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21.
O. Auciello S. Saha D.Y. Kaufman S.K. Streiffer W. Fan B. Kabius J. Im P. Baumann 《Journal of Electroceramics》2004,12(1-2):119-131
Thin films of Ba1?x Sr x Ti1+y O3+z (BST), were fabricated using both by RF-magnetron sputtering and MOCVD to demonstrate application to high frequency devices. Precise control of composition and microstructure is critical for the production of (Ba x Sr1?x )Ti1+y O3+z (BST) dielectric thin films with the large dependence of permittivity on electric field, low losses, and high electrical breakdown fields that are required for successful integration of BST into tunable high frequency devices. Here we review results on composition-microstructure-electrical property relationships of polycrystalline BST films produced by magnetron sputter deposition that are appropriate for microwave devices such as phase shifters. BST films with a multilayer structure were also developed with different Ti-elemental ratio in each layer to minimize losses and leakage current. Interfacial contamination from C and H species was studied and implications on electrical properties are highlighted. Finally, York's group at the University of California-Santa Barbara successfully integrated our BST films onto phase shifter arrays. The results show potential of BST films in such applications. Results from initial work on the integration of Cu-electrodes with BST films are also presented. 相似文献
22.
23.
Young?Tae?Im Seung?Tae?ChoiEmail author Tae?Sang?Park Jae?Hyun?Kim 《Journal of Mechanical Science and Technology》2004,18(1):12-19
Using LSM (laser scanning method), the radius of curvature due to thermal deformation in polyimide film coated on Si substrate
is measured. Since the polyimide film shows viscoelastic behavior, i.e., the modulus and deformation of the film vary with
time and temperature, we estimate the relaxation modulus and the residual stresses of the polyimide film by measuring the
radius of curvature and subsequently by performing viscoelastic analysis. The residual stresses relax by an amount of 10%
at 100°C and 20% at 150°C for two hours. 相似文献
24.
Kapp N Kreyling W Schulz H Im Hof V Gehr P Semmler M Geiser M 《Microscopy research and technique》2004,63(5):298-305
Epidemiologic studies have associated cardiovascular morbidity and mortality with ambient particulate air pollution. Particles smaller than 100 nm in diameter (ultrafine particles) are present in the urban atmosphere in very high numbers yet at very low mass concentration. Organs beyond the lungs are considered as targets for inhaled ultrafine particles, whereby the route of particle translocation deeper into the lungs is unclear. Five rats were exposed to aerosols of ultrafine titanium dioxide particles of a count median diameter of 22 nm (geometric standard deviation, GSD 1.7) for 1 hour. The lungs were fixed by intravascular perfusion of fixatives immediately thereafter. TiO(2) particles in probes of the aerosol as well as in systematic tissue samples were analyzed with a LEO 912 transmission electron microscope equipped with an energy filter for elemental microanalysis. The characteristic energy loss spectra were obtained by fast spectrum acquisition. Aerosol particles as well as those in the lung tissue were unambiguously identified by electron energy loss spectroscopy. Particles were mainly found as small clusters with a rounded shape. Seven percent of the particles in the lung tissue had a needle-like shape. The size distribution of the cluster profiles in the tissue had a count median diameter of 29 nm (GSD 1.7), which indicates no severe clustering or reshaping of the originally inhaled particles. Electron energy loss spectroscopy and related analytical methods were found to be suitable to identify and localize ultrafine titanium dioxide particles within chemically fixed and resin-embedded lung tissue. 相似文献
25.
Jumi Yun Dae Hoon Lee Ji Sun Im Hyung-Il Kim 《Materials science & engineering. C, Materials for biological applications》2012,32(6):1564-1570
Transdermal drug delivery system (TDDS) was prepared with temperature-responsive hydrogel. The graphite was oxidized and incorporated into hydrogel matrix to improve the thermal response of hydrogel. The micro heater was fabricated to control the temperature precisely by adopting a joule heating method. The drug in hydrogel was delivered through a hairless mouse skin by controlling temperature. The efficiency of drug delivery was improved obviously by incorporation of graphite oxide due to the excellent thermal conductivity and the increased interfacial affinity between graphite oxide and hydrogel matrix. The fabricated micro heater was effective in controlling the temperature over lower critical solution temperature of hydrogel precisely with a small voltage less than 1 V. The cell viability test on graphite oxide composite hydrogel showed enough safety for using as a transdermal drug delivery patch. The performance of TDDS could be improved noticeably based on temperature-responsive hydrogel, thermally conductive graphite oxide, and efficient micro heater. 相似文献
26.
