全文获取类型
收费全文 | 932篇 |
免费 | 48篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 16篇 |
综合类 | 3篇 |
化学工业 | 199篇 |
金属工艺 | 18篇 |
机械仪表 | 52篇 |
建筑科学 | 22篇 |
矿业工程 | 1篇 |
能源动力 | 27篇 |
轻工业 | 65篇 |
水利工程 | 3篇 |
石油天然气 | 1篇 |
无线电 | 89篇 |
一般工业技术 | 250篇 |
冶金工业 | 65篇 |
原子能技术 | 6篇 |
自动化技术 | 165篇 |
出版年
2023年 | 19篇 |
2022年 | 32篇 |
2021年 | 25篇 |
2020年 | 26篇 |
2019年 | 24篇 |
2018年 | 35篇 |
2017年 | 49篇 |
2016年 | 53篇 |
2015年 | 33篇 |
2014年 | 45篇 |
2013年 | 66篇 |
2012年 | 45篇 |
2011年 | 61篇 |
2010年 | 28篇 |
2009年 | 37篇 |
2008年 | 39篇 |
2007年 | 33篇 |
2006年 | 20篇 |
2005年 | 17篇 |
2004年 | 16篇 |
2003年 | 23篇 |
2002年 | 14篇 |
2001年 | 22篇 |
2000年 | 16篇 |
1999年 | 10篇 |
1998年 | 25篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 4篇 |
1994年 | 14篇 |
1993年 | 12篇 |
1992年 | 10篇 |
1991年 | 12篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1984年 | 4篇 |
1982年 | 9篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1965年 | 7篇 |
1964年 | 2篇 |
1963年 | 2篇 |
1962年 | 2篇 |
排序方式: 共有982条查询结果,搜索用时 27 毫秒
41.
J. Sivasankari S. Sankar S. Selvakumar L. Vimaladevi R. Krithiga 《Materials Chemistry and Physics》2014
Pure zinc oxide (ZnO) and 2 mol% of Er, 1 mol% of Li individually doped and Er + Li co-doped ZnO nanopowders were synthesized by auto-combustion method. Crystal structure and grain size were characterized by X-ray diffractometer and found that all synthesized samples have hexagonal wurtzite crystal structure. Scanning electron microscope (SEM) and Transmission electron microscope (TEM) studies were used to determine the morphology and size of the nanocrystallites. A UV–VIS measurement shows four absorbance peaks in the visible regions and the band gap is slowly blue shifted after annealing at 800 °C. The presence of Er, Li and the hexagonal wurtzite structure was confirmed by FT-IR studies. FT-Raman spectroscopy has been employed to study the crystalline quality and structural disorders. 相似文献
42.
43.
M. Sankar R. G. Baligidad Shivkumar Khaple V. V. Satya Prasad V. V. Bhanu Prasad 《Transactions of the Indian Institute of Metals》2012,65(5):467-472
Niobium consumable electrodes of 10?mm dia?×?50?mm length were prepared by cold isostaic pressing with compaction pressure of 125?C250?MPa. The compacts were sintered under vacuum at different temperatures in the range of 1000?C1800?oC. The CIPed and sintered electrodes were characterized with respect to chemical analysis, density, microstructure and bend strength. The results showed that there is a marginal improvement in density at a sintering temperature in the range of 1000?C1400?oC, while a significant improvement in density was observed at sintering temperature in the range of 1600?C1800?oC. The bend strength of sintered electrode was found to increase with increasing sintering temperature and that attains a highest value at a sintering temperature in the range of 1600?C1800?oC. Sintering at a temperature higher than 1400?oC leads to decrease in oxygen content of the electrodes. The oxygen content was decreased from 2000 to 500?ppm when electrode was sintered at 1800?oC. 相似文献
44.
