quantitatively detect adulterations in “Fava Santorinis” with other relative commercial “Fava” food products.     

Mesh deformation-based multi-tissue mesh generation for brain images

Multi-tissue meshing is necessary for the realistic building of a biomechanical model of the brain, which has been widely used in brain surgery simulation, brain shift, and non-rigid registration. A two step multi-tissue mesher is developed. First, a coarse multi-tissue mesh is generated by redistributing labels of a body-centered cubic (BCC) mesh. Second, all the surfaces of the submeshes are deformed to their corresponding tissue boundaries. To deform the mesh, two strategies are developed. One is based on a point-based registration (PBR) and the other is based on a robust point matching (RPM). The PBR method explicitly calculates the correspondence, which takes both smoothing and quality into account, then resolves the displacement vector by minimizing an energy function. Unlike PBR method, RPM does not require the correspondence between the source points and the target points to be known in advance. To simultaneously resolve the displacement vector and the correspondence, the Expectation and Maximization optimization is employed to alternately estimate the correspondence and the displacement vector. To effectively cope with outliers, least trimmed square, a robust regression technique, is employed to correct the regression bias induced by outliers. Both methods are effective in deforming the multi-tissue mesh. However, the PBR method favors quality and smoothing, and the RPM method favors fidelity. The resulting mesh is characterized by its flexible control of four mesh properties: (1) tissue-dependent resolution, (2) fidelity to tissue boundaries, (3) smoothness of mesh surfaces, and (4) element quality. Each mesh property can be controlled on a tissue level. Our experiments conducted on synthetic data, clinic MRI, visible human data, and brain atlas effectively demonstrate these features of this multi-tissue mesher.     

Comparing hybrid learning with traditional approaches on learning the Microsoft Office Power Point 2003 program in tertiary education

The purpose of this study was to determine the effectiveness of a hybrid learning approach to deliver a computer science course concerning the Microsoft office PowerPoint 2003 program in comparison to delivering the same course content in the form of traditional lectures. A hundred and seventy-two first year university students were randomly assigned into two teaching method groups: traditional lecture instruction (TLI) and hybrid lecture instruction (HLI). Each group received six 95-min periods of instruction divided into 4 sections: a) 5-min brief outline of the key learning points, b) 40-min lecture on general knowledge c) 45-min constructivist-inspired learning activities and d) 5-min summary on key learning points. In the beginning and the end of this study students completed a 17-item multiple choice knowledge test. Two-way analysis of variances (ANOVA), with repeated measures on the last factor, were conducted to determine effect of method groups (TLI, HLI) and measures (pre-test, post-test) on knowledge test. The measures main effect was significant, as well as the groups x measures interaction effect. Two independent-samples t test were conducted to follow up the significant interaction. Differences in mean ratings of knowledge performance between the two teaching groups were not significantly different at first measure, while the TLI method group yielded a significantly lower mean rating at second measure. The findings indicated that HLI approach might be a superior option for undergraduate students on learning the Microsoft office PowerPoint 2003 program.     

Room‐Temperature Phase Demixing in Bulk Heterojunction Layers of Solution‐Processed Organic Photodetectors: the Effect of Active Layer Ageing on the Device Electro‐optical Properties

Herein, we address the reduction in the external quantum efficiency (EQE) of solution‐processed organic photodetectors caused by the room temperature phase demixing of components in the composite material of the photoactive layer. The reduction takes place under ambient conditions and after the completion of device fabrication. As a model system, we study photoactive blend films that consist of the electron acceptor N,N’‐bis(alkyl)‐3,4,9,10‐perylene tetracarboxylic diimide) (PDI) and the electron donor polymer poly(9,9’‐dioctylfluorene‐co‐benzothiadiazole) (F8BT). The ambient ageing of these photo­active layers is a consequence of the PDI component segregation; however, the final PDI domain size remains smaller than the resolution limit of optical microscopy. We find that the photophysical properties of the aged F8BT:PDI layer and the EQE of the aged device are significantly altered. The fabrication of F8BT:PDI layers from solvents of increasing boiling point allows for the spectroscopic monitoring of the ageing‐induced phase segregation (a‐PSG) process. For each solvent used, the extent of a‐PSG is correlated with the PDI dispersion in the F8BT matrix as received immediately after layer deposition. The tendency for room temperature phase demixing becomes stronger as PDI is more finely dispersed in the freshly spun F8BT:PDI layer. The evolution of the room temperature phase segregation of PDI has a negative impact on the photophysical processes that are essential for charge photogeneration in the F8BT:PDI photoactive layer.