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排序方式: 共有436条查询结果,搜索用时 265 毫秒
61.
Gheorghe Virgil Aldica Magdalena Lidia Ciurea Dorina Magdalena Chipara Ana Maria Lepadatu Karen Lozano Ionel Stavarache Stelian Popa Mircea Chipara 《应用聚合物科学杂志》2017,134(38)
Nanocomposites have been obtained by dispersing various amounts of vapor grown carbon nanofibers within isotactic polypropylene. Thermal investigations done by differential scanning calorimetry and dynamic mechanical analysis revealed the effect of the vapor grown carbon nanofibers on the melting, crystallization, α, and β relaxations. Direct current electrical features of these nanocomposites have been investigated and related to the thermal features of these nanocomposites. The effect of the loading with carbon nanofibers on the electrical properties of these nanocomposites is discussed within the percolation theory. The percolation threshold was estimated at about 5.5% wt carbon nanofibers. The temperature dependence of the direct current conductivity is analyzed in detail and it is concluded that the electronic hopping is the dominant transport mechanism. A transition from one‐dimensional hopping towards a three‐dimensional hopping was noticed as the concentration of carbon nanofibers was increased from 10% wt to 20% wt carbon nanofiber. The possibility of a differential negative resistivity is suggested. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45297. 相似文献
62.
Gold Nanoparticles and g‐C3N4‐Intercalated Graphene Oxide Membrane for Recyclable Surface Enhanced Raman Scattering
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Lulu Qu Na Wang Hui Xu Weipeng Wang Yang Liu Lidia Kuo T. P. Yadav Jingjie Wu Jarin Joyner Yanhua Song Haitao Li Jun Lou Robert Vajtai Pulickel M. Ajayan 《Advanced functional materials》2017,27(31)
Toxic organic pollutants in the aquatic environment cause severe threats to both humans and the global environment. Thus, the development of robust strategies for detection and removal of these organic pollutants is essential. For this purpose, a multifunctional and recyclable membrane by intercalating gold nanoparticles and graphitic carbon nitride into graphene oxide (GNPs/g‐C3N4/GO) is fabricated. The membranes exhibit not only superior surface enhanced Raman scattering (SERS) activity attributed to high preconcentration ability to analytes through π–π and electrostatic interactions, but also excellent catalytic activity due to the enhanced electron–hole separation efficiency. These outstanding properties allow the membrane to be used for highly sensitive detection of rhodamine 6G with a limit of detection of 5.0 × 10?14m and self‐cleaning by photocatalytic degradation of the adsorbed analytes into inorganic small molecules, thus achieving recyclable SERS application. Furthermore, the excellent SERS activity of the membrane is demonstrated by detection of 4‐chlorophenol at less than nanomolar level and no significant SERS or catalytic activity loss was observed when reusability is tested. These results suggest that the GNPs/g‐C3N4/GO membrane provides a new strategy for eliminating traditional, single‐use SERS substrates, and expands practical SERS application to simultaneous detection and removal of environmental pollutants. 相似文献
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Marcin Grniak Dariusz L. Szlachetko Natalia Oldrzyska Aleksandra M. Naczk Agata Mieszkowska Lidia Boss Marek S. Zitara 《International journal of molecular sciences》2021,22(21)
The phylogeny of the genus Paphiopedilum based on the plastome is consistent with morphological analysis. However, to date, none of the analyzed nuclear markers has confirmed this. Topology incongruence among the trees of different nuclear markers concerns entire sections of the subgenus Paphiopedilum. The low-copy nuclear protein-coding gene PHYC was obtained for 22 species representing all sections and subgenera of Paphiopedilum. The nuclear-based phylogeny is supported by morphological characteristics and plastid data analysis. We assumed that an incongruence in nuclear gene trees is caused by ancestral homoploid hybridization. We present a model for inferring the phylogeny of the species despite the incongruence of the different tree topologies. Our analysis, based on six low-copy nuclear genes, is congruent with plastome phylogeny and has been confirmed by phylogenetic network analysis. 相似文献
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Irene Rosa Eloisa Romano Bianca Saveria Fioretto Daniele Guasti Lidia Ibba-Manneschi Marco Matucci-Cerinic Mirko Manetti 《International journal of molecular sciences》2021,22(22)
Considerable evidence accumulated over the past decade supports that telocytes (TCs)/CD34+ stromal cells represent an exclusive type of interstitial cells identifiable by transmission electron microscopy (TEM) or immunohistochemistry in various organs of the human body, including the skin. By means of their characteristic cellular extensions (telopodes), dermal TCs are arranged in networks intermingled with a multitude of neighboring cells and, hence, they are thought to contribute to skin homeostasis through both intercellular contacts and releasing extracellular vesicles. In this context, fibrotic skin lesions from patients with systemic sclerosis (SSc, scleroderma) appear to be characterized by a disruption of the dermal network of TCs, which has been ascribed to either cell degenerative processes or possible transformation into profibrotic myofibroblasts. In the present study, we utilized the well-established mouse model of bleomycin-induced scleroderma to gain further insights into the TC alterations found in cutaneous fibrosis. CD34 immunofluorescence revealed a severe impairment in the dermal network of TCs/CD34+ stromal cells in bleomycin-treated mice. CD31/CD34 double immunofluorescence confirmed that CD31−/CD34+ TC counts were greatly reduced in the skin of bleomycin-treated mice compared with control mice. Ultrastructural signs of TC injury were detected in the skin of bleomycin-treated mice by TEM. The analyses of skin samples from mice treated with bleomycin for different times by either TEM or double immunostaining and immunoblotting for the CD34/α-SMA antigens collectively suggested that, although a few TCs may transition to α-SMA+ myofibroblasts in the early disease stage, most of these cells rather undergo degeneration, and then are lost. Taken together, our data demonstrate that TC changes in the skin of bleomycin-treated mice mimic very closely those observed in human SSc skin, which makes this experimental model a suitable tool to (i) unravel the pathological mechanisms underlying TC damage and (ii) clarify the possible contribution of the TC loss to the development/progression of dermal fibrosis. In perspective, these findings may have important implications in the field of skin regenerative medicine. 相似文献
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Two series of polyesters containing phenoxaphosphine rings and several halogens were synthesized by low-temperature solution polycondensation in the presence of triethylamine. One series, containing halogens only in the bisphenol moiety, was obtained from 2,8-dichloroformyl-10-phenylphenoxaphosphine-10-oxide and chlorinated bisphenol. In the second series, halogens belonged both to bisphenol and diacid dichlorides. For the last series, 2,8-dichloroformyl-10-(4-bromophenyl)phenoxaphosphine-10-oxide was prepared as a new monomer. All resulting polyesters were characterized by elemental analysis, reduced viscosity, IR and 1H NMR spectroscopy, and thermogravimetric analysis. These polymers began to lose weight at about 400°C in air being seen as self-extinguishing ones. 相似文献
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