丙烯酸的现状与发展趋势

详细介绍了丙烯酸的制备方法，并简要地概括了它的性能和目前的生产和消费状况。最后，展望了今后丙烯酸的发展趋势。     

Structure and surface properties of a novel bulk-matte waterborne polyurethane coating composite

This paper reports on a novel self-matte or bulk-matte waterborne polyurethane coating composite with inherently extremely low gloss. The coating composite was comprised of a siloxane-containing waterborne polyurethane (SPU) resin and a crosslinked waterborne polyurethane (CPU) resin. The CPU resin was mainly responsible for fabricating the micro-rough surface of the film, which was achieved by a crosslinking reaction between the waterborne polyurethane and bisphenol A-type epoxy E-44 resin. The SPU resin was used to improve the comprehensive properties of the film, which was ascribed to the addition of silane coupling agent KH792. Compared with traditional matte coatings, this coating composite made it possible to avoid high loadings of matting agent and to arrive at highly flexible low-gloss finishes. Gloss levels of as low as a few tenths of a percent, even at high incidence angles, have been achieved with zero loading of extraneous dulling agent. The chemical structures of the SPU and CPU resins were characterized by FTIR-ATR and NMR spectra. The micro-rough topographies and surface rough degrees of the SPU, CPU and their 50%/50% composite films were measured by SEM and MSP, respectively. The particle sizes and particle morphologies of the SPU and CPU resins were imaged by TEM. Finally, the comprehensive properties of the SPU, CPU and their 50%/50% composite resins were evaluated, including the water contact angle, film transparency, tensile strength and storage stability.     

高清洁度铜管退火内吹扫工艺研究

退火是影响铜盘管内表面清洁度质量特性的关键工序之一,内吹扫是退火工序提高铜盘管清洁度的支配性工序要素。本文着重研究钟罩炉内吹扫(排气、冷吹和热吹)三种方式。结果证明,热吹是一种最佳的内吹扫方式。     

Synthesis of poly(1-methyl-1-phenyl-1-silapentane) by chemical reduction of poly)1-methyl-1-phenyl-1-sila-cis-pent-3-ene with diimide

Summary Poly(1-methyl-1-phenyl-1-silapentane) (I) has been prepared by the chemical reduction of the carbon-carbon double bonds of poly(1-methyl-1-phenyl-1-sila-cis-pent-3-ene (cis-II) with diimide, which was generatedin-situ by the thermal decomposition ofp-toluenesulfonhydrazide in refluxing toluene. At lower temperature (100°C),cis-II is isomerized byp-toluenesulfinic acid to lower molecular weight poly(1-methyl-1-phenyl-1-sila-cis andtrans-pent-3-ene) (cis/trans-II). Protodesilation of I with trifluoromethanesulfonic acid yields poly(1-methyl-1-trifluoromethanesulfonyl-1-silapentane) (III). The structures of I andcis/trans-II have been characterized by¹H,¹³C and²⁹Si NMR, GPC, TGA and elemental analysis. The structure of I has been characterized spectroscopically by¹H,¹³C,¹⁹F and²⁹Si NMR.     

AN INVESTIGATION OF QUASI-CLEAVAGE FRACTURE IN STEEL

本文试图探讨准解理断裂的本质。联系多晶材料的典型应力一应变曲线,对不同钢的断裂韧度试样的断口分析表明,准解理断裂可以看作是一种过渡的断裂机制。首先,一系列微观解理裂纹在高拉伸应力集中地方生核,然后这些裂纹各自沿着它本身已变形晶粒的解理面上扩展,最后借助于微观塑性聚合方式,这些微裂纹彼此连接。根据上述断裂模型可以认为:解理裂纹与塑性变形间的相互作用是准解理断裂的一种重要性质。借助于断口定量分析方法,有可能把断口形貌和一些力学参数间关系建立起来。     

锡膏固晶与铝片焊线工艺应用于功率及分立器件封装

对于许多单双芯片的MOSFET封装于像SC-70、SOT-2X、TO-252、SOP-8L、TSSOP-8L、QFN等形式的器件来说,标准的固晶工艺如:银浆、软焊料加上金丝、铝丝焊的工艺方法已不能同时满足连续的成本压缩要求和提升封装器件本身的性能。2年来,通过与当地著名的客户和设备供应商的合作,晶微科技有限公司已经开发出了一款新的高温锡膏快速固化机,用以实现这种锡膏固晶的工艺。这种工艺与银浆工艺相比在产品阻抗值及产品因热而导致阻抗漂移问题方面能够得到极好的结果;比起软焊料固晶工艺,在产能和设备应用效率上优越很多,这种新的工艺能带来了相当积极的影响。换言之,这种工艺能把固晶产量相应地提高60%～70%,以非常低的生产成本实现了多种多样的固晶封装形式。     

基于ADS1100高精度智能测力计

文中介绍基于串行A/D转换器ADS1100的新型高精度智能测力计的开发,阐述它的硬件结构和软件程序.该测力计将作用于传感器的力转换成电压值,经A/D转换后用单片机进行处理,其结果通过LCD显示,并具有超荷报警、电压欠压报警、掉电进入低功耗模式等功能.     

博士后简介

博士后简介陈树强陈树强男，１９６０年出生于福建省福州市．１９８２年毕业于厦门大学物理系，获理学学士学位；１９８２～１９８４年在化工部晨光化工研究院从事塑料测试技术研究；１９８７年在西北工业大学获工学硕士学位；１９８７～１９８９年在南昌航空工业学院任教...     

贮氢负极的电化学交流阻抗特性研究

通过试验测得金属氢化物电极的电化学交流阻抗谱（ＥＩＳ）,经过分析得到该电极的等效电路图。为了分析电极在不同状态下的阻抗及不同种类电极的阻抗,ＥＩＳ被用于其分析：（１）不同带电态的电极;（２）不同集流体电极;（３）不同化成态的电极。试验结果表明：（１）随放电深度的增加,电荷传递阻抗Ｒ７有先减小后增大的趋势,温伯格阻抗对应电导逐渐减小;对此进行了理论分析;（２）泡沫镍在电极中起到的集流作用不一定明显优于冲孔镍带,但可能由于镍的电催化作用,能减小电极反应的电子转移步骤阻抗;（３）以充放电方式的电化学化成主要是减小电荷转移阻抗,而对温伯格阻抗无明显影响。