Interfacial Energy in Phase-Separated Glasses from Emulsion Rheology

Classical theories of emulsion rheology yield information on the deformation of a liquid drop dispersed into another liquid matrix phase. By connecting the deformation and relaxation, respectively, and the capillary number of the dispersed phase, interfacial energy can be estimated. This was applied to demixing borosilicate and lead borate glasses, which are known to exhibit significant form anisotropy after elongation. Interfacial energies in these two systems were calculated based on graphical data of prior isothermal elongation experiments. The method is discussed in terms of experimental difficulties. It might provide an alternative way to overcome the obvious lack of information on interfacial energies in glasses.     

Gemini Surfactants Foam Formation Ability and Foam Stability Depends on Spacer Length

A series of cationic gemini surfactants containing different spacer length were synthesized and analyzed structurally. It was shown that the surface tension (σ) and critical micelle concentration (CMC), which had a maximum for the n-C₄H₈ spacer depended on the spacer length. The foaming ability and foam stability are high for the gemini surfactants with short spacers (C₂H₄ to n-C₄H₈), while longer spacers lead to a distinct decrease of these foam parameters. Foaming properties are discussed in terms of configuration and conformation of a surfactant molecule and in relation to micellization state kinetic.     

Dynamic Min-Max Problems

In this paper a method to check the solvability of a set of linear equations in the (max, min, +) algebra is described. Then, extensions to dynamic (or periodic) systems in the (max, min, +) algebra are provided. Further, some results regarding the uniqueness of solutions in both cases are given. Finally, we address a more general quasi periodic problem and provide an algorithm for its solution.     

Si-containing copolymer of 2,3-epoxypropyl-1-methacrylate

Summary Poly-p-trimethylsilylphenylmethacrylate(75)-co-glycidylmethacrylate (25) containing aromatic bisazides exhibits uv sensitivity as a negative type photoresist. Sensitometric data have been evaluated. The pressure-dependant reactivity under the conditions of oxygen reactive ion etching was determined.