A study on hot corrosion behaviour of Ni–5Al coatings on Ni- and Fe-based superalloys in an aggressive environment at 900 °C

Ni–5Al coating was deposited on Ni- and Fe-based superalloys by high velocity oxy fuel (HVOF) process to enhance their high-temperature corrosion resistance. Hot corrosion studies were conducted on bare as well as HVOF-coated superalloy specimens after exposure to a molten salt environment at 900 °C under cyclic conditions. Each cycles consisted of 1 h heating in the silicon carbide tube furnace followed by 20 min cooling in air. Thermogravimetric technique was used to approximate the kinetics of corrosion. Techniques like X-ray diffraction (XRD), scanning electron microscopy/energy dispersive X-ray analysis (SEM/EDAX) were used to characterize the corrosion products. The coatings and the oxide scale formed on the exposed surface were found to be intact with the superalloys. Superfer 800 with Ni–5Al coating has provided a good protection to the superalloys in the given molten salt environment.     

Causes and consequences of inflammation on anemia management in hemodialysis patients

Inflammation is common among hemodialysis patients, and evidence is accumulating to suggest that inflammation is a major contributor to morbidity and mortality. Several factors have been suggested as potential causes of inflammation, including infections and the atherosclerosis process, as well as etiologies directly related to kidney disease such as reduced renal function and dialysis. Among several inflammatory biomarkers investigated, serum C-reactive protein (CRP) is the most widely used. In hemodialysis patients, raised CRP levels have been shown to be predictive of cardiovascular events, hospitalization, and all-cause and cardiovascular mortality. Elevated CRP levels may correlate with comorbidities and intercurrent events, all of which may impact the response to erythropoiesis-stimulating agents (ESAs) and lead to higher ESA doses. Most dialysis facilities do not routinely measure CRP, despite recommendations by the National Kidney Foundation's Kidney Disease Outcomes Quality Initiative. Regular measurement of CRP levels may help providers to understand change in ESA dosing and identify patients at risk for cardiovascular events. This review explores the inter-relationships between inflammation, CRP levels, and anemia management in patients receiving hemodialysis.     

Phase Reversion‐Induced Nanograined/Ultrafine‐Grained Structures in Austenitic Stainless Steel and their Significance in Modulating Cellular Response: Biochemical and Morphological Study with Fibroblasts

Materials science, engineering, and biological sciences have been combined to improve the tissue compatibility of medical devices. In this regard, nano/ultrafine structuring of austenitic stainless steel obtained using an innovative approach of “phase‐reversion” has been evaluated for modulation of cellular activity. The biochemical and morphology study with fibroblasts point toward the improvement of tissue compatibility on comparison with coarse‐grained structures, strengthening the foundation of nanostructured materials for bio‐medical applications.     

Effect of Al on the hydrogenation characteristics of nanocrystalline Mg powder

We have fabricated nanocrystalline Mg–Al powders with nominal Al compositions of 4 and 8 at% by the electrodeposition technique and have compared their hydrogenation characteristics with those for a commercially available pure Mg powder. It is elucidated that interestingly the amount of Al incorporated in MgH₂ increases with decreasing the hydrogenation temperature. This observation indicates that the magnesium hydride phase has a limited solubility for aluminum and the supersaturation of hydride with Al is attributed to the slower mobility of aluminum at low temperatures. The rejection of Al during hydride formation is shown to result in a higher fraction of the intermetallic phase, thus reducing the hydrogen capacity. It is suggested that the presence of the intermetallic phase prior to hydrogenation enhances the hydride nucleation rate, which further decreases the hydrogen capacity in comparison to pure Mg.     

Microstructure-sensitive notch root analysis for dwell fatigue in Ni-base superalloys

Macroscopic viscoplastic constitutive models for γ–γ′ Ni-base superalloys typically do not contain an explicit dependence on the underlying microstructure. Microstructure-sensitive models are of interest in many applications since microstructure can vary in components, whether intentional or not. In such cases, the use of experiments from one microstructure condition to fit macroscopic models may be too limiting. The principal microstructure attributes that can significantly affect the cyclic stress–strain response of γ–γ′ Ni-base superalloys are the grain size and γ′ precipitate volume fraction and size distributions. An artificial neural network (ANN) is used to correlate the material parameters of a macroscale internal state variable cyclic viscoplasticity model with these microstructure attributes using a combination of limited experiments augmented by polycrystal plasticity calculations performed on other (virtual) microstructures within the range characterized experimentally. The trained model is applied to an example of a component fatigue notch root analysis with dwell periods at peak load to demonstrate the methodology and explore the potential impact of microstructure-sensitive constitutive models on life prediction for notched structures subjected to realistic load histories.     

