The effect of loading rates and particle geometry on compressive properties of polypropylene/zinc oxide nanocomposites: Experimental and numerical prediction

Compressive properties, of particulate filled polymer matrix composites, are affected (to a certain extent) by the geometry of the particles, as well as the loadingrates. Therefore, this article presents the results on the compressive properties of polypropylene/zinc oxide nanocomposites across strain rates from 10⁻² to 10⁻³ s⁻¹. The specimens were tested using a Universal Testing Machine for static loading and a conventional Split Hopkinson Pressure Bar apparatus for dynamic loading. Results show that the yield stress and 2.5% flow stress, of both PP/ZnO nanocomposites, showed a positive increment with increasing strain rates. However, the yield strain shows a contradictory pattern, where it decreased with increasing strain rates. PP/ZnO‐white seal recorded higher strain rate sensitivity, dissipation energy, stiffness, and strength properties, than that of PP/ZnO‐pharmaceutical, over a wide range of strain rates investigated. Interestingly, the Eyring theory almost agreed with the experimental results. Overall, based on the experimental and numerical results, we do believe that particle geometry, as well as strain rates, has a significant influence on the compressive properties of polypropylene/zinc oxide nanocomposites specimens. POLYM. COMPOS., 2012. © 2011 Society of Plastics Engineers     

Analysis of forces in an automobile ECV using in external variable displacement swash plate type compressor for air conditioning control system

To meet the demand of improved comfort for passengers, drive ability and standard in fuel economy; external variable displacement swash (wobble) plate type compressors are used in automobile air conditioning control system because of their low energy consumption and highly efficient characteristics. It controls the compressor displacement by increasing or reducing the swash plate angle. Solenoid operated electromagnetic control valve (ECV) in the compressor controls the air conditioning system by means of a pulse width modulation (PWM) input signal supplied from an external source (controller). The mechanism changes the swash plate angle by increasing or reducing the pressure of swash plate chamber using the ECV functions. The force (solenoid) for ECV operation is important as the force directly related to the movement of the internal feature i.e. mainly plunger of the ECV which is responsible for the amount of air/refrigerant flow that results the air conditioning control procedures with various pressure ports. The research paper highlights the improved theory and equation for calculating the working force (solenoid force) in ECV and experimental analysis of 3 (three) ECV samples followed by the comparison of theoretical and experimental force results.     

A unique mechanism for methyl ester formation via an amide intermediate found in myxobacteria

Secondary metabolism involves a broad diversity of biochemical reactions that result in a wide variety of biologically active compounds. Terminal amide formation during the biosynthesis of the myxobacterial electron-transport inhibitor, myxothiazol, was analyzed by heterologous expression of the unique nonribosomal-peptide synthetase, MtaG, and incubation with a synthesized substrate mimic. These experiments provide evidence that the terminal amide is formed from a carrier protein-bound myxothiazol acid that is thioesterified to MtaF. This intermediate is transformed to an amide by extension with glycine and subsequent oxidative cleavage by MtaG. The final steps of melithiazol assembly involve a highly similar protein-bound intermediate (attached to MelF, a homologue of MtaF), which is transformed to an amide by MelG (homologue of MtaG). In this study, we also show that the amide moiety of myxothiazol A can be hydrolyzed in vivo to the formerly unknown free myxothiazol acid by heterologous expression of melJ in the myxothiazol producer Stigmatella aurantiaca DW4/3-1. The methyltransferase MelK can finally methylate the acid to give rise to the methyl ester, which is produced as the final product in the melithiazol A biosynthetic pathway. These experiments clarify the role of MelJ and MelK during melithiazol assembly.     

Static and dynamic compressive properties of polypropylene/zinc oxide nanocomposites

The effect of strain rate is widely recognized as an essential factor that influences the mechanical properties of polymer matrix composites. Despite its importance, no previous work has been reported on the high‐strain rate behavior of polypropylene/zinc oxide nanocomposites. Based on this, static and dynamic compression properties of polypropylene/zinc oxide nanocomposites, with particle contents of 1%, 3%, and 5% by weight, were successfully studied at different strain rates (i.e., 0.01 s^?1, 0.1 s^?1, 650 s^?1, 900 s^?1, and 1100 s^?1) using a universal testing machine and a split Hopkinson pressure bar apparatus. For standardization, approximately 24 nm of zinc oxide nanoparticles were embedded into polypropylene matrix for each of the tested polypropylene/zinc oxide nanocomposites. Results show that the yield strength, the ultimate strength, and the stiffness properties, of polypropylene/zinc oxide nanocomposites, were greatly affected by both particle loading and applied strain rate. Furthermore, the rate sensitivity and the absorbed energy of all tested specimens showed a positive increment with increasing strain rate, whereas the thermal activation volume showed a contrary trend. In addition, the fractographic analysis and particle dispersion of all composite specimens were successfully obtained using a field emisission scanning electron microscopy. POLYM. ENG. SCI., 54:949–960, 2014. © 2013 Society of Plastics Engineers     

Effect of Location of Restraint on Fire Response of Steel Beams

Restrained steel beams, when exposed to fire, develop significant restraint forces and often behave as beam-columns. The response of such restrained steel beams under fire depends on many factors including: fire scenario, beam slenderness ratio, location of axial restraint at the supports, and high-temperature properties of steel. A set of numerical studies, using finite element computer program ANSYS, is carried out to study the fire response of steel beam-columns under realistic fire and restraint scenarios. Results from the parametric studies indicate that fire scenario, beam slenderness, location of axial restraint and high-temperature creep have significant influence on the behavior of restrained beams under fire conditions. Severe fires produce high axial forces at early stages of fire exposure; whereas in moderate fires, significant axial force develops only at later stages of fire exposure. Axial restraint enhances the fire resistance due to the development of tensile catenary action in restrained beams. Furthermore, restrained beams with low slenderness ratio exhibit better fire performance when the axial restraint at the support is located at the bottom flange.     

