Separation and determination of mineral, animal and vegetable oils in water with the use of molecular sieve 5A

Mineral, animal and vegetable oils in water were separated and determined by the infrared method with the use of molecular sieve 5A (MS 5A). After being extracted by carbon tetrachloride, the extract were treated with MS 5A. Mineral oil was not adsorbed on MS 5A, but animal and vegetable oils were. Oils extracted with carbon tetrachloride were measured by the peak at 2950 cm⁻¹ due to the vibration of the CH groups.     

Radiocesium in muscle tissue of reindeer and pike from northern Sweden before and after the Chernobyl accident. A retrospective study on tissue samples from the Swedish Environmental Specimen Bank.

After the Chernobyl accident in April 1986, considerable deposition of radionuclides occurred regionally in eastern, central and northwestern Sweden. Locally, the fallout of radiocesium exceeded the remainder from atmospheric nuclear weapons tests by several magnitudes. Since the end of the 1960s samples of organs from various plant and animal species, annually collected at different localities, have been preserved in the Swedish Environmental Specimen Bank (ESB). In this work samples from the ESB have been used for retrospective studies of radioactive pollution. The activities of Cs-134 and Cs-137 in muscle tissues from reindeer, Rangifer tarandus, and pike, Esox lucius, preserved in the ESB, were measured. The samples were collected annually; the reindeer at three localities in northern Sweden and the pike at one of them. In material collected prior to the Chernobyl accident, the levels of Cs-137 were 57-180 Bq/kg in reindeer and 14-24 Bq/kg in pike, fresh weight basis. These levels relate to earlier nuclear bomb tests. A significant decrease was found in pike during the pre-Chernobyl period (1971-86). In post-Chernobyl samples the burden of Cs-137 varied from amounts equal to the former levels in the northernmost locality and up to 80 times higher for the maximum values in the southernmost locality. The highest value recorded was 18,425 Bq/kg in reindeer. The geographic variations in reindeer from Chernobyl fallout were in accordance with the pattern of deposition estimated by aircraft surveys performed in May 1986. The ratio between 'new' and 'old' radiocesium burdens in pike, caught in 1987, approached the corresponding ratio for reindeer grazing in the precipitation area of the lake; 33 and 19, respectively.     

Contribution à l'étude de la détermination des conditions de formation des haloformes

In recent years the presence of haloforms has been observed by some researchers in waters of various origins.The aim of this study is to determine the conditions in which chloroform is formed by chlorination of aqueous solutions of some organic compounds.The first part of this work was carried out by chlorination of synthetic basic solutions of acetone and thus enabled us to determine the reagent concentrations needed to obtain the maximum quantity of chloroform.We studied next the effect of chlorination on organic material solutions (humic acids and phenols), in the course of an oxidation treatment; the results obtained by chlorination of aqueous solutions of humic substances show that the quantity of chloroform produced passes through a maximum value which depends on the time of ozonisation. Similar results were obtained for the chlorination of phenol solutions during oxidation by the u.v. + H₂O₂ system. These results may be explained by the partial degradation of the molecules which leads in the formation of reactional intermediate precursors of the haloform reaction. We undertook at the same time the study of a rapid test allowing us to detect the presence of haloform reaction precursors in a certain sample of water.     

Oxygen transfer in a rotating disc treatment plant

In this paper experiments are described in a bio-disc pilot plant. A new method has been developed for a reproducible measurement of the thickness of the waterfilm on the rotating discs. The results were used to calculate the oxygen transfer coefficient into water (K_L). The values of K_L, calculated in this way, appeared to be considerably higher than experimental K_L-values, which is mainly due to the fact that the water layer on the rotating disc is outdistanced by the disc. This effect has not been taken into account in the literature so far.     

Settlements and deformations of industrial structure built on weak soils

Conclusions 1. In engineering-geologic explorations, it is necessary to investigate the engineering-geologic morphology to a depth of 15–18 m: lenses and interlayers of weak soils - unevenly compacted silty-sand fills, peat, slime, etc.2. Open unwatering of pits in the vicinity (10–15 m) of existing structures is impermissible, since it leads to removal of fine soil fractions because of piping, and to large and impermissible deformations of the load-bearing elements of the structures. In such cases, deep groundwater lowering by means of wellpoints should be used.In the case described in this article, the industrial structure underwent a mean settlement of about 20 cm, a tilt of 0.015, and a wall deflection of 0.002. By using deep groundwater lowering, such deformations could have been prevented.3. The development of settlements with time was due to the presence of weak soils - peat lenses and thin slime interlayers - in the foundation bed of the shop.4. An effective means for stopping the settlement of the industrial structure was the construction, under the walls, of two rows of cast-in-place piles with cantilever beams to which the wall loads were transmitted.Scientific-Research Institute of Foundations. GIPROLESKhIM. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 1, pp. 5–7, January–February, 1975.     