Homogeneous 2D MoTe2 p–n Junctions and CMOS Inverters formed by Atomic‐Layer‐Deposition‐Induced Doping 下载免费PDF全文
June Yeong Lim Atiye Pezeshki Sehoon Oh Jin Sung Kim Young Tack Lee Sanghyuck Yu Do Kyung Hwang Gwan‐Hyoung Lee Hyoung Joon Choi Seongil Im 《Advanced materials (Deerfield Beach, Fla.)》2017,29(30)
Recently, α‐MoTe2, a 2D transition‐metal dichalcogenide (TMD), has shown outstanding properties, aiming at future electronic devices. Such TMD structures without surface dangling bonds make the 2D α‐MoTe2 a more favorable candidate than conventional 3D Si on the scale of a few nanometers. The bandgap of thin α‐MoTe2 appears close to that of Si and is quite smaller than those of other typical TMD semiconductors. Even though there have been a few attempts to control the charge‐carrier polarity of MoTe2, functional devices such as p–n junction or complementary metal–oxide–semiconductor (CMOS) inverters have not been reported. Here, we demonstrate a 2D CMOS inverter and p–n junction diode in a single α‐MoTe2 nanosheet by a straightforward selective doping technique. In a single α‐MoTe2 flake, an initially p‐doped channel is selectively converted to an n‐doped region with high electron mobility of 18 cm2 V?1 s?1 by atomic‐layer‐deposition‐induced H‐doping. The ultrathin CMOS inverter exhibits a high DC voltage gain of 29, an AC gain of 18 at 1 kHz, and a low static power consumption of a few nanowatts. The results show a great potential of α‐MoTe2 for future electronic devices based on 2D semiconducting materials. 相似文献
27.
Im Deok Jung Min Kook Cho Kong Myeong Bae Sang Min Lee Phill Gu Jung Ho Kyung Kim Sung Sik Kim Jong Soo Ko 《ETRI Journal》2008,30(5):747-749
We introduce a pixel‐structured scintillator realized on a flexible polymeric substrate and demonstrate its feasibility as an X‐ray converter when it is coupled to photosensitive elements. The sample was prepared by filling Gd2O2S:Tb scintillation material into a square‐pore‐shape cavity array fabricated with polyethylene. For comparison, a sample with the conventional continuous geometry was also prepared. Although the pixelated geometry showed X‐ray sensitivity of about 58% compared with the conventional geometry, the resolving power was improved by about 70% above a spatial frequency of 3 mm?1. The spatial frequency at 10% of the modulation‐transfer function was about 6 mm?1. 相似文献
28.
Thin‐Film Transistors: Synthesis of Ultrathin,Homogeneous Copolymer Dielectrics to Control the Threshold Voltage of Organic Thin‐Film Transistors (Adv. Funct. Mater. 36/2016) 下载免费PDF全文
Kwanyong Pak Hyejeong Seong Junhwan Choi Wan Sik Hwang Sung Gap Im 《Advanced functional materials》2016,26(36):6672-6672
29.
Yonghyun Kim Huiwen Liu Yi Liu Boa Jin Hao Zhang Wenjing Tian Chan Im 《Frontiers of Chemical Science and Engineering》2021,15(1):187-197
Cesium lead halide perovskite(CsPbX3,X=Cl,Br,I)quantum dots(QDs)and their partly Mn2+-substituted QDs(CsPb1–xMnxX3)attract considerable attention owing to their unique photoluminescence(PL)efficiencies.The two types of QDs,having different PL decay dynamics,needed to be further investigated in a form of aggregates to understand their solid-state-induced exciton dynamics in conjunction with their behaviors upon degradation to achieve practical applications of those promising QDs.However,thus far,these QDs have not been sufficiently investigated to obtain deep insights related to the long-term stability of their PL properties as aggregated solid-states.Therefore,in this study,we comparatively examined CsPbX3-and CsPb1–xMnxX3-type QDs stocked for>50 d under dark ambient conditions by using excitation wavelength-dependent PL quantum yield and time-resolved PL spectroscopy.These investigations were performed with powder samples in addition to solutions to determine the influence of the inter-QD interaction of the aged QD aggregates on their radiative decays.It turns out that the Mn2+-substituted QDs exhibited long-lasting PL quantum efficiencies,while the unsubstituted CsPbX3-type QDs exhibited a drastic reduction of their PL efficiencies.And the obtained PL traces were clearly sensitive to the sample status.This is discussed with the possible interaction depending on the size and distance of the QD aggregates. 相似文献
30.
In Ho Kim Hye Sik Kong Bo Im Choi Young Soo Kim Hee Jung Kim Young Wook Yang 《Drug development and industrial pharmacy》2013,39(3):389-397
ABSTRACTWe synthesized dexamethasone 21-sulfate sodium (DS) as a colon-specific prodrug of dexamethasone and investigated its properties. Introduction of a sulfate group to dexamethasone lowered the apparent partition coefficient from 52.5 to 0.27 in 1-octanol/pH 6.8 phosphate buffer at 37°C. DS was stable on incubation with buffer solutions of varied pH or with the upper intestinal contents of rats at 37°C for 24 h. On incubation with the cecal contents, DS was hydrolyzed by producing dexamethasone over 80% of the dose at 10 h. When DS was incubated with the cecal contents collected from trinitrobenzenesulfonic acid (TNBS)-induced colitic rats, the degree of prodrug hydrolysis and production of dexamethasone amounted to 70% of healthy rats. In comparison with prednisolone, hydrocortisone, and cortisone, dexamethasone was stable against bioinactivation by the cecal contents, a desirable property for the development of a colon-specific prodrug. These results demonstrated that DS might be delivered specifically to the colon as an intact form to produce dexamethasone in high yield, suggesting DS as a potential colon-specific prodrug of dexamethasone. 相似文献