The dependence of the width of void-denuded zones (VDZs) on grain boundary (GB) characters was investigated in Cu irradiated with He ions at elevated temperature. Dislocation loops and voids formed near GBs during irradiation were characterized by transmission electron microscopy, and GB misorientations and normal planes were determined by electron back-scatter diffraction. The VDZ widths at Σ3〈1 1 0〉 tilt GBs ranged from 0 to 24 nm and increased with the GB plane inclination angle. For non-Σ3 GBs, VDZ widths ranged from 40 to 70 nm and generally increased with misorientation angle. Nevertheless, there is considerable scatter about this general trend, indicating that the remaining crystallographic parameters also play a role in determining the sink efficiencies of these GBs. In addition, the VDZ widths at two sides of a GB show different values for certain asymmetrical GBs. Voids were also observed within GB planes and their density and radius also appeared to depend on GB character. We conclude that GB sink efficiencies depend on the overall GB character, including both misorientation and GB plane orientation. 相似文献
Prediction of stock index remains a challenging task of the financial time series prediction process. Random fluctuations in the stock index make it difficult to predict. Usually the time series prediction is based on the observations of past trend over a period of time. In general, the curve the time series data follows has a linear part and a non-linear part. Prediction of the linear part with past history is not a difficult task, but the prediction of non linear segments is difficult. Though different non-linear prediction models are in use, but their prediction accuracy does not improve beyond a certain level. It is observed that close enough data positions are more informative where as far away data positions mislead prediction of such non linear segments. Apart from the existing data positions, exploration of few more close enough data positions enhance the prediction accuracy of the non-linear segments significantly. In this study, an evolutionary virtual data position (EVDP) exploration method for financial time series is proposed. It uses multilayer perceptron and genetic algorithm to build this model. Performance of the proposed model is compared with three deterministic methods such as linear, Lagrange and Taylor interpolation as well as two stochastic methods such as Uniform and Gaussian method. Ten different stock indices from across the globe are used for this experiment and it is observed that in majority of the cases performance of the proposed EVDP exploration method is better. Some stylized facts exhibited by the financial time series are also documented.
Soy meal-based biodegradable blends were prepared by melt extrusion process. The effects of denaturants, i.e., urea and sodium
sulfite and plasticizer (glycerol) and polyester type (polybutylene succinate, polycaprolactone, polybutylene adipate terephthalate)
on tensile strength and elongation at break were investigated using a Taguchi experimental design approach. The results showed
that the sodium sulfite had little or no effect on final properties of the blends. Also, biodegradable polyester type had
significant effect on the tensile strength and elongation at break of the blends prepared. The predicted values and experimental
were found to be in tune with each other. The chemical structure and morphology of the optimum sample was probed by FT-IR
spectroscopy and scanning electron microscopy (SEM). Also, the results provided an insight into how important the plasticization
and destructurization of soy protein to obtain the blends with desired mechanical properties. 相似文献
Effect of ultrasound pretreatment on yield and functional properties of taro starch was investigated. A three-factor two-level factorial design was employed with treatment time (5 and 10 min), treatment cycle (0.5 and 1), and amplitude of ultrasound (50 and 100 %). Starch yield from ultrasonic treatment varied from 17.45 to 18.97 % compared to 15.29 % in conventional method. The highest yield of 18.97 % was obtained with treatment time 10 min, treatment cycle 0.5, and amplitude 50 %. A significant increase in swelling, solubility, pasting, and texture properties of the ultrasonically extracted starch was observed. A slight decrease in clarity of the starch pastes was also observed after ultrasonic pretreatment, but the differences were not much significant. Freeze-thaw stability of the ultrasonically extracted starches was found to be better compared to starch extracted using conventional method, making them suitable for foods subjected to refrigeration. The whiteness of the ultrasonically extracted starch powders was lower compared to conventionally extracted starch, but the differences were not statistically significant. 相似文献
Advanced hybrid biocomposites are engineered from nylon 6, waste wood biosourced carbon (biocarbon) with a low content of synthetic fiber for lightweight auto-parts uses. The novel engineering process through direct injection molding of only 2 wt% synthetic fibers in the form of masterbatch with 20 wt% biocarbon, results outstanding performance of the resulting nylon biocomposites. Such uniquely developed biocomposites show tensile strength of 105 MPa and tensile modulus of 5.14 GPa with a remarkable heat deflection temperature (HDT) of 206 °C. The direct injection molding of synthetic fiber retains the length ≈3 times higher as compared to traditional extrusion and injection molding; resulting greater degree of entanglement and composite reinforcement effectiveness in the hybrid biocomposites. Highly dimensionally stable nylon 6 biocomposites with a very low coefficient of linear thermal expansion results through reinforcing ability of the sustainable biocarbon and small amount of synthetic fiber. 相似文献
A new chalcone derivative, 1-(4-aminophenyl)-3-(3,4-dimethoxyphenyl)-prop-2-en-1-one (DMAC) was synthesized and single crystals were grown by slow evaporation technique. The FT-Raman and FT-IR spectra of the sample were recorded in the region 3700–100 cm−1 and 4000–400 cm−1, respectively. The spectra were interpreted with the aid of normal coordinate analysis following structure optimizations and force field calculations based on density functional theory (DFT) at the B3LYP/6-311+G(d,p) level of theory. Normal coordinate calculations were performed using the DFT force field, corrected by a recommended set of scaling factors, yielding fairly good agreement between the observed and calculated wavenumbers. DMAC is thermally stable up to 220.0 °C and optically transparent in the visible region. Information about the size, shape, charge density distribution and site of chemical reactivity of the molecule has been obtained by mapping electron density isosurface with electrostatic potential surfaces (ESP). The SHG efficiency of DMAC is observed to be 10 times that of standard urea crystal of identical particle size. 相似文献
Carbon nanotube (CNT) reinforced nanostructured Cu matrix composite with a grain size less than 25 nm has been successfully fabricated via a combination of ball milling and high-pressure torsion. CNTs were found to be homogeneously dispersed into the metal matrix, leading to grain refinement with a narrow grain size distribution and significant increase in hardness. 相似文献