Treatment capability of a physical—Chemical package plant

A short-term study of a commercially-available physical—chemical waste treatment plant is reported. Results indicate that an excellent quality of effluent can be consistently obtained despite wide fluctuations of influent wastewater characteristics. Physical, chemical, and biological parameters were monitored. The short-term data obtained offer some evidence of superior treatment efficiency in terms of COD, color, turbidity, and phosphorus removals when compared to more conventional treatment methods.     

The uptake of heavy metals by epiphytic bacteria on Alisma plantago-aquatica

Bacterial epiphytes on the surface of the fresh-water plant Alisma plantago-aquatica collected from a polluted river were found to be a major factor in contributing to the total metal concentrations of the plant. The removal of epiphytes from the leaf surface resulted in significant reductions in the concentrations of Cr (reduced by 15–50%), Cu (30–35%), Fe, Pb, and Zn (10–50%). While numbers of epiphytes and concentrations of heavy metals increased in samples collected from polluted water compared with from unpolluted water, the fraction of metals held by the epiphytes appeared to remain similar for all samples.     

Orientation of smoke production in polyacrylonitrile

The introduction of ionic additives, such as KCN, or acidic comonomer units, such as methacrylic acid, which change the nature of the mechanism of nitrile oligomerization reaction from radical to ionic and cause its initiation at lower temperature, allows the level of obscurity and the total amount of smoke production, both in smouldering and flaming conditions to be decreased. An opposite result is obtained if diphenylpicrylhydrayl (DPPH) radicals in polyacrylonitrile is introduced; DPPH retards the initiation of the radical nitrile oligomerization reaction. The acrylonitrile-methacrylic acid copolymers have a limiting oxygen index, which increases with the methacrylic acid content. Owing to the increased amount of NH₃ produced during pyrolysis, the copolymers have a swelling behavior during the combustion test.     

Coagulation dynamics of fractal flocs induced by enmeshment and electrostatic patch mechanisms

The size and structure of flocs during floc formation were monitored for various coagulation mechanisms. Two distinctive mechanisms, namely, enmeshment and electrostatic patch, govern the dynamics of kaolin particles coagulation by polyaluminum chloride (PACl). They were investigated by small angle static light scattering (SASLS) and solid-state ²⁷Al NMR. In addition, a novel wet SEM (WSEM) was used in-situ to image the morphology of the aggregate in aqueous solution. Synthetic suspended particles were coagulated by two PACl products, a commercial product (PACl) and one laboratory product (PACl-E). The PACl-E contained more than 60% Al₁₃ while the PACl contained only 7% Al₁₃, with large percentage of colloidal Al. For coagulation by PACl at neutral pH and high dosage where the strong repulsion between particles occurs, the enmeshment ruled by reaction-limited aggregation (RLA) results in larger sweep flocs as well as higher fractal dimensional structure. For coagulation by PACl-E at alkaline pH and low dosage, the flocs were coagulated predominately by electrostatic patch with Al₁₃ aggregates. At such condition, it is likely that diffusion-limited aggregation (DLA) predominately rule PACl-E coagulation. The fractal dimension (D_s) values of PACl and PACl-E flocs formed at enmeshment and electrostatic patch increased with dosage, respectively. When breakage of flocs occurs, the breakage rate of PACl-E flocs is slower than that of sweep flocs. By WSEM imaging, the adsorption of spherical Al precipitates onto the particles was observed to form sweep flocs with a rough and ragged contour, while the PACl-E flocs were formed with a smooth and glossy structure.     

A large-scalein situ permeability test at Presenzano (Italy)

Bulletin of Engineering Geology and the Environment - Soil permeability had to be carefully determined in order to decide whether or not the whole lower reservior (750.000 m2) of the Presenzano...