S.C.G. Kiruba Daniel B. Nazeema Banu M. Harshiny K. Nehru P. Sankar Ganesh S. Kumaran 《Journal of Experimental Nanoscience》2014,9(2):197-209
The biosynthesis of silver nanoparticles (AgNps) has a wide range of applications, and here we develop a rapid synthesis using the leaf extract of Ipomea carnea. We demonstrated that 100?mL of a 1?mM silver nitrate solution was reduced to AgNps by 500?µL of I. carnea extract in 5?min and that one or more of the chemical constituents present in the extract acted as the reducing agent. Surface plasmon resonance peaks were observed from 410 to 440?nm for AgNps synthesised using the plant extract, and the peaks showed a characteristic blue shift with variation of pH from 2 to 8. Particle size analysis revealed the size of the AgNps to be from 30 to 130?nm, which was also confirmed by dynamic light scattering, atomic force microscopy and transmission electron microscopy. Additionally, the antibacterial effects of the AgNps were evaluated against selected human pathogens such as Staphylococcus aureus, Bacillus cereus, Bacillus subtilis, Klebsiella pneumoniae, Aeromonas hydrophila, Salmonella typhi, Proteus vulgaris and Pseudomonas aeruginosa. Finally, the AgNps were impregnated with a cellulose acetate membrane to form an antimycobacterial membrane. Antimycobacterial activity against a non-pathogenic Mycobacterium smegmatis showed that the AgNp-embedded membrane system has a zone of inhibition of 14?mm. 相似文献
45.
The encapsulation of 1,8-naphthalic anhydride (NAN), 9-dicyanomethylenefluorene (9-DCF), acenaphthenequinone (ANQ), and 4-chloro-7-nitrobenzofurazan (NBD-Cl) by diethylpyrrole-bridged bisporphyrin (H4DEP) and its dizinc(II) analogue (Zn2DEP) are employed to investigate the structural and spectroscopic changes within the bisporphyrin cavity upon substrate binding. Synthesis and X-ray structures of all four encapsulated host-guest complexes (H4DEP⋅NAN, H4DEP⋅9-DCF, Zn2DEP⋅ANQ, and Zn2DEP⋅NBD-Cl) are reported here. The binding constant calculations show strong 1 : 1 binding between the hosts (H4DEP and Zn2DEP) and the guests (NAN/9-DCF/ANQ/NBD-Cl). 1H-NMR spectra also support the retention of the host-guest assemblies in solution. Negative and positive shifts of the reduction and oxidation potentials, respectively, indicate that it is difficult to reduce/oxidize the encapsulated complexes. The emission intensities of the bisporphyrins (H4DEP and Zn2DEP) are substantially quenched in all the complexes, owing to photoinduced electron transfer from the excited state of the bisporphyrins to guest molecules. All the experimental evidence is further substantiated by DFT calculations. Such an efficient electron transfer is only possible when the donor and the acceptor moieties are in close propinquity to each other, which eventually lowers the reorganization energy. 相似文献
46.
G. M. Karthik P. Mastanaiah G. D. Janaki Ram Ravi Sankar Kottada 《Metallurgical and Materials Transactions B》2017,48(3):1416-1422
This work offers a fresh perspective on buttering, a technique often considered for fusion welding of dissimilar metals. For the first time, buttering was attempted in solid state using friction deposition. Using this new “friction buttering” technique, fusion welding of two different dissimilar metal pairs (austenitic stainless steel/borated stainless steel and Al-Cu-Mg/Al-Zn-Mg-Cu) was successfully demonstrated. The results show that friction buttering can simplify a tough dissimilar welding problem into a routine fusion welding task. 相似文献
47.
Arup Jyoti Das Prerna Khawas Tatsuro Miyaji Sankar Chandra Deka 《International Journal of Food Properties》2016,19(9):2087-2101
Phytochemicals content and antimicrobial activity of Artocarpus heterophyllus, Cyclosorus extensa, Oldendia corymbosa, and Alpinia malaccensis were investigated. Maximum alkaloids and terpenoids were found in A. heterophyllus; tannins and saponins in C. extensa; flavonoids, polyphenols, and phytosterols in O. corymbosa and anthraquinone, glycosides, and anthocyaninin A. malaccensis. Aqueous, methanolic, ethyl acetate, and hexane extracts were prepared from all the leaves. Attenuated total reflectance Fourier transform infrared spectrophotometric (ATR-FTIR) analysis revealed that alkanes and alkyl halides were prevalent in all the extracts and the ethyl acetate extracts contained comparatively higher number of functional groups, which were also more effective against Candida albicans, Escherichia coli, and Staphylococcus aureus. The minimum inhibitory concentration values of A. malaccensis against the tested pathogens were found to be lesser than the other species. 相似文献
48.
Material properties and operating configurations of membrane reactors for propane dehydrogenation 下载免费PDF全文
Seung‐Won Choi Christopher W. Jones Sankar Nair David S. Sholl Jason S. Moore Yujun Liu Ravindra S. Dixit John G. Pendergast 《American Institute of Chemical Engineers》2015,61(3):922-935
A modeling‐based approach is presented to understand physically realistic and technologically interesting material properties and operating configurations of packed‐bed membrane reactors (PBMRs) for propane dehydrogenation (PDH). PBMRs composed of microporous or mesoporous membranes combined with a PDH catalyst are considered. The influence of reaction and membrane transport parameters, as well as operating parameters such as sweep flow and catalyst placement, are investigated to determine desired “operating windows” for isothermal and nonisothermal operation. Higher Damköhler (Da) and lower Péclet (Pe) numbers are generally helpful, but are much more beneficial with highly H2‐selective membranes rather than higher‐flux, lower‐selectivity membranes. H2‐selective membranes show a plateau region of conversion that can be overcome by a large sweep flow or countercurrent operation. The latter shows a complex trade‐off between kinetics and permeation, and is effective only in a limited window. H2‐selective PBMRs will greatly benefit from the fabrication of thin (~1 µm or less) membranes. © 2014 American Institute of Chemical Engineers AIChE J, 61: 922–935, 2015 相似文献
49.
Cobalt oxide thin films are prepared by the nebulizer spray pyrolysis technique using cobalt chloride as the precursor material. The structural, optical, morphological and electrical properties are investigated as a function of substrate temperature (300–450 °C). The X-ray diffraction (XRD) analysis reveals that all the films are polycrystalline in nature, having cubic structure with preferential orientation along the (111) plane. The optical spectra show that the films are transparent (68 %) in the IR region. The optical band gap values are calculated for different substrate temperature. Photoluminescence (PL) spectra of the films indicate the presence of indigo, blue and green emission peaks with an ultraviolet emission peak centered around 368nm. SEM images reveals small sphere-like structures for the prepared Co3O4 films. The maximum conductivity obtained is 1.48 x 10?3 S/cm at 350 °C. The activation energy varies between 0.039 and 0.138 eV for the substrate temperature variation from 300-450 Q°C. 相似文献
50.
I. Jerin Leno S. Saravana Sankar S. G. Ponnambalam 《The International Journal of Advanced Manufacturing Technology》2016,84(5-8):787-799
A well-planned arrangement of manufacturing departments on a two-dimensional planar region considerably increases the efficiency of its production systems, which is termed facility layout problem (FLP). Conventional layout design approach often designs intercell layout (determining exact location of each department on shop floor area) and flow path layout design of material handling system (MHS) step by step in a sequential manner. This results in suboptimal solutions for FLP. In this paper, an integrated approach is adopted to design the intercell layout and the flow path layout of MHS simultaneously. The quality of the final layout is evaluated by minimizing total material handling cost. Sequence pair (SP) representation is used for layout encoding. The translation from SP to layout is efficiently made by longest common subsequence (LCS) methodology. An elitist strategy genetic algorithm using simulated annealing (E-GASAA) as a local search mechanism is developed and tested with four test problem instances available in the literature. Elitist strategy is incorporated to enhance convergence characteristic of the proposed algorithm. It is found that the proposed E-GASAA is able to produce best solutions consistently for the test problem instance of different sizes within acceptable computational effort. In addition to that, we tried to reduce the computational load with the help of adopted LCS computation methodology and achieved a good improvement. 相似文献