Acoustic Emission Study on Effect of Stress Triaxiality on Damage Micromechanisms in Near Alpha Titanium Alloy

Acoustic Emission (AE) studies have been performed on smooth and notched specimens of a near alpha titanium alloy under monotonic loading condition to study the effect of stress triaxiality on damage micromechanisms. The damage in the notched specimen was found to be of cleavage type as against the ductile type of damage in smooth specimen. This difference was distinguished in the AE energy evolution with notched specimen producing higher energy rate with lower total energy than that of smooth specimen.     

EFFECT OF PROCESS PARAMETERS AND TOOL SHAPE ON THE MACHINABILITY OF A PARTICULATE FILLED-POLYMER COMPOSITE MATERIAL FOR RAPID TOOLING

This paper presents the results of an experimental study on the effects of machining parameters (cutting speed, feed, depth of cut) and tool shape on chip formation, surface topography, resultant cutting force and surface roughness produced in flat and ball end milling of the Ren Shape-Express 2000™ aluminum particulate filled-polymer composite material. This material is shown to exhibit a brittle-to-ductile transition in chip formation with decreasing cutting speed. The transition is explained by the strain-rate sensitivity of the polymer matrix and is found to correlate well with a corresponding change in the surface roughness. The absence of clear feed marks on the milled surface explains why molds made from the composite material require less hand polishing than machined metal molds. The influence of cutting conditions and tool shape (flat end vs. ball-nose) on the cutting force, surface roughness, and workpiece breakout are discussed and relevant comparisons with conventional metal and polymer machining are made.     

Microstructure and High Temperature Impression Creep Properties of Mg–3Ca–xZr (x = 0.3, 0.6, 0.9 wt%) Alloys

The current study has investigated the influence of zirconium (Zr) addition to Mg–3Ca–xZr (x = 0.3, 0.6, 0.9 wt%) alloys prepared using argon arc melting on the microstructure and impression properties at 448–498 K under constant stress of 380 MPa. Microstructural analysis of as-cast Mg–3Ca–xZr alloys showed grain refinement with Zr addition. The observed grain refinement was attributed to the growth restriction effect of Zr in hypoperitectic Mg–3Ca–0.3 wt% Zr alloys. Heterogeneous nucleation of α-Mg in properitectic Zr during solidification resulted in grain refinement of hyperperitectic Mg–3Ca–0.6 wt% Zr and Mg–3Ca–0.9 wt% Zr alloys. The hardness of Mg–3Ca–xZr alloys increased as the amount of Zr increased due to grain refinement and solid solution strengthening of α-Mg by Zr. Creep resistance of Mg–3Ca–xZr alloys increased with the addition of Zr due to solid solution strengthening of α-Mg by Zr. The calculated activation energy (Q_a) for Mg–3Ca samples (131.49 kJ/mol) was the highest among all alloy compositions. The Q_a values for 0.3, 0.6 and 0.9 wt% Zr containing Mg–3Ca alloys were 107.22, 118.18 and 115.24 kJ/mol, respectively.     

A new approach of sizing battery energy storage system for smoothing the power fluctuations of a PV/wind hybrid system

In this paper, a new approach for optimally sizing the storage system employing the battery banks for the suppression of the output power fluctuations generated in the hybrid photovoltaic/wind hybrid energy system. At first, a novel multiple averaging technique has been used to find the smoothing power that has to be supplied by the batteries for the different levels of smoothing of output power. Then the battery energy storage system is optimally sized using particle swarm optimization according to the level of smoothing power requirement, with the constraints of maintaining the battery state of charge and keeping the energy loss within the acceptable limits. Two different case studies have been presented for different locations and different sizes of the hybrid systems in this work. The results of the simulation studies and detailed discussions are presented at the end to portrait the effectiveness of the proposed method for sizing of the battery energy storage system. Copyright © 2016 John Wiley & Sons, Ltd.