Resistance of stainless steel CHS columns based on cross-section deformation capacity

A conceptually new structural design approach has recently been proposed by the authors to predict the resistance of stainless steel members subjected to various types of loading with cross-sections formed from thin flat plates including angles, channels, lipped channels, I-sections and rectangular hollow sections (RHS). The proposed method does not follow the traditional cross-section classification approach, which primarily relies on the assumption of a bilinear, elastic-perfectly-plastic material model. Instead, deformation capacity of a cross-section is determined directly from the local buckling characteristics of the constituent plate elements. This is then used to obtain the corresponding local buckling stress utilising an appropriate material model. This basic concept is extended herein to predict compression resistance of stainless steel columns with circular hollow sections (CHS). Available test and finite element (FE) results have been used to develop the basic design equation to predict the compression resistance of cross-sections and to propose column curves to determine flexural buckling resistances. The predicted resistances have been compared to those obtained using the current Eurocode; the predictions are significantly more accurate and more consistent than those given by the existing Eurocode.     

A new design of magnetorheological fluid based braking system using genetic algorithm optimization

This paper proposes a new design for an automotive magnetorheological (MR) braking system using multiple rotary disks. We develop an analytical model to calculate the torque and validate our results using finite element analysis considering a non-linear relationship between magnetic field and magnetic flux. Using genetic algorithm, we optimize the system’s dimensions to generate maximum torque. The optimized geometry shows an improvement in output torque compared to existing systems. Moreover, our design directs higher flux onto the MR fluid and subsequently generates greater shear frictions. This design can be used in applications such as rehabilitation devices.     

Influences of copolymers (Copovidone,Eudragit RL PO and Kollicoat MAE 30 DP) on stability and bioactivity of spray-dried and freeze-dried lysozyme

Protein stability is the most crucial factor in protein pharmaceutical preparations. Various techniques were applied for producing stable protein formulations such as spray-drying and freeze-drying. However, heating and freezing stresses are disadvantages for proteins using these methods, respectively. Accordingly, excipients have been used to preserve therapeutic effects of proteins during processing and for long period of time. Therefore, influences of Copovidone, Eudragit^® RL-PO and Kollicoat^® MAE-30 DP (as excipients) on stability and integrity of lysozyme (as a model protein) in spray-dried and freeze-dried forms were investigated. Protein formulations in both dried forms were prepared without and with the addition of mentioned excipients at different concentrations. Protein formulations were characterized for yield determination, morphology using scanning electron microscopic (SEM), thermal analysis by Differential Scanning Calorimetry (DSC), secondary structure stability using Fourier transform infrared (FT-IR) spectroscopy and biological activity. All protein formulations were subjected to a stability study as solid protein formulations for 3 weeks at 24?°C/76% relative humidity and aqueous protein samples were stored at 50?°C for 30?min in a water bath. Results showed that Copovidone successfully preserved integrity and biological activity of lysozyme before and after storage in both spray-dried and freeze-dried forms with more advantage for using higher concentration of the same excipient. Smooth spheres of spray-dried lysozyme formulations with Copovidone were smaller than spray-dried lysozyme without and with Kollicoat^® MAE-30 DP, which affected %yield produced. Copovidone has demonstrated valuable protection ability for lysozyme.     

Blockchain-Enabled EHR Framework for Internet of Medical Things

The Internet of Medical Things (IoMT) offers an infrastructure made of smart medical equipment and software applications for healthcare services. Through the internet, the IoMT is capable of providing remote medical diagnosis and timely health services. The patients can use their smart devices to create, store and share their electronic health records (EHR) with a variety of medical personnel including medical doctors and nurses. However, unless the underlying commination within IoMT is secured, malicious users can intercept, modify and even delete the sensitive EHR data of patients. Patients also lose full control of their EHR since most healthcare services within IoMT are constructed under a centralized platform outsourced in the cloud. Therefore, it is appealing to design a decentralized, auditable and secure EHR system that guarantees absolute access control for the patients while ensuring privacy and security. Using the features of blockchain including decentralization, auditability and immutability, we propose a secure EHR framework which is mainly maintained by the medical centers. In this framework, the patients’ EHR data are encrypted and stored in the servers of medical institutions while the corresponding hash values are kept on the blockchain. We make use of security primitives to offer authentication, integrity and confidentiality of EHR data while access control and immutability is guaranteed by the blockchain technology. The security analysis and performance evaluation of the proposed framework confirms its efficiency.     

Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism

Nano-Micro Letters - Antibacterial activity of zinc oxide nanoparticles (ZnO-NPs) has received significant interest worldwide particularly by the implementation of nanotechnology to synthesize...