Spin‐polarized charge transfer at the interface between a ferromagnetic (FM) metal and a molecule can lead to ferromagnetic coupling and to a high spin polarization at room temperature. The magnetic properties of these interfaces can not only alter those of the ferromagnet but can also stabilize molecular spin chains with interesting opportunities toward quantum computing. With the aim to enhance an organic spintronic device's functionality, external control over this spin polarization may thus be achieved by altering the ferromagnet/molecule interface's magnetic properties. To do so, the magnetoelectric properties of an underlying ferroelectric/ferromagnetic interface are utilized. Switching the ferroelectric polarization state of a PbZr0.2Ti0.8O3 (PZT) bottom layer within a PZT/Co/FePc‐based (Pc ‐ phthalocyanine) device alters the X‐ray magnetic circular dichroism of the Fe site within the phthalocyanine molecular top layer. Thus, how to electrically alter the magnetic properties of an interface with high spin polarization at room temperature is demonstrated. This expands electrical control over spin‐polarized FM/molecule interfaces, which is first demonstrated using ferroelectric molecules, to all molecular classes. 相似文献
This study is related to the use of hydroxyl functional acrylic cross‐linked polymer microparticles (CPM, also named microgels) as a chain transfer agent in cationic photopolymerization of cycloaliphatic epoxy monomer. All CPM were based on butyl acrylate and were consequently rubbery at ambient temperature. The effect of the stabilizing acrylate monomer used during the CPM synthesis was evaluated with respect to the viscoelastic properties of the photopolymerized cationic‐type epoxy films. The viscoelastic properties were correlated to the photopolymerized film morphology observed by transmission electron microscopy. Two acrylate monomers used as stabilizing agents during CPM synthesis were compared: cardura acrylate (CA) and lauryl acrylate (LA). CA was a good stabilizer for CPM in epoxy monomer before photocure and the CPM were well dispersed into the network after reaction. In contrast, LA was a poor stabilizer resulting in large CPM aggregation. The blend of these two types of CPM led to intermediate morphology, probably because of the flocculation of the CPM stabilized with LA. Conversely, CPM synthesized with a blend of the two stabilizing acrylate monomers induced in epoxy matrix a specific bi‐continuous morphology and consequently unique viscoelastic properties.
TEM micrographs of a photopolymerized film with 15 wt.‐% CPM(BA + 20%HEA)‐20%CA + 15% CPM(BA + 18%HEA)‐27%LA used as chain transfer agents. 相似文献
(Meth)acrylic cross‐linked polymer microparticles (CPM, also named microgels) were used as toughening agent for an epoxy/amine network. CPM were mainly based on butyl acrylate and consequently they were rubbery at ambient temperature. Various types of reactive groups were introduced onto the CPM: epoxy, carboxy (meth)acrylic double bonds, and epoxy + acrylic double bonds, carboxyl + methacrylic double bonds. Non functional microparticles were also used. Before any reaction, most of the CPM were soluble in the thermoset precursors. Nevertheless, the CPM functionality strongly influenced their initial miscibility in the epoxy‐amine monomers and their final dispersion in the cross‐linked matrix, as well as the mechanical properties of the network. Non‐functional CPM did not lead to a high increase of fracture toughness because of the low adhesion between microparticles and epoxy matrix. However, fracture toughness was increased with reactive CPM because of better adhesion between the microparticles and the matrix. The best toughness was obtained with microparticles containing two types of reactive groups, allowing at the same time cross‐linking reactions between CPM and chemical bonding between CPM and the epoxy matrix. In this case, fracture toughness can be greatly improved, up to 3‐times if the chemical composition of the microparticles was wisely chosen, without significantly reducing the thermal properties.
Viscoelastic properties of toughened DGEBA/MCDEA networks. 相似文献
Semi-supervised context characterized by the presence of a few pairs of constraints between learning samples is abundant in many real applications. Analysing these instance constraints by recent spectral scores has shown good performances for semi-supervised feature selection. The performance evaluation of these scores is generally based on classification accuracy and is performed in a ground truth context. However, this supervised context used by the evaluation step is inconsistent with the semi-supervised context in which the feature selection operates. In this paper, we propose a semi-supervised performance evaluation procedure, so that both feature selection and clustering steps take into account the constraints given by the user. In this way, the selection and the evaluation steps are performed in the same context which is close to real life applications. Extensive experiments on benchmark datasets are carried out in the last section. These experiments are performed using a supervised classical evaluation and the semi-supervised proposed one. They demonstrate the effectiveness of feature selection based on constraint analysis that uses both pairwise constraints and the information brought by the unlabeled data. 相似文献
Structured light methods achieve 3D modelling by observing with a camera system, a known pattern projected on the scene. The main drawback of single projection structured light methods is that moving the projector changes significatively the appearance of the scene at every acquisition time. Classical multi-view stereovision approaches based on the appearance matching are then not useable. The presented work is based on a two-cameras and one single slide projector system embedded in a hand-held device for industrial applications (reverse engineering, dimensional control, etc). We propose a method to achieve multi-view modelling for camera pose and surface reconstruction estimation in a joint process. The proposed method is based on the extension of a stereo-correlation criterion. Acquisitions are linked through a generalized expression of local homographies. The constraints brought by this formulation allow an accurate estimation of the modelling parameters for dense reconstruction of the scene and improve the result when dealing with detailed or sharp objects, compared to pairwise stereovision methods. 相似文献
Journal of Real-Time Image Processing - This paper focuses on the classification of color textures acquired by single-sensor color cameras under various illuminants. Local binary patterns (LBPs)... 